Citation: WANG Xin-Mei, XU Gui-Ju, WANG Xiao-Li, WANG Xia, WANG Ming-Lin, ZHAO Ru-Song, LIN Jin-Ming. Melamine/o-Phthalaldehyde Covalent Organic Frameworks for Solid Phase Extraction-Liquid Chromatography-Tandem Mass Spectrometry Analysis of Sulfonamide Antibiotics in Environmental Samples[J]. Chinese Journal of Analytical Chemistry, ;2018, 46(12): 1990-1996. doi: 10.11895/j.issn.0253-3820.181416 shu

Melamine/o-Phthalaldehyde Covalent Organic Frameworks for Solid Phase Extraction-Liquid Chromatography-Tandem Mass Spectrometry Analysis of Sulfonamide Antibiotics in Environmental Samples

1.
College of Food Science and Engineering, Shandong Agricultural University, Taian 271018, China;
2.
Analysis and Test Center, Shandong Academy of Sciences, Jinan 250014, China;
3.
Department of Chemistry, Tsinghua University, Beijing 100084, China

Received Date: 22 June 2018
Revised Date: 17 July 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21777089), the Natural Science Foundation of Shandong Province (No. ZR2018MB040), the Key Research and Development Program of Shandong Province (Nos. 2017GSF17107, 2018GSF117036), and the Taishan Scholar Special Foundation of Shandong Province, China (No.ts201712063).

In this work, melamine/o-phthalaldehyde covalent organic framework was used as a novel trapping media in solid-phase extraction of sulfonamides at ultra-trace levels in real water samples. Six sulfonamides, including sulfadiazine (SDZ), sulfathiazole (ST), sulfapyridine (SPD), sulfamethyldiazine (SM1), sulfamethazine (SM2), sulfamethoxazole (SMX), were absorbed on the SPE cartridge. Important factors affecting extraction effect were optimized by single factor optimization method, and the optimized relevant parameters were as follows:eluent and its volume, 8 mL MA; sample flow rate, 3 mL/min; sample pH, pH=4 and sample volume, 200 mL. Sulfonamide antibiotics were detected and quantified by liquid chromatography-tandem mass spectrometry. Low limits of detection (0.05-0.36 ng/L), wide linearity range (0.25-1000 ng/L), good repeatability and high recovery (82.5%-104.8%) for sulfonamides were obtained under the optimized conditions. The optimized method was used in the analysis of sulfonamides in real environmental water samples (drinking water, tap water and pool water) successfully. The novel COFs as a solid phase trapping material was a good choice for the rapid and effective analysis of sulfonamides at ultra trace levels in environmental water samples.
- Covalent organic frameworks,
- Solid phase extraction,
- Sulfonamides,
- Liquid chromatography-tandem mass spectrometry,
- Environmental water sample
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