Citation: Pei-Pei CUI, Yong LIU, Hong-Guo ZHAI, Jian-Peng ZHU, Wen-Ning YAN, Yun-Min YANG. Two Copper-organic Frameworks Constructed from the Flexible Dicarboxylic Ligands[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 368-374. doi: 10.14102/j.cnki.0254–5861.2011–2417 shu

Two Copper-organic Frameworks Constructed from the Flexible Dicarboxylic Ligands

a.
Shandong Provincial Key Laboratory of Functional Macromolecular Biophysics, Shandong Universities Key Laboratory of Functional Biological Resources Utilization and Development, School of Life Science, Dezhou University, Dezhou, Shandong 253023, China
b.
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, Nanjing University, Jiangsu 210023, China
c.
School of Mechanical and Electronical Engineering, Dezhou University, Dezhou, Shandong 253023, China

Corresponding author: Pei-Pei CUI, 1cuipeipei1@163.com
Received Date: 19 April 2019
Accepted Date: 4 July 2019

Fund Project: the National Natural Science Foundation of China 21701021the Natural Science Foundation ZR2017BEM023the Open Fund of State Key Laboratory of Coordination Chemistry of Shandong Province SKL CC1905

Figures(5)

Two new copper-organic frameworks [Cu₄(L¹)₄(DMF)₄·2DMF]_n (DZ-1) and [Cu(L²)(DMF)]_n (DZ-2) (H₂L¹ = 2, 2'-(1, 4-phenylenebis(methylene))bis(sulfanediyl)dinicotinic acid and H₂L² = 2, 2'-(1, 2-phenylenebis(methylene))bis(sulfanediyl)dinicotinic acid) have been synthesized and characterized. DZ-1 with a zero-dimensional structure crystallizes in monoclinic crystal system, space group P2₁/n with a = 17.1697(11), b = 17.1241(11), c = 18.8638(14) Å, V = 5193.2(6) Å³, Z = 2, D_c = 1.493 g·cm^-3, μ = 1.046 mm^-1, F(000) = 2408. All L¹ ligands adopted syn-conformation. DZ-2 is a two-dimensional structure crystallized in monoclinic crystal system, space group P2₁/n with a = 11.855(5), b = 18.601(8), c = 12.319(5) Å, V = 2400.4(18) Å³, Z = 4, D_c = 1.514 g·cm^-3, μ = 1.124 mm^-1, F(000) = 1124. The selective sorption of CO₂ over N₂ for DZ-1 was found.
- copper-organic framework,
- flexible dicarboxylic ligand,
- conformation
1. [1]
  Cui, Y. Y.; Zhang, J.; He, H. J.; Qian, G. D. Photonic functional metal-organic frameworks. Chem. Soc. Rev. 2018, 47, 5740−5785. doi: 10.1039/C7CS00879A
2. [2]
  Dhakshinamoorthy, A.; Li, Z. H.; Garcia, H. Catalysis and photocatalysis by metal organic frameworks. Chem. Soc. Rev. 2018, 47, 8134−8172. doi: 10.1039/C8CS00256H
3. [3]
  Li, J.; Wang, X. X.; Zhao, G. X.; Chen, C. L.; Chai, Z. F.; Alsaedi, A.; Hayatf, T.; Wang, X. K. Metal-organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions. Chem. Soc. Rev. 2018, 47, 2322−2356. doi: 10.1039/C7CS00543A
4. [4]
  Kang, Y. S.; Lu, Y.; Chen, K.; Zhao, Y.; Wang P.; Sun, W. Y. Metal-organic frameworks with catalytic centers: from synthesis to catalytic application. Coord. Chem. Rev. 2019, 378, 262−280. doi: 10.1016/j.ccr.2018.02.009
5. [5]
  Cui, P. P.; Wang, P.; Zhao, Y.; Sun, W. Y. Fabrication of desired metal-organic frameworks via postsynthetic exchange and sequential linker installation. Cryst. Growth Des. 2019, 19, 1454−1470. doi: 10.1021/acs.cgd.8b01628
6. [6]
