Citation: YUAN Xiao-Xue, JIANG Yang, YANG Chang-Xiao, XIE Bi-Jun, YONG Li, HU Bin, LIU Tao. Determination of 16 Kinds of Polycyclic Aromatic Hydrocarbons in Atmospheric Fine Particles by Accelerated Solvent Extraction Coupled with High Performance Liquid Chromatography[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(11): 1641-1647. doi: 10.11895/j.issn.0253-3820.170262 shu

Determination of 16 Kinds of Polycyclic Aromatic Hydrocarbons in Atmospheric Fine Particles by Accelerated Solvent Extraction Coupled with High Performance Liquid Chromatography

Sichuan Center for Disease Control and Prevention, Institute of Physicochemical Detection, Chengdu 610041, China

Received Date: 26 April 2017
Revised Date: 4 September 2017

A method for determination of 16 kinds of polycyclic aromatic hydrocarbons (PAHs) in atmospheric fine particles (PM2.5) was developed based on accelerated solvent extraction-direct injection coupled with high performance liquid chromatography (HPLC). PM2.5 was collected by glass fiber membrane filter and pretreated with acetonitrile by accelerated solvent extraction. The extract was separated by ZORBAX Eclipse PAH column with acetonitrile and water as mobile phase, and detected by ultraviolet and fluorescence detectors. The result showed that the 16 kinds of PAHs were well separated and there were good linear relationships (r ≥ 0.9998) in the concentration range of 0.025-5.00 μg/mL. The recoveries were from 78.3% to 113.2%. The relative standard deviations ranged from 0.5% to 9.5%. The detection limits were 0.007-0.062 ng/m³. The method was simple, rapid, accurate and sensitive, and suitable for the simultaneous determination of 16 kinds of PAHS in PM2.5.
- Accelerated solvent extraction,
- Atmospheric fine particles,
- Polycyclic aromatic hydrocarbons,
- High performance liquid chromatography
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