Citation: WANG Xiao-Meng, ZHANG Zhen, LIU Jing, ZHANG Shu-Sheng. Stable Cu₂O@Au for Accurate and Rapid Surface Enhancement Raman Scattering Analysis of Rhodamine B[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(12): 2026-2031. doi: 10.11895/j.issn.0253-3820.171314 shu

Stable Cu₂O@Au for Accurate and Rapid Surface Enhancement Raman Scattering Analysis of Rhodamine B

Linyi University, Linyi 276005, China

Corresponding author: ZHANG Shu-Sheng, shushzhang@126.com
Received Date: 10 October 2017
Accepted Date: 7 November 2017

Fund Project: the National Natural Science Foundation of China 21645001the National Natural Science Foundation of China 21775061the National Natural Science Foundation of China 21705070This work was supported by the National Natural Science Foundation of China (Nos. 21645001, 21705070, 21405071, 21775061)the National Natural Science Foundation of China 21405071

Figures(7)

A simple and efficient method for fabricating a novel surface-enhanced Raman scattering (SERS) substrate with good reproducibility and high SERS activity was reported. Cu₂O was prepared by mixing CuCl₂·2H₂O with ascorbic acid, which was then used as the templates for depositing of gold nanoparticles (AuNPs) on their surfaces, forming Cu₂O@Au with heterostructures. Transmission electron microscopy, scanning electron microscopy and X-ray diffraction observation revealed that Cu₂O had polyhedral structure and smooth surface, and AuNPs were closely deposited on the surface of Cu₂O. It was used as SERS substrate for detection of Rhodamine B with linear detection range of 1×10^-2-5×10^-6 mol/L, and detection limit of 3×10^-7 mol/L. Cu₂O@Au showed good chemical stability, remained stable in acid, PBS and river samples, and could be used in the SERS detection of target in water sample.
- Cuprous oxide,
- Gold nanoparticles,
- Surface-enhanced Raman scattering,
- Rhodamine B
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Stable Cu₂O@Au for Accurate and Rapid Surface Enhancement Raman Scattering Analysis of Rhodamine B