Citation: Yu-Ru FU, Qin LIU, Chuan-Fu SUN. A Perimidin Derivative with Multiple Redox Centers as an Anode for Lithium-ion Batteries[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 263-268. doi: 10.14102/j.cnki.0254–5861.2011–2458 shu

A Perimidin Derivative with Multiple Redox Centers as an Anode for Lithium-ion Batteries

Yu-Ru FU ^{a, b} ,
Qin LIU ^a ,
Chuan-Fu SUN ^{a, b,,}

a.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: Chuan-Fu SUN, cfsun@fjirsm.ac.cn
Received Date: 14 May 2019
Accepted Date: 10 July 2019

Fund Project: the National Natural Science Foundation of China 21771180the National Natural Science Foundation of China 51702318the Natural Science Foundation of Fujian Province 2018J01031

Figures(4)

Organic molecules are attractive electrode materials for rechargeable batteries owing to their sustainability, low cost, and light weight. In this work, we report a new organic anode, a perimidin derivative 1, 3, 5-tri(1H-perimidin-2-yl)-benzene (TPB), for lithium-ion batteries. The TPB structure contains multiple redox centers including π-conjugated benzene ring, C=N, and -NH groups and delivers a high reversible specific capacity of 300 mAh/g at 50 mA/g under a six-electron redox reaction. Moreover, TPB exhibits excellent rate capability and long-term cyclability with 98.1% capacity retention over 1500 cycles at 1000 mA/g. The results may open new opportunities for the development of low-cost and long-lifespan lithium-ion batteries.
- lithium-ion batteries,
- organic electrode,
- multiple redox centers,
- long lifespan
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