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Citation: LIU Feng-Xian, BI Xin-Hui, REN Zhao-Fang, ZHANG Guo-Hua, WANG Xin-Ming, PENG Ping-An, SHENG Guo-Ying. Determination of Amines in Particulate Matter by Gas Chromatography-Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2017, 45(4): 477-482. doi: 10.11895/j.issn.0253-3820.170086 shu

Determination of Amines in Particulate Matter by Gas Chromatography-Mass Spectrometry

1.
State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 18 January 2017
Revised Date: 17 February 2017

Fund Project: This work was supported by the Major Research Plan of the National Natural Science Foundation of China (No.91544101)

A method was developed for determination of thirteen amines including seven aliphatic amines, two heterocyclic amines and four aromatic amines in atmospheric particulate matter (PM) by gas chromatography-mass spectrometry (GC-MS). Samples were ultrasonically extracted with ultra-pure water and derivatized with benzenesulfonyl chloride (BSC) under alkaline conditions. The derivatives were extracted with dichloromethane and then detected by GC-MS using DB-5MS chromatographic column. The method detection limit (S/N=3) and quantitation limit (S/N=10) were 0.00008-0.017 μg/mL and 0.00026-0.0565 μg/mL respectively, and the correlation coefficients were 0.9903-0.9996, which indicated that the standard curve had good linear correlation. In addition, the relative standard deviation was less than 30% and the average recovery was 54.4%-159.7% except for methylamine and benzylamine at spiked level of 1.0 μg/mL, showing high precision and accuracy. 9 kinds of amines were detected in the PM2.5 samples collected in Guangzhou city by this method, among which dimethylamine and butylamine accounted for 90% of the total nine amines, which indicated that they were primary amines in PM2.5; while propylamine exhibited the lowest level in PM2.5 with the concentration less than 1.0 ng/m³.
- Atmospheric particulates,
- Amines,
- Gas chromatography-mass spectrometry
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