Citation: JIANG Dan-Dan, PENG Li-Ying, ZHOU Qing-Hua, CHEN Chuang, LIU Ji-Wei, WANG Shuang, LI Hai-Yang. Quantitative Detection of Hexamethylene Triperoxide Diamine in Complex Matrix Using Ion Mobility Spectrometer by Dopart-assisted Photoionization Ion Mobility Spectrometry[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(11): 1671-1678. doi: 10.11895/j.issn.0253-3820.160298 shu

Quantitative Detection of Hexamethylene Triperoxide Diamine in Complex Matrix Using Ion Mobility Spectrometer by Dopart-assisted Photoionization Ion Mobility Spectrometry

JIANG Dan-Dan ^1,2, ,
PENG Li-Ying ^1,2 ,
ZHOU Qing-Hua ^1,2 ,
CHEN Chuang ¹ ,
LIU Ji-Wei ¹ ,
WANG Shuang ^1,2 ,
LI Hai-Yang ¹

1.
Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
2.
University of Chinese Academy of Sciences, Beijing 100039, China

Received Date: 15 April 2016
Revised Date: 28 June 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21177124) and the State Key Laboratory of NBC Protection for Civilian (No. SKLN BC 2012-08K)

Hexamethylene triperoxide diamine (HMTD), as one kind of new organic peroxide explosives, was often used in the terrorist attacks due to its easy synthesis from available starting materials. Herein, on the basis of nonradioactive ionization source vacuum ultraviolet lamp (VUV), a dopant-assisted positive photoionization ion mobility spectrometer was developed for the determination of HMTD. Toluene and ketones such as acetone, and 2-butanone, were tested as dopants, and acetone was finally chosen as the optimal dopant for the quantitative detection of HMTD in perfume. With mass spectrometer, the reactant ions and the product ions of HMTD were assigned. The reactant ions of acetone were proton dimer m/z 117[(CH₃)₂CO]₂H⁺, while the product ions of HMTD were proton molecular ion m/z 209[HMTD+H]⁺. When both the drift tube and the thermal desorber temperature was under 120℃, the HMTD standard samples were quantified with the maximum signal intensity and the signal intensity at the 10th second, the linear range was 5-50 ng/μL and 5-100 ng/μL, and the limit of detection (LOD) was 0.2 and 0.3 ng/μL, respectively. Cosmetics such as perfume often interfered and inhibited the measurement of ion mobility spectrometry, so the detection of HMTD in perfume matrix for the rapid screening and detection of HMTD on-site was of realistic significance. These two quantitative methods were used for the quantitative detection of HMTD in three different brands of perfume samples. By comparison, the method using the 10th second signal intensity of HMTD for the quantitative detection had a better recovery and accuracy. This method was suitable for the accurate and rapid quantitative detection of HMTD in complex matrix.
- Ion mobility spectrometry,
- Peroxide explosives,
- Hexamethylene triperoxide diamine,
- Complex matrix,
- Perfume
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