  Cui, P. P.; Wu, J. L.; Zhao, X. L.; Sun, D.; Zhang, L. L.; Guo, J.; Sun, D. F. Two solvent-dependent zinc(Ⅱ) supramolecular isomers: rare kgd and lonsdaleite network topologies based on a tripodal flexible ligand. Cryst. Growth Des. 2011, 11, 5182−5187. doi: 10.1021/cg201181s
7. [7]
  Wan, X. Y.; Jiang, F. L.; Liu, C. P.; Zhou, K.; Chen, L.; Gai, Y. L.; Yang, Y.; Hong, M. C. Rapid and discriminative detection of nitro aromatic compounds with high sensitivity using two zinc MOFs synthesized through a temperature-modulated method. J. Mater. Chem. A 2015, 3, 22369−22376. doi: 10.1039/C5TA04552E
8. [8]
  Sun, Y. X.; Sun, W. Y. Zinc(Ⅱ)-and cadmium(Ⅱ)-organic frameworks with 1-imidazole-containing and 1-imidazolecarboxylate ligands. CrystEngComm 2015, 17, 4045−4063. doi: 10.1039/C5CE00372E
9. [9]
  You, L. X.; Xie, S. Y.; Xia, C. C.; Wang, S. J.; Xiong, G.; He, Y. K.; Dragutan, I.; Dragutan, V.; Fedinc, V. P.; Sun, Y. G. Unprecedented homochiral 3D lanthanide coordination polymers with triple-stranded helical architecture constructed from a rigid achiral aryldicarboxylate ligand, CrystEngComm. 2019, 21, 1758−1763. doi: 10.1039/C8CE01242C
10. [10]
  Dai, F. N.; Fan W. D.; Bi, J. H.; Jiang, P.; Liu, D. D.; Zhang, X. R.; Lin, H.; Gong, C. F.; Wang, R. M.; Zhang, L. L.; Sun, D. F. Lead-porphyrin metal-organic framework: gas adsorption properties and electrocatalytic activity for water oxidation. Dalton Trans. 2016, 45, 61−65. doi: 10.1039/C5DT04025F
11. [11]
  Lin, Z. J.; Lü, J.; Hong, M. C.; Cao, R. Metal-organic frameworks based on flexible ligands (FL-MOFs): structures and applications. Chem. Soc. Rev. 2014, 43, 5867−5895. doi: 10.1039/C3CS60483G
12. [12]
  Cui, P. P.; Dou, J. M.; Sun, D.; Dai, F. N.; Wang, S. N.; Sun, D. F.; Wu, Q. Y. Reaction vessel-and concentration-induced supramolecular isomerism in layered lanthanide-organic frameworks. CrystEngComm 2011, 13, 6968–6971. doi: 10.1039/c1ce05839h
13. [13]
  Yu, Q.; Zeng, Y. F.; Zhao, J. P.; Yang, Q.; Bu, X. H. Zeolite-like metal-organic framework based on a flexible 2-(1H-benzimidazol-2-ylthio)acetic ligand: synthesis, structures, and properties. Cryst. Growth Des. 2010, 10, 1878–1884. doi: 10.1021/cg901571m
14. [14]
  Baladi, E.; Nobakht, V.; Tarassoli, A.; Proserpio, D. M.; Carlucci, L. Three cationic, nonporous Cu^I-coordination polymers: structural investigation and vapor iodine capture. Cryst. Growth Des. 2018, 18, 7207–7218. doi: 10.1021/acs.cgd.8b01446
15. [15]
  Hsu, C. H.; Huang, W. C.; Yang, X. K.; Yang, C. T.; Chhetri, P. M.; Chen, J. D. Entanglement and irreversible structural transformation in Co(Ⅱ) coordination polymers based on isomeric bis-pyridyl-bis-amide ligands. Cryst. Growth Des. 2019, 19, 1728–1737. doi: 10.1021/acs.cgd.8b01706
16. [16]
  Zhang, X. T.; Chen, H. T.; Li, B.; Liu, G. Z.; Liu, X. Z. Construction of functional coordination polymers derived from designed flexible bis(4-carboxybenzyl)amine. CrystEngComm. 2019, 21, 1231–1241 doi: 10.1039/C8CE01418C
17. [17]
  Das, D.; Biradha, K. Luminescent coordination polymers of naphthalene dased diamide with rigid and flexible dicarboxylates: sensing of nitro explosives, Fe(Ⅲ) Ion, and dyes. Cryst. Growth Des. 2018, 18, 3683–3692. doi: 10.1021/acs.cgd.8b00498
18. [18]
  Zong, Z. A.; Fan, C. B.; Zhang, X.; Meng, X. M.; Jin, F.; Fan, Y. -H. Four Co(Ⅱ) coordination polymers based on 4, 4'-(1H-1, 2, 4-triazol-1-yl)methylenebis(benzoic acid): syntheses, structural diversity, magnetic properties, dye adsorption and photocatalytic properties. CrystEngComm. 2019, 21, 673–686. doi: 10.1039/C8CE01203B
19. [19]
  Dai, F. N.; He, H. Y.; Xie, A. P.; Chu, G. D.; Sun, D. F.; Ke, Y. X. Self-assembly of a novel metal-organic coordination cage (MOCC) based on a new flexible dicarboxylate ligand: synthesis, crystal structure and magnetic property. CrystEngComm. 2009, 11, 47–49. doi: 10.1039/B816015P
20. [20]
  Dai, F. N.; Dou, J. M.; He, H. Y.; Zhao, X. L.; Sun, D. F. Self-assembly of metal-organic supramolecules: from a metallamacrocycle and a metal-organic coordination cage to 1D or 2D coordination polymers based on flexible dicarboxylate ligands. Inorg. Chem. 2010, 49, 4117–4124. doi: 10.1021/ic902178c
21. [21]
  Dai, F. N.; He, H. Y.; Gao, D. L.; Ye, F.; Qiu, X. L.; Sun, D. F. Construction of copper metal-organic systems based on paddlewheel SBU through altering the substituent positions of new flexible carboxylate ligands. CrystEngComm. 2009, 11, 2516–2522. doi: 10.1039/b904671b
22. [22]
  Cui, P. P.; Cui, L. F.; Fu. A. Y. Three lanthanide-carboxylate coordination polymers with conformation variation based on flexible ligands: synthesis, structure and photoluminescence property. Chin. J. Inorg. Chem. 2016, 32, 1231–1238.
23. [23]
  Cui, P. P.; Fu, A. Y.; Wang, P. Topology and photoluminescence property of a neodymium-carboxylate coordination polymer based on tripodal flexible ligand. Chin. J. Struc. Chem. 2016, 35, 1391–1398.
24. [24]
  Yang, C.; Wong, W. T. Self-assembly of guanidinium hexagonal carboxylate: how many H-bonds and H-bonding pattern between ArCOO⁻ and C(NH₂)³⁺. Chem. Lett. 2004, 33, 856–857. doi: 10.1246/cl.2004.856
25. [25]
  Yang, C.; Wong, W. T.; Chen, X. M.; Cui Y. D.; Yang, Y. S. Star hexacarboxylate: synthesis, crystal structure and luminescent properties of its terbium complex. Sci. Chin. B 2003, 46, 558–565. doi: 10.1360/03yb0050
26. [26]
  SAINT, Program for Data Extraction and Reduction, Bruker AXS, Inc., Madison, WI 2001.
27. [27]
  Sheldrick, G. M. SADABS, University of Göttingen, Göttingen, Germany 2003.
28. [28]
  Sheldrick G. M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, Germany 1997.
29. [29]
  Sheldrick G. M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany 1997.
30. [30]
  Thakuria, R.; Nath, N. K.; Saha, B. K. The nature and applications of π-π interactions: A perspective. Cryst. Growth Des. 2019, 19, 523–528. doi: 10.1021/acs.cgd.8b01630
31. [31]
  Khavasi, H. R.; Fard, M. A. π-π Interactions affect coordination geometries. Cryst. Growth Des. 2010, 10, 1892–1896. doi: 10.1021/cg100265d
32. [32]
  Spek, A. L. Implemented as the PLATON Procedure, a Multipurpose Crystallographic Tool. Utrecht University, Utrecht, The Netherlands 1998.
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