Citation: Sheng-Nan LU, Feng-Xiang SHI, Wen-Shi WU, Zhi-Long QUAN. Three Zinc(Ⅱ) Complexes Based on 2-Carboxylic Acid-4-nitropyridine-1-oxide: Synthesis, Crystal Structure, and Fluorescence Properties[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 340-349. doi: 10.14102/j.cnki.0254–5861.2011–2406 shu

Three Zinc(Ⅱ) Complexes Based on 2-Carboxylic Acid-4-nitropyridine-1-oxide: Synthesis, Crystal Structure, and Fluorescence Properties

College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, China

Corresponding author: Wen-Shi WU, wws@hqu.edu.cn
Received Date: 12 April 2019
Accepted Date: 17 June 2019

Fund Project: Industrial pilot (key) project in Fujian Province 2017H0018

Figures(7)

Three new metal-organic complexes, namely [Zn(POA)₂(H₂O)₂] (1), [Zn(POA)₂(H₂O)₂]·2H₂O (2) and [Zn(POA)₂]_n (3), have been synthesized by organic ligand 2-carboxylic acid-4-nitropyridine-1-oxide (POA) and zinc(Ⅱ) ions. The structures of complexes 1~3 are characterized by single-crystal X-ray analysis, XRD powder diffraction analysis, infrared spectroscopy and thermal stability analysis method. Complex 1 belongs to monoclinic system, space group C2/c with a = 22.8215(15), b = 7.5613(16), c = 10.048(3) Å, β = 109.47°, V = 1634.7(6) Å³, Z = 4, F(000) = 944, D_c = 1.900 g/cm³, C₁₂H₁₀N₄O₁₂Zn, M_r = 467.61 and μ = 1.584 mm^-1. The whole molecule presents "V" shape. Complex 2 is a centrosymmetric structure in triclinic system with space group P\begin{document}$ \overline 1 $\end{document}: a = 7.4728(5), b = 7.6825(6), c = 8.5184(6) Å, α = 65.975(2), β = 79.87(2), γ = 89.855(2)°, V = 4384.1(5) Å³, Z = 1, F(000) = 256, D_c = 1.908 g/cm³, C₁₂H₁₄N₄O₁₄Zn, M_r = 503.64 and μ = 1.492 mm^-1. Complex 3 is a one-dimensional chain structure belonging to monoclinic system and space group P2₁/c with a = 4.9456(6), b = 12.5322(14), c = 11.2514(13) Å, β = 97.313(11)°, V = 6916.8(14) Å³, Z = 2, F(000) = 432, D_c = 2.072 g/cm³, C₁₂H₆N₄O₁₀Zn, M_r = 431.58, and μ = 1.852 mm^-1. In three complexes, six oxygen atoms from the surrounding coordination atoms form a ZnO₆ distorted octahedral coordination geometry around the zinc ions. Meanwhile, fluorescent properties of the three complexes were investigated at room temperature. The fluorescence spectroscopic analysis demonstrated that the ligand POA shows red-shift after coordinating with the zinc(Ⅱ) ions.
- 2-carboxylic acid-4-nitropyridine-1-oxide,
- zinc complexes,
- crystal structures,
- fluorescence properties
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