Citation: Ya-Li XUE, Dan ZHAO, Xiao-Qi CUI, Xiao-Yang HAN, Bao-Zhong LIU, Yan-Ping FAN. Crystal Structure of Scheelite-type LiTb(WO₄)₂ and Multi-color Emitting Properties Doped by Eu³⁺[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 310-320. doi: 10.14102/j.cnki.0254–5861.2011–2405 shu

Crystal Structure of Scheelite-type LiTb(WO₄)₂ and Multi-color Emitting Properties Doped by Eu³⁺

College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China

Corresponding author: Dan ZHAO, iamzd1996@163.com Yan-Ping FAN, fanyanping@hpu.edu.cn
Received Date: 16 April 2019
Accepted Date: 3 September 2019

Fund Project: the National Natural Science Foundation of China 51871090the National Natural Science Foundation of China U1804135the National Natural Science Foundation of China 51671080Plan for Scientific Innovation Talent of Henan Province 194200510019

Figures(8)

Single crystal of lithium terbium tungstate LiTb(WO₄)₂ has been grown by the flux method. The crystal structure was refined from single-crystal X-ray data. It crystallizes in tetragonal system, space group I4₁/a with a = 5.1749(9), c = 11.1953(19) Å, V = 299.81(12) Å³, Z = 2, M_r = 661.56, D_c = 7.328 g/cm³, F(000) = 560, μ(MoKα) = 49.94 mm^-1, R(F² > 2σ(F²)) = 0.026 and wR(F²) = 0.070. It features a typical scheelite-type structure composed of two-direction packing of isolated WO₄ tetrahedra. Li and Tb atoms in the structure occupy the same crystallographic site. Moreover, a series of solid solution phosphors LiTb_1-xEu_x(WO₄)₂ (x = 0.004~0.1) were synthesized by high temperature solid-state reactions. The phosphors could be effectively excited by a wavelength range from 379 to 487 nm, which matches well with the UV and near-UV LED chip. The emission color of the phosphor can be tuned from green, through yellow to red by simply adjusting the relative Eu³⁺ and Tb³⁺ concentration due to the Tb³⁺ to Eu³⁺ energy transfer.
- rare earth compounds,
- crystal structure,
- optical properties,
- phosphor,
- charge transfer
1. [1]
  Jiao, M. M.; Guo, N.; Lu, W.; Jia, Y. C.; Lv, W. Z.; Zhao, Q.; Shao, B. Q.; You, H. P. Tunable blue-green-emitting Ba₃LaNa(PO₄)₃F: Eu²⁺, Tb³⁺ phosphor with energy transfer for near-UV white LEDs. Inorg. Chem. 2013, 52, 10340−10346. doi: 10.1021/ic401033u
2. [2]
  Nelli, I.; Kaczmarek, A. M.; Locardi, F.; Caratto, V.; Costa, G. A.; Deun, R. V. Multidoped Ln³⁺ gadolinium dioxycarbonates as tunable white light emitting phosphors. Dalton Trans. 2017, 46, 2785−2792. doi: 10.1039/C6DT04629K
3. [3]
  Morrison, G.; Smith, M. D.; Zur Loye, H. C. Flux versus hydrothermal growth: polymorphism of A₂(UO₂)Si₂O₆ (A = Rb, Cs). Inorg. Chem. 2017, 56, 1053−1056. doi: 10.1021/acs.inorgchem.6b02931
4. [4]
  Zhang, F.; Zhang, T.; Li, G.; Zhang, W. Single phase M⁺ (M = Li, Na, K), Dy³⁺ co-doped KSrBP₂O₈ white light emitting phosphors. J. Alloys Compd. 2015, 618, 484−487. doi: 10.1016/j.jallcom.2014.08.178
5. [5]
  Taşcıoğlu, S.; Pekgözlü, İ.; Mergen, A. Synthesis and photoluminescence properties of Pb²⁺ doped SrAl₂B₂O₇. Mater. Chem. Phys. 2018, 112, 78−82.
6. [6]
  Dhanaraj, J.; Jagannathan, R.; Trivedi, D. C. Y₂O₂S: Eu³⁺ nanocrystals-synthesis and luminescent properties. J. Mater. Chem. 2003, 13, 1778−1782. doi: 10.1039/B302073H
