Citation: Pei-Pei CUI, Yong LIU, Hong-Guo ZHAI, Jian-Peng ZHU, Wen-Ning YAN, Yun-Min YANG. Two Copper-organic Frameworks Constructed from the Flexible Dicarboxylic Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 368-374. doi: 10.14102/j.cnki.0254–5861.2011–2417 shu

Two Copper-organic Frameworks Constructed from the Flexible Dicarboxylic Ligands

a.
Shandong Provincial Key Laboratory of Functional Macromolecular Biophysics, Shandong Universities Key Laboratory of Functional Biological Resources Utilization and Development, School of Life Science, Dezhou University, Dezhou, Shandong 253023, China
b.
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, Nanjing University, Jiangsu 210023, China
c.
School of Mechanical and Electronical Engineering, Dezhou University, Dezhou, Shandong 253023, China

Corresponding author: Pei-Pei CUI, 1cuipeipei1@163.com
Received Date: 19 April 2019
Accepted Date: 4 July 2019

Fund Project: the National Natural Science Foundation of China 21701021the Natural Science Foundation ZR2017BEM023the Open Fund of State Key Laboratory of Coordination Chemistry of Shandong Province SKL CC1905

Figures(5)

Two new copper-organic frameworks [Cu₄(L¹)₄(DMF)₄·2DMF]_n (DZ-1) and [Cu(L²)(DMF)]_n (DZ-2) (H₂L¹ = 2, 2'-(1, 4-phenylenebis(methylene))bis(sulfanediyl)dinicotinic acid and H₂L² = 2, 2'-(1, 2-phenylenebis(methylene))bis(sulfanediyl)dinicotinic acid) have been synthesized and characterized. DZ-1 with a zero-dimensional structure crystallizes in monoclinic crystal system, space group P2₁/n with a = 17.1697(11), b = 17.1241(11), c = 18.8638(14) Å, V = 5193.2(6) Å³, Z = 2, D_c = 1.493 g·cm^-3, μ = 1.046 mm^-1, F(000) = 2408. All L¹ ligands adopted syn-conformation. DZ-2 is a two-dimensional structure crystallized in monoclinic crystal system, space group P2₁/n with a = 11.855(5), b = 18.601(8), c = 12.319(5) Å, V = 2400.4(18) Å³, Z = 4, D_c = 1.514 g·cm^-3, μ = 1.124 mm^-1, F(000) = 1124. The selective sorption of CO₂ over N₂ for DZ-1 was found.
- copper-organic framework,
- flexible dicarboxylic ligand,
- conformation
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