Citation:
YAO Ru-Jiao, HE Yang, XIAO Yu, DING Zheng-Zhi, YUAN Guang-Zhou, ZHANG Zai-Yue, QIAN Jie, ZHANG Shu-Guang, LI Xiao-Xu. Optimization of Linear Ion Trