Citation: Hui-Liang WEN, Bo-Wen LAI, Hua-Long PENG, Zhi-Qiang XIONG, Chong-Bo LIU. Characterization and Infrared Stealthy Properties of Two Schiff-base Compounds Derived from 1-Amino-2-hydroxypropane and Their Complexes[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 279-286. doi: 10.14102/j.cnki.0254–5861.2011–2420 shu

Characterization and Infrared Stealthy Properties of Two Schiff-base Compounds Derived from 1-Amino-2-hydroxypropane and Their Complexes

a.
State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang 330047, China
b.
Chemicals Analysis Department, Nanchang Institute for Food and Drug Control, Nanchang 330038, China
c.
School of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China

Corresponding author: Chong-Bo LIU, cbliu2002@163.com
Received Date: 19 April 2019
Accepted Date: 19 September 2019

Fund Project: the National Natural Science Foundation of China 21264011the National Natural Science Foundation of China 20961007the State Key Laboratory of Food Science and Technology of Nanchang University SKLF-ZZB-201519

Figures(5)

Single crystals of two Schiff base compounds 1 and 2 derived from 1-amino-2-hydroxypropane were obtained via condensation reaction of an amine and a reactive carbonyl group. The compounds were characterized by elemental analysis, IR and single-crystal X-ray diffraction. Compound 1 (C₁₀H₁₃NO₂) crystallizes in the monoclinic system, space group P2₁ with a = 4.487(9), b = 10.913(2), c = 9.886(19) Å, β = 97.823(3)º, V = 479.59(16) Å³, Z = 2, M_r = 179.21, D_c = 1.241 g/cm³, F(000) = 192, GOOF = 1.005, μ = 0.087 mm^-1, the final R = 0.0328 and wR = 0.0738 for 1721 observed reflections with I > 2σ(I). Compound 2 (C₁₄H₂₀N₂O₂) crystallizes in orthorhombic system, space group Pbca with a = 6.295(2), b = 7.290(3), c = 30.519(11) Å, V = 1400.5(9) Å³, Z = 8, M_r = 248.32, D_c = 1.178 g/cm³, F(000) = 536, GOOF = 1.125, μ = 0.079 mm^-1, the final R = 0.0871 and wR = 0.1748 for 1307 observed reflections with I > 2σ(I). Compound 1 exhibits a 3D supramolecular structure and compound 2 show a 3D supramolecular structure under hydrogen bonding interactions. Furthermore, the infrared stealthy performance of two Schiff base compounds and their Fe(Ⅲ) complexes were studied. The results show that their Fe(Ⅲ) complexes show lower infrared emissivity than corresponding Schiff base compounds, and the lowest infrared emissivity reaches to 0.657.
- two Schiff base compounds,
- 1-amino-2-hydroxypropane,
- crystal structure,
- Fe(Ⅲ) complexes,
- infrared stealth
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