Citation: Shuai Yuan, Yaofeng Yuan. Academician Chengye Yuan and Organic Phosphorus Chemistry[J]. University Chemistry, ;2025, 40(7): 393-400. doi: 10.12461/PKU.DXHX202409123 shu

Academician Chengye Yuan and Organic Phosphorus Chemistry

Shuai Yuan ,
Yaofeng Yuan

College of Chemistry, Fuzhou University, Fuzhou 350108, China

Received Date: 27 September 2024
Revised Date: 16 January 2025

Yuan Chengye is the pioneer in the field of extractant chemistry in China. In response to national defense needs such as the “Two Bombs, One Satellite” program, he successfully developed key extractants, including P204 (bis(2-ethylhexyl)phosphoric acid ester) and P350 (methylphosphonic acid dimethylheptyl ester). He also developed various phosphorus extractants, such as P507 (2-ethylheptylphosphonic acid-2-ethylheptyl ester), based on the comprehensive utilization of non-ferrous metals. Mr. Yuan Chengye’s team conducted extensive research on the structure and performance of extractants, based on a large amount of experimental data. Through in-depth analysis using quantum chemistry, molecular mechanics, thermodynamics, and other testing methods, they enhanced the chemical properties of organic phosphorus extractants to a new level. These studies provide a solid theoretical foundation for the design and optimization of extractants and have also advanced industrial applications.
- Organic phosphorus chemistry,
- Extractant,
- Scientist spirit,
- Nuclear fuel
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
  Yuan, C. Y. Some Problems in Chemical Structures and Properties of Organic Extractants. Proceedings of the International Solvent Extraction Conference, Liege, Belgium, Sept 6–12, 1980; Assoc. des Ingénieurs Sortis de l'Univ.: Liège, Belgium, 1980.
8. [8]
  Li, D. J. Rare Earths 2019, 37 (5), 468.
9. [9]
10. [10]
  Li, J. J. Michaelis–Arbuzov phosphonate synthesis. In Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications; Li, J. J. Ed.; Springer: Berlin and Heidelberg, Germany, 2009; pp. 357–358.
11. [11]
12. [12]
13. [13]
  Yuan, C. Y.; Ding, Y. Y. Acta Chim. Sin. 1987, 5 (1), 73.
14. [14]
  Ma, E. X.; Yan, J. Y.; Wang, S. Y.; Long, H. Y.; Yuan, C. Y. Sci. China Math. 1981, 29 (9), 1237.
15. [15]
  Ma, E. X.; Yan, J. Y.; Wang, G. L.; Yuan, C. Y. Chin. Sci. Bull. 1980, 25 (11), 911.
16. [16]
17. [17]
18. [18]
  Yuan, C. Y.; Yan, J. Y.; Feng, H. Z.; Long, H. Y.; Wu, F. B.; Jin, P. L. Sci. China Ser. B 1987, No. 7, 681.
19. [19]
  Li, S. S.; Cheng, Z. Y.; Yuan, C. Y. Sci. China Ser. B 1989, No. 10, 1172.
20. [20]
21. [21]
1. [1]
  Fengxiao Wang , Zhiwei Miao , Yaofeng Yuan . 有机磷化学与化学教学. University Chemistry, 2025, 40(8): 158-168. doi: 10.12461/PKU.DXHX202410077
2. [2]
  Sifang Zhang , Yanli Tan , Yu Tao , Jiaoyan Zhao , Haihong Zhu . Exploration and Practice of Ideological and Political Cases in the Course of Chemistry History and Methodology. University Chemistry, 2024, 39(10): 377-388. doi: 10.12461/PKU.DXHX202312067
3. [3]
  Jianguo Wang . Patriotic Dedication of Professor Li Zheng-Ming: Reflections from the Establishment of the Li Zheng-Ming Scholarship. University Chemistry, 2025, 40(11): 391-396. doi: 10.12461/PKU.DXHX202412089
4. [4]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
5. [5]
  Junyuan Zhang , Zhiwei Miao . 有机磷杀虫剂的前世今生. University Chemistry, 2025, 40(6): 129-138. doi: 10.12461/PKU.DXHX202408118
6. [6]
  Zhanxiang Liu , Chengshan Yuan , Jie Han , Shuanglian Cai , Qihan Zhang , Lin Wu , Yuan Zheng , Xingwen Sun , Qingwen Liu , Ying Xiong , Guangao Yu , Xin Du , Houjin Li , Jianrong Zhang , Shuyong Zhang . Recommendations for Basic Operations and Standards for Organic Chemical Extraction and Washing Experiments. University Chemistry, 2025, 40(5): 55-65. doi: 10.12461/PKU.DXHX202410039
7. [7]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
8. [8]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . Research Progress on Carbon-based Catalysts for Catalytic Dehydrogenation of Liquid Organic Hydrogen Carriers. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-0. doi: 10.1016/j.actphy.2024.100044
9. [9]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-0. doi: 10.1016/j.actphy.2025.100086
10. [10]
  Mian Wei , Chang Cheng , Bowen He , Bei Cheng , Kezhen Qi , Chuanbiao Bie . Inorganic-organic CdS/YBTPy S-scheme photocatalyst for efficient hydrogen production and its mechanism. Acta Physico-Chimica Sinica, 2025, 41(12): 100158-0. doi: 10.1016/j.actphy.2025.100158
11. [11]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
12. [12]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
13. [13]
  Wenjun Zhu , Chenbin Ai , Kaiqiang Xu , Yatai Zhou , Xidong Zhang , Yong Zhang . WO₃@TP inorganic@organic S-scheme photocatalyst for boosting H₂O₂ production. Acta Physico-Chimica Sinica, 2026, 42(3): 100184-0. doi: 10.1016/j.actphy.2025.100184
14. [14]
  Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
15. [15]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
16. [16]
  Yachao HUANG , Chuanwang ZENG , Guiyong LIU , Jinming ZENG , Chao LIU , Xiaopeng QI . Oxygen vacancies and phosphorus doping enhanced metal-organic framework derived nitrogen-doped carbon-coated Co₃O₄ bifunctional electrocatalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2251-2260. doi: 10.11862/CJIC.20250133
17. [17]
  Yong Wang , Yingying Zhao , Boshun Wan . Analysis of Organic Questions in the 37th Chinese Chemistry Olympiad (Preliminary). University Chemistry, 2024, 39(11): 406-416. doi: 10.12461/PKU.DXHX202403009
18. [18]
  Yongjian Zhang , Fangling Gao , Hong Yan , Keyin Ye . Electrochemical Transformation of Organosulfur Compounds. University Chemistry, 2025, 40(5): 311-317. doi: 10.12461/PKU.DXHX202407035
19. [19]
  Xipu He , Wengui Duan , Guishan Lin . Reform and Practice of Organic Chemistry Teaching for Non-Chemistry Major under the Four New Construction: Taking the Organic Chemistry Course Reform of Biological Science Major at Guangxi University as an Example. University Chemistry, 2025, 40(7): 42-47. doi: 10.12461/PKU.DXHX202408021
20. [20]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(744)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142