Citation: Jiu-Fu LU, Juan ZHAO, Cai-Bin ZHAO, Xiao-Hu YU, Kumar Roy SOUMENDRA, Si-Yu YUE, Li LI, Ke ZHOU, Ling-Xia JIN, Hong-Guang GE. A Chinese Lantern-like 2D Cu(Ⅱ) Coordination Polymer Constructed by Bis-imidazole and Dicarboxylate Co-ligands: Synthesis, Crystal Structure and Photocatalytic Activity[J]. Chinese Journal of Structural Chemistry, ;2020, 39(2): 321-328. doi: 10.14102/j.cnki.0254–5861.2011–2339 shu

A Chinese Lantern-like 2D Cu(Ⅱ) Coordination Polymer Constructed by Bis-imidazole and Dicarboxylate Co-ligands: Synthesis, Crystal Structure and Photocatalytic Activity

Shaanxi Key Laboratory of Catalysis, College of Chemical and Environment Science, Shaanxi University of Technology, Hanzhong 723001, China

Corresponding author: Ling-Xia JIN, jinlx@snut.edu.cn Hong-Guang GE, gehg@snut.edu.cn
Received Date: 2 February 2019
Accepted Date: 21 October 2019

Fund Project: the team of syngas catalytic conversion of Shaanxi University of Technology, the National Natural Science Foundation of China 21373132the team of syngas catalytic conversion of Shaanxi University of Technology, the National Natural Science Foundation of China 21603133Key scientific research project of education department of Shaanxi province 18JS023Shaanxi provincial science and technology department project 2018JM2043Shaanxi provincial science and technology department project 2019JQ149Shaanxi provincial science and technology department project 2019JM471the Science Foundation of Shaanxi University of Technology SLGQD2017-14

Figures(9)

A new Cu(Ⅱ) coordination polymer, {[Cu(1, 3-BIP)(TFBDC)]·DMF}_n (1, 1, 3-BIP is a 1, 3-bis(imidazole)propane, and H₂TFBDC is 2, 3, 5, 6-tetrafluoroterephthalic acid) was prepared under solvothermal conditions and characterized by single-crystal and powder X-ray diffraction, IR spectra, thermogravimetric analyses and elemental analyses. The single-crystal X-ray diffraction reveals that metal coordination polymer 1 (MCP 1) shows a two-dimensional sheet layer structure, which is further reinforced through strong intermolecular hydrogen bonding to form a 3D supramolecular framework. Furthermore, the photocatalytic experiment result indicates the degradation ratios of methyl orange (MO) reach 83.4% within 180 minutes when MCP 1 acts as catalyst.
- solvothermal synthesis,
- crystal structure,
- Cu(Ⅱ) coordination polymer,
- photocatalytic activity
1. [1]
  Hao, H. J.; Sun, D.; Liu, F. J.; Huang, R. B.; Zheng, L. S. Dicarboxylate-controlled three Zn(Ⅱ) coordination polymers incorporating flexible 1, 2-bis(imidazol-10-yl)ethane ligand: syntheses, structures, thermal stabilities and photoluminescent properties. J. Mol. Struct. 2012, 1012, 131–136. doi: 10.1016/j.molstruc.2011.12.030
2. [2]
  Li, P. X.; Lu, J. F. A novel 3D twofold Zn(Ⅱ) coordination polymer constructed by mixed flexible ligands: synthesis, crystal structure and fluorescence property. Chin. J. Struct. Chem. 2017, 36, 303–309.
3. [3]
  Kamal, K. B.; Yadagiri, R.; Bhavesh, P.; Eringathodi, S. Mixed ligand coordination polymers with flexible bis-imidazole linker and angular sulfonyldibenzoate: crystal structure, photoluminescence and photocatalytic activity. J. Solid State Chem. 2014, 213, 43−51. doi: 10.1016/j.jssc.2014.02.007
4. [4]
  Kamal, K. B.; Yadagiri, R.; Bhavesh, P.; Bhavesh, P.; Eringathodi, S. Structural and functional studies on ternary coordination polymers from 5-bromoisophthalate and imidazole based flexible linker. RSC Adv. 2014, 4, 7352−7360. doi: 10.1039/c3ra45411h
5. [5]
  Wang, C. C.; Li, J. R.; Lv, X. L.; Zhang, Y. Q.; Guo, G. S. Photocatalytic organic pollutants degradation in metal-organic frameworks. Energy Environ. Sci. 2014, 7, 2831−2867. doi: 10.1039/C4EE01299B
6. [6]
  Tranchemontagne, D. J.; Ni, Z.; O'Keeffe, M.; Yaghi, O. Reticular chemistry of metal-organic polyhedra. Angew. Chem. Int. Ed. 2008, 47, 5136−5147. doi: 10.1002/anie.200705008
7. [7]
  Leong, W. L.; Vittal, J. J. One-dimensional coordination polymers: complexity and diversity in structures, properties, and applications. Chem. Rev. 2011, 111, 688−764. doi: 10.1021/cr100160e
8. [8]
  Renata, L.; Halina, G.; Liliana, M.; Bogdan, T.; Vasyl, K.; Alexander, M. K. Structural diversity of alkali metal coordination polymers driven by flexible biphenyl-4, 4΄-dioxydiacetic acid. J. Solid State Chem. 2018, 265, 92−99. doi: 10.1016/j.jssc.2018.05.022
9. [9]
  Osta, R. E.; Frigoli, M.; Marrot, J.; Medina, M. E.; Walton, R. I.; Millange, F.; Fei, H.; Liu, X.; Li, Z.; Feng, W. Synthesis, structure, and crystallization study of a layered lithium thiophene-dicarboxylate. Cryst. Growth Des. 2012, 12, 1531−1539. doi: 10.1021/cg201587u
10. [10]
  Qiao, Y.; Ren, S. S.; Liu, L. H.; Guan, W. S. Adsorption and photocatalytic properties of transition metal zinc(Ⅱ) complex based on 5-(4-(tetrazol-5-yl)phenyl)isophthalic acid. J. Mol. Struct. 2018, 1161, 238−254. doi: 10.1016/j.molstruc.2018.02.049
11. [11]
  Kitagawa, S.; Kitaura, R.; Noro, S. I. Functional porous coordination polymers. Angew. Chem. Int. Ed. 2004, 43, 2334−2375. doi: 10.1002/anie.200300610
12. [12]
  Zhang, Z. J.; Shi, W.; Niu, Z.; Li, H. H.; Zhao, B.; Cheng, P.; Liao, D. Z.; Yan, S. P. A new type of polyhedron-based metal-organic frameworks with interpenetrating cationic and anionic nets demonstrating ion exchange, adsorption and luminescent properties. Chem. Commun. 2001, 47, 6425−6427.
13. [13]
  Lu, J. F.; Min, S. T.; Ge, H. G. Synthesis, crystal structures and properties of two-dimensional complexes constructed by dicarboxylate and bis(imidazole) co-ligands. J. Chem. Res. 2014, 38, 726−730. doi: 10.3184/174751914X14176001751990
14. [14]
  Lu, J. F.; Liu, J.; Ge, H. G.; Jiang, M. Synthesis, structure and luminescent property of a 2D Cd(Ⅱ) coordination polymer based on mixed ligands of 1, 3-bis(imidazol)propane and pyridine-3, 5-dicarboxylic acid. Chin. J. Struct. Chem. 2015, 34, 248−252.
15. [15]
  Lu, J. F.; Xu, Y. H.; Li, P. A.; Jin, L. X.; Zhao, C. B.; Guo, X. H.; Ge, H. G. Synthesis, crystal structure, and luminescent properties of Ag(Ⅰ) coordination polymer with tricarboxylic acid and flexible N-donor ligand. Crystallogr. Rep. 2017, 2, 1046−1050.
16. [16]
  Wang, Z. J.; Qin, L.; Zhang, X.; Chen, J. X.; Zheng, H. G. Syntheses, characterizations, luminescent properties, and controlling interpenetration of five metal-organic frameworks based on bis(4-(pyridine-4-yl)phenyl)amine. Cryst. Growth Des. 2015, 44, 4670–4679.
17. [17]
  Zhang, Z. H.; Yang, X. S.; Guo, W.; Chen, S. C.; He, M. Y.; Chen, Q. Positional isomeric effect on Cu^Ⅱ and Cd^Ⅱ complexes based on perfluorinated dicarboxylate ligands and bipyridyl co-tectons. Polyhedron 2016, 117, 695–702. doi: 10.1016/j.poly.2016.07.015
18. [18]
  Li, X. Y.; Han, C. X.; Yue, K. F.; Liu, Y. L.; Zhou, C. S.; Hou, Y. F.; He, T.; Yan, T. Syntheses, structures and properties of three 4-fold interpenetration coordination polymers based on two different dia interpenetrating modes. Polyhedron 2015, 87, 156–162. doi: 10.1016/j.poly.2014.11.019
19. [19]
  Perry, J. J.; Perman, J. A.; Zaworotko, M. J. Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks. Chem. Soc. Rev. 2009, 38, 1400−1417. doi: 10.1039/b807086p
20. [20]
  Ji, X. H.; Zhao, J.; Lu, J. F.; Ji, L. X.; Ge, H. G. Synthesis, Crystal Structure and Biological Activity of 1-(3-Amino-4-morpholino-1H-indazole-1-carbonyl)-N-(4-fluorophenyl)cyclopropane-1-carboxamide. Chin. J. Struct. Chem. 2019, 38, 1889−1894.
21. [21]
  Li, H. J.; He, Y. L.; Zhao, W. L.; Li, Q. Q.; Xu, Z. Q.; Wang, Y. Designing different functional frameworks from 0D to 3D for exploring structural correlation with photocatalytic activity. Polyhedron 2017, 133, 412−418. doi: 10.1016/j.poly.2017.05.009
22. [22]
  Yu, Q.; Ren, S. S.; Liu, L. H.; Guan, W. S. Adsorption and photocatalytic properties of transition metal zinc(Ⅱ) complex based on 5-(4-(tetrazol-5-yl)phenyl)isophthalic acid. J. Mol. Struct. 2018, 1161, 238−245. doi: 10.1016/j.molstruc.2018.02.049
23. [23]
  Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997.
24. [24]
  Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.
25. [25]
  Zhao, S.; Zheng, T. R.; Shi, L. L.; Li, K.; Li, B. L.; Li, H. Y. Two intriguing hydroxy-copper(Ⅱ) coordination polymers with bis(triazole) and bicarboxylate ligands: syntheses, structures and photocatalytic degradation of organic dyes. J. Mol. Struct. 2017, 1143, 146−152. doi: 10.1016/j.molstruc.2017.04.087
26. [26]
  Wang, F.; Liu, Z. S.; Yang, H.; Tan, Y. X.; Zhang, J. Hybrid zeolitic imidazolate frameworks with catalytically active TO₄ building blocks. Angew. Chem. Ed. Int. 2011, 50, 450−453. doi: 10.1002/anie.201005917
27. [27]
  Lu, J. F.; Wang, M. Z.; Liu, Z. H. Two novel coordination polymers constructed by the same mixed ligands of 1, 3-bip and H₂bpdc: syntheses, structures and catalytic properties. J. Mol. Struct. 2015, 1098, 41−46. doi: 10.1016/j.molstruc.2015.05.030
28. [28]
  Lu, J. F.; Jin, L. X.; Song, J.; Zhao, C. B.; Yue, S. Y.; Li, L.; Yang, H. T.; Cao, X. Y.; Ge, H. G. A novel 3D metal coordination polymer based on tetranuclear cobalt cluster building blocks: synthesis, crystal structure and photocatalytic property. Chin. J. Struct. Chem. 2018, 37, 1814−1820.
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