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Citation: WANG Jia-Ni, ZHANG Han, HONG Zhen-Yu, Xu Hui, ZHANG Xian, CHEN Jin-Sheng. Analysis of Volatile Organic Compounds by Specific Carbon Stable Isotope[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(9): 1342-1347. doi: 10.11895/j.issn.0253-3820.160153 shu

Analysis of Volatile Organic Compounds by Specific Carbon Stable Isotope

Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China

Received Date: 3 March 2016
Revised Date: 15 June 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21207126)

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The δ¹³C values of volatile organic compounds (VOCs) in various emission sources and ambient air were analyzed by using thermal desorption coupled with gas chromatography and isotope ratio mass. The lowest sample concentration and peak shape quality needed for high precision and accurate analysis were investigated. Fuel evaporation (gasoline and diesel), vehicle exhaust, solvent evaporation, dining fumes and ambient air of different functional zones of Xiamen city were collected using Tenax TA tube, and the significant differences in δ¹³C values of VOCs between these sources were observed. The δ¹³C value of gasoline exhaust (97^#) was heavier (-25.84‰) than that of dining fumes (-30.26‰) and the δ¹³C values of fuel evaporation were heavier than that of vehicle exhaust after combustion. The average δ¹³C value of atmospheric VOCs in Xiamen was at the level of -27.03‰ to -25.40‰, which was close to the δ¹³C value of the evaporation and exhaust of gasoline and diesel, indicating that the VOCs in the atmosphere of Xiamen was highly influenced by transportation related sources.
- Compound specific carbon stable isotope,
- Volatile organic compounds,
- Thermal desorption
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