7. [7]
  Bi, W.; Meng, Q. Y.; Sun, W. J. Luminescent properties and energy transfer mechanism of NaGd(MoO₄)₂: Sm³⁺, Eu³⁺ phosphors. Ceram. Int. 2016, 42, 14086−14093. doi: 10.1016/j.ceramint.2016.06.017
8. [8]
  Zhao, D.; Cui, J. Y.; Han, H. X.; Li, C. K₈Nb₇P₇O₃₉: a new type of complicated incommensurately modulated structure and photoluminescence properties of Eu³⁺-doped solid solutions. J. Mater. Chem. C 2016, 4, 11436−11448. doi: 10.1039/C6TC03022J
9. [9]
  Han, B.; Zhang, J.; Li, P.; Li, J.; Bian, Y.; Shi, H. L. Luminescence and energy transfer of emission tunable phosphors YBa₃B₉O₁₈: Ce³⁺, Tb³⁺. Optik 2015, 126, 1851−1854. doi: 10.1016/j.ijleo.2015.05.003
10. [10]
  Yawalkar, M. M.; Nair, G. B.; Zade, G. D.; Dhoble, S. J. Effect of the synthesis route on the luminescence properties of Eu³⁺ activated Li₆M(BO₃)₃ (M = Y, Gd) phosphors. Mater. Chem. Phys. 2017, 189, 136−145. doi: 10.1016/j.matchemphys.2016.12.006
11. [11]
  Yoon, S. J.; Hakeem, D. A.; Park, K. Synthesis and photoluminescence properties of MgAl₂O₄: Eu³⁺ phosphors. Ceram. Int. 2016, 42, 1261−1266. doi: 10.1016/j.ceramint.2015.09.059
12. [12]
  Evans, R. C.; Carlos, L. D.; Douglas, P.; Rocha, J. Tuning the emission colour in mixed lanthanide microporous silicates: energy transfer, composition and chromaticity. J. Mater. Chem. 2018, 18, 1100−1107.
13. [13]
  Zhang, F.; Xie, J.; Li, G.; Zhang, W.; Wang, Y.; Huang, Y.; Tao, Y. Cation composition sensitive visible quantum cutting behavior of high-efficiency green phosphors Ca₉Ln(PO₄)₇: Tb³⁺ (Ln = Y, La, Gd). J. Mater. Chem. C 2017, 5, 872−881. doi: 10.1039/C6TC03982K
14. [14]
  Xue, Y. L.; Zhao, D.; Shi, C. L.; Liu, B. Z.; Zhao, J.; Li, F. F. Energy transfer and green emitting properties of solid solution PbGd_1-xTb_xB₇O₁₃ (x = 0~1). Chin. J. Struct. Chem. 2018, 37, 1279−1286
15. [15]
  Xu, Z. H.; Li, C. X.; Li, G. G.; Chai, R. T.; Peng, C.; Yang D. M.; Lin, J. Self-assembled 3D urchin-like NaY(MoO₄)₂: Eu³⁺/Tb³⁺ microarchitectures: hydrothermal synthesis and tunable emission colors. J. Phys. Chem. C 2010, 114, 2573−2582. doi: 10.1021/jp9115029
16. [16]
  Nazarov, M. V.; Jeon, D. Y.; Kang, J. H.; Popovici, E. J.; Muresan, L. E.; Zamoryanskaya, M. V.; Tsukerblat, B. S. Luminescence properties of europium-terbium double activated calcium tungstate phosphor. Solid State Commun. 2004, 131, 307−311. doi: 10.1016/j.ssc.2004.05.025
17. [17]
  Moadhen, A.; Elhouichet, H.; Canut, B.; Sandu, C. S.; Queslati, M.; Roger, J. A. Evidence for energy transfer between Eu³⁺ and Tb³⁺ in aporous silicon matrix. Mater. Sci. Eng. B 2003, 105, 157−160. doi: 10.1016/j.mseb.2003.08.036
18. [18]
  Kim Annh, T.; Ngoc, T.; Thu Nga, P.; Bitch, V. T.; Long, P.; Strek, W. J. Energy transfer between Tb³⁺ and Eu³⁺ in Y₂O₃ crystals. J. Lumin. 1988, 39, 215−221. doi: 10.1016/0022-2313(88)90032-4
19. [19]
  Shi, P. L.; Xia, Z. G.; Molokeev, M. S.; Atuchin, V. V. Crystal chemistry and luminescence properties of red-emitting CsGd_1-xEu_x(MoO₄)₂ solid-solution phosphors. Dalton Trans. 2014, 43, 9669−9676. doi: 10.1039/C4DT00339J
20. [20]
  Durairajan, A.; Thangaraju, D.; Babu, S. M.; Valente, M. A. Luminescence characterization of sol-gel derived Pr³⁺ doped NaGd(WO₄)₂ phosphors for solid-state lighting applications. Mater. Chem. Phys. 2016, 179, 295−303. doi: 10.1016/j.matchemphys.2016.05.042
21. [21]
  Zhao, D.; Zhao, E. X.; Xin, X.; Li, F. F. Single-crystal structure and bond structure of Scheelite-like KGd(MoO₄)₂. Chin. J. Inorg. Chem. 2014, 30, 1143−1150.
22. [22]
  Rudowicz, C.; Karbowiak, M.; Gnutek, P.; Lewandowska, M. Comparative analysis of crystal-field parameters for rare-earth ions at monoclinic sites in AB(WO₄)₂ crystals: Ⅱ. Pr³⁺ and Nd³⁺ ions in KRE(WO₄)₂ (RE = Y or Gd), Pr³⁺ ions in M⁺Bi(XO₄)₂ (M⁺ = Li or Na and X = W or Mo), and Nd³⁺ ions in NaBi(WO₄)₂ and AgNd(WO₄)₂. J. Phys. : Condens. Matter. 2014, 26, 065501−15. doi: 10.1088/0953-8984/26/6/065501
23. [23]
  Han, S. J.; Bai, C. Y.; Zhang, B. B.; Yang, Z. H.; Pan, S. L. Synthesis, structure and optical properties of two isotypic crystals, Na₃MO₄Cl (M = W, Mo). J. Solid State Chem. 2016, 237, 14−18. doi: 10.1016/j.jssc.2016.01.009
24. [24]
  Zhao, D.; Shi, J. C.; Nie, K. C.; Zhang, R. J. Crystal structure and luminescent properties of two lithium lanthanide tungstate LiLn(WO₄)₂ (Ln = Sm, Eu). Optik. 2017, 138, 476−486. doi: 10.1016/j.ijleo.2017.02.106
25. [25]
  Postema, J. M.; Fu, W. T.; Ijdo, D. J. W. Crystal structure of LiLnW₂O₈ (Ln = lanthanides and Y): an X-ray powder diffraction study. J. Solid State Chem. 2011, 184, 2004−2008. doi: 10.1016/j.jssc.2011.05.046
26. [26]
  Han, S.; Wang, Y.; Jing, Q.; Wu, H.; Pan, S. L.; Yang, Z. H. Effect of the cation size on the framework structures of magnesium tungstate, A₄Mg(WO₄)₃ (A = Na, K), R₂Mg₂(WO)₃ (R = Rb, Cs). Dalton Trans. 2015, 44, 5810−5817. doi: 10.1039/C5DT00332F
27. [27]
  Adib, K.; Nasrabadi, M. R.; Rezvani, Z.; Pourmortazavi, S. M.; Ahmadi, F.; Naderi, H. R.; Ganjali, M. R. Facile chemical synthesis of cobalt tungstates nanoparticles as high-performance supercapacitor. J. Mater. Sci. : Mater. Electron. 2016, 27, 4541−4550. doi: 10.1007/s10854-016-4329-4
28. [28]
  Galceran, M.; Pujol, M. C.; Aguiló, M.; Díaz, F. Sol-gel modified Pechini method for obtaining nanocrystalline KRE(WO₄)₂ (RE = Gd and Yb). J. Sol-Gel. Sci. Techn. 2007, 42, 79−88. doi: 10.1007/s10971-006-1517-3
29. [29]
  Jiang, Z. H.; Cai, P. Q.; Chen, C. L.; Pu, X. P.; Kim, S.; Seo, H. J. Facile one-step hydrothermal synthesis and luminescence properties of Eu³⁺-doped NaGd(WO₄)₂ nanophosphors. Mater. Chem. Phys. 2017, 193, 227−233. doi: 10.1016/j.matchemphys.2017.02.032
30. [30]
  Zhang, F.; Xie, J.; Li, G.; Zhang, W.; Wang, Y.; Huang, Y.; Tao, Y. Cation composition sensitive visible quantum cutting behavior of high-efficiency green phosphors Ca₉Ln(PO₄)₇: Tb³⁺ (Ln = Y, La, Gd). J. Mater. Chem. C 2017, 5, 872−881. doi: 10.1039/C6TC03982K
31. [31]
  Wen, D. W.; Feng, J. J.; Li, J. H.; Shi, J. X.; Wu, M. M.; Su, Q. K₂Ln(PO₄)(WO₄): Tb³⁺, Eu³⁺ (Ln = Y, Gd and Lu) phosphors: highly efficient pure red and tunable emission for white light-emitting diodes. J. Mater. Chem. C 2015, 3, 2107−2114. doi: 10.1039/C4TC02406K
32. [32]
  Si, J. Y.; Liu, N.; Song, S. Y.; Cai, G. M.; Yang, N.; Li, Z. Investigation on Eu/Tb activated photoluminescent properties of Li₃Sc(BO₃)₂ based phosphors. J. Alloy. Compd. 2017, 719, 171−181. doi: 10.1016/j.jallcom.2017.05.161
33. [33]
  Sharma, A.; Varshney, M.; Shin, H. J.; Chae, K. H.; Won, S. O. XANES, EXAFS and photoluminescence investigations on the amorphous Eu: HfO₂ Spectrochim. Acta A 2017, 173, 549−555. doi: 10.1016/j.saa.2016.10.006
34. [34]
  Park, K.; Kim, H.; Hakeem, D. A. Effect of host composition and Eu³⁺ concentration on the photoluminescence of aluminosilicate (Ca, Sr)₂Al₂SiO₇: Eu³⁺ phosphors. Dyes Pigments. 2017, 136, 70−77. doi: 10.1016/j.dyepig.2016.08.022
35. [35]
  Zhao, D.; Ma, F. X.; Wu, Z. Q.; Zhang, L.; Wei, W.; Yang, J.; Zhang, R. H.; Chen, P. F.; Wu, S. X. Synthesis, crystal structure and characterizations of a new red phosphor K₃EuB₆O₁₂. Mater. Chem. Phys. 2016, 182, 231−236. doi: 10.1016/j.matchemphys.2016.07.027
36. [36]
  Zhang, X. W.; Zhao, Z.; Zhang, X.; Marathe, A.; Cordes, D. B.; Weeksc, B.; Chaudhuri, J. Tunable photoluminescence and energy transfer of YBO₃: Tb³⁺, Eu³⁺ for white light emitting diodes. J. Mater. Chem. C 2013, 1, 7202−7207. doi: 10.1039/c3tc31200c
37. [37]
  Liu, L.; Liang, Y. M.; Li, L. L.; Zou, L. C.; Gan, S. C. White light-emitting properties of NaGdF₄ nanotubes through Tb³⁺, Eu³⁺doping. Cryst. Eng. Comm. 2015, 17, 7754−7761. doi: 10.1039/C5CE01118C
38. [38]
  Narukawa, Y.; Ichikawa, M.; Sanga, D.; Sano, M.; Mukai, T. White light emitting diodes with super-high luminous efficacy. J. Phys. D: Appl. Phys. 2010, 43, 354002−6. doi: 10.1088/0022-3727/43/35/354002
39. [39]
  Zhang, X.; Zhang, J.; Chen, Y.; Gong, M. Energy transfer and multicolor tunable emission in single-phase Tb³⁺, Eu³⁺ co-doped Sr₃La(PO₄)₃ phosphors. Ceram. Int. 2016, 42, 13919−13924. doi: 10.1016/j.ceramint.2016.05.202
40. [40]
  Zhao, D.; Nie, C. K. Synthesis and multi-color luminescent properties of Tb³⁺/Sm³⁺-codoped K₃Gd₃B₄O₁₂ phosphor. J. Liaocheng Univ. 2019, 32, 85−89.
41. [41]
  Qin, D.; Tang, W. J. Efficient energy transfer and tunable emission in NaLa(MoO₄)(WO₄): Tb³⁺/Eu³⁺ phosphors. Ceram. Int. 2016, 42, 1538−1544. doi: 10.1016/j.ceramint.2015.09.102
42. [42]
  Zhang, X. G.; Zhou, L. Y.; Shi, J. X.; Gong, M. L. Luminescence and energy transfer of a color tunable phosphor Tb³⁺, Eu³⁺ co-doped KCaY(PO₄)₂. Mater. Lett. 2014, 137, 32−35. doi: 10.1016/j.matlet.2014.08.112
43. [43]
  Liao, J. S.; Wang, Q.; Wen, H. R.; Yuan, H. L.; Liu, S. J.; Fu, J. X.; Qiu, B. First observation of mutual energy transfer of Mn⁴⁺-Er³⁺ via different excitation in Gd₂ZnTiO₆: Mn⁴⁺/Er³⁺ phosphors. J. Mater. Chem. C 2017, 5, 9098−9105. doi: 10.1039/C7TC03045B
44. [44]
  Liao, J. S.; Kong, L. Y.; Wang, Q.; Li, J. Q.; Peng, G. H.; Sun, Y. J.; Wen, H. R. Sol-gel preparation and near-infrared emission properties of Yb³⁺ sensitized by Mn⁴⁺ in double-perovskite La₂ZnTiO₆. Opt. Mater. 2018, 84, 82−88. doi: 10.1016/j.optmat.2018.06.055
45. [45]
  Xu, D.; Zhou, W.; Zhang, Z.; Ma, X.; Xia, Z. Luminescence property and energy transfer behavior of apatite-type Ca₄La₆(SiO₄)₄(PO₄)₂O₂: Tb³⁺, Eu³⁺ phosphor. Mater. Res. Bull. 2018, 108, 101−105. doi: 10.1016/j.materresbull.2018.08.040
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Crystal Structure of Scheelite-type LiTb(WO4)2 and Multi-color Emitting Properties Doped by Eu3+

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Crystal Structure of Scheelite-type LiTb(WO₄)₂ and Multi-color Emitting Properties Doped by Eu³⁺