Citation: ZHANG Yong, LIU Jin-Feng, YI Run-Hao, AI Si-Fan, CHENG Huan-Ren, JIA Wen-Zhi. Synthesis and Application of A Flavone-based Fluorescent Probe for Detection of Hydrazine[J]. Chinese Journal of Analytical Chemistry, ;2018, 46(4): 511-516. doi: 10.11895/j.issn.0253-3820.171222 shu

Synthesis and Application of A Flavone-based Fluorescent Probe for Detection of Hydrazine

1.
College of Chemistry and Chemical Engineering, Hubei Polytechnic University, Huangshi 435003, China;
2.
College of Science, Tianjin University of Science and Technology, Tianjin 300457, China

Received Date: 4 September 2017
Revised Date: 26 January 2018

Fund Project: This work was supported by the National Natural Science Foundation of China (No.21603069), Young College Teachers' Entering into Enterprises Program of Hubei Provincial Department of Education (No.XD2014677) and College Students' Science and Technology Innovation Project of Hubei Polytechnic University(No.17cx08).

A fluorescence enhancement probe (ZY8) for the detection of N₂H₄ was designed and synthesized by employing 3-hydroxyflavone as a fluorophore, and its spectral properties had been investigated. The results showed that ZY8 had relatively good selectivity and specificity to N₂H₄ in Tris-HCl-ethanol solution (9:1, V/V, pH 7.40). The fluorescent intensity of ZY8 exhibited good linear relationship with concentration of N₂H₄ in the concentration range of 1.6×10^-7 mol/L-6.2×10^-5 mol/L, and its detection limit was estimated to be 1.6×10^-7 mol/L. ZY8 itself had weak fluorescence, upon addition of N₂H₄, an approximate 9-fold fluorescence enhancement was observed, and the color of the solution changed from light grayish green to bright grass-green at UV light of 365 nm. So ZY8 might be used to the visual recognition of N₂H₄. ZY8 could detect N₂H₄in near-physiological pH range, and it had fast response and strong anti-interference ability. Moreover, ZY8 could be loaded as test paper for naked-eye detection of N₂H₄ at mmol/L level in water solution, and it was also applied in the determination of N₂H₄ in various water samples by the standard addition recovery experiments, with the recovery ratio ranged from 96.0% to 104.2%%, and RSD of all < 4%. The results of this study demonstrated that ZY8 had potential application to the detection of N₂H₄ in the monitoring of environmental pollution.
- Hydrazine,
- Fluorescent probe,
- 3-Hydroxyflavone
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沈阳化工大学材料科学与工程学院沈阳 110142