Citation: WANG Yu-Jiao, NIE Ji-Yun, YAN Zhen, LI Zhi-Xia, CHENG Yang, ZHANG Xiao-Nan. Simultaneous Determination of 16 Kinds of Mycotoxins in Common Dried Fruits by Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(10): 1556-1563. doi: 10.11895/j.issn.0253-3820.170186 shu

Simultaneous Determination of 16 Kinds of Mycotoxins in Common Dried Fruits by Ultra Performance Liquid Chromatography-Tandem Mass Spectrometry

Institute of Pomology, Chinese Academy of Agricultural Sciences/Laboratory of Quality & Safety Risk Assessment for Fruit(Xingcheng), Ministry of Agriculture, Xingcheng 125100, China

Received Date: 24 March 2017
Revised Date: 14 July 2017

Fund Project: This work was supported by the National Program for Quality and Safety Risk Assessment of Agricultural Products of China (Nos. GJFP2016003、GJFP2017003) and the Scientific and Technological Innovation Project of the Chinese Academy of Agricultural Sciences (No. CAAS-ASTIP).

A method for simultaneous detection of multi-mycotoxins in ten kinds of common dried fruits was been exploited by using ultra performance liquid chromatography-tandem mass spectrometry. The edible part of dried fruits was ground up with certain quantity of water. The mash was extracted by 10 mmol/L citric acid-acetonitrile, purified by C₁₈ column, and filtered using 0.22-μm organic filtration. All the sixteen mycotoxins were well separated in 8 min on ACQUITY UPLC BEH C₁₈ column with acetonitrile as phase A and 10 mmol/L ammonium acetate solution containing 0.1% formic acid as mobile phase B. Result showed that the limits of detection (LODs) for the sixteen mycotoxins were 0.01-1.00 μg/L, with linearity range of 1-200 μg/L and correlation coefficients above 0.9981. The average recoveries of the sixteen mycotoxins in ten matrices were 70.48%-118.85%, and the relative standard deviation (RSD, n=6) was 0.3%-11.9%. This economical, fast, simple and efficient method could be used for simultaneous detection of multi-mycotoxins in different dried fruits matrixes.
- Mycotoxins,
- Ultra high performance liquid chromatography-tandem mass spectrometry,
- Dried fruits
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