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Citation: WANG Yi-Fei, ZHOU Li-Jun, YANG Ji, MENG Zi-Hui, XUE Min, QIU Li-Li, LIU Xue-Yong, HE Xuan, ZHONG Fa-Chun. Detection of Sulfur Dioxide Using Cellulose Photonic Crystal Membrane[J]. Chinese Journal of Analytical Chemistry, ;2018, 46(9): 1472-1478. doi: 10.11895/j.issn.0253-3820.181044 shu

Detection of Sulfur Dioxide Using Cellulose Photonic Crystal Membrane

WANG Yi-Fei ^1, ,
ZHOU Li-Jun ¹ ,
YANG Ji ¹ ,
MENG Zi-Hui ¹ ,
XUE Min ¹ ,
QIU Li-Li ¹ ,
LIU Xue-Yong ² ,
HE Xuan ² ,
ZHONG Fa-Chun ²

1.
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China;
2.
Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, China

Received Date: 21 January 2018
Revised Date: 25 June 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (Nos. U1530141, 21375009).

Sulfur oxide is one of the most concerned air pollutants. Current detection technique for sulfur oxide is complicated, and in situ techniques are in highly demand. Herein, 3D polymethyl methacylate colloidal arrays which were embedded inside methylcellulose (MC) and carboxymethylcellulose (CMC) membrane were prepared, and then opal and inverse opal cellulose photonic crystal with bright structural color were obtained. After treated with dimethyl sulfoxide (DMSO), the structural color of the inverse opal cellulose photonic crystal turned from red to colorless, and the naked-eye detection for SO₂ was achieved with a detection limit of lower than 7898 mg/m³. This technique might be useful for the in situ detection of SO₂ pollutant in the air.
- Photonic crystal,
- Chemical sensor,
- Carboxymethylcellulose,
- Sulfur dioxide,
- Dimethyl sulfoxide
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