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Citation: SHENG Cun-Cun, ZHANG Shi-Juan, WANG Fang-Fang, JI Zhong-Yin, DOU Kun, YOU Jin-Mao. Determination of Aliphatic Amines in Infant Food Packaging Materials by High Performance Liquid Chromatography[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(9): 1365-1371. doi: 10.11895/j.issn.0253-3820.160277 shu

Determination of Aliphatic Amines in Infant Food Packaging Materials by High Performance Liquid Chromatography

1.
Shandong Province Key Laboratory of Life-Organic Analysis, Key Laboratory of Pharmaceutical Intermediates and Analysis of Natural Medicine, College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
2.
Northwest Institute of Plateau Biology, Chinese Academy of Sciences, Xining 810001, China

Received Date: 9 April 2016
Revised Date: 26 June 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (No.21275089) and the Natural Science Foundation of Shandong Province, China (No. ZR2014BQ009)

Figures(3)

Aliphatic amines in infant food packaging materials were extracted and concentrated by 0.5 mL of acidified methanol using gas purge microsyringe extraction (GP-MSE). Pre-column fluorescence labeling of amines was achieved in mild conditions with 10-ethyl-acridine-2-sulfonyl chloride (EASC) as labeling reagent. The derivatization was carried out at 60℃ and pH 10. The derivatives were successfully separated on a Hypersil GOLD column with excitation and emission wavelengths of 262 and 430 nm, respectively. The detection limits were in the range of 0.4-0.6 μg/kg, and the quantitation limits were in the range of 1.2-2.1 μg/kg. All analytes were in good linearity in the concentration range of 2.0-2000 μg/L with correlation coefficients of higher than 0.998. The developed method was characterized by celerity, accuracy and high sensitivity. It was successfully applied to the determination of aliphatic amines in infant food packaging materials.
- High performance liquid chromatography,
- Gas purge-microsyringe extraction,
- Packaging materials of baby food,
- Fluorescence detection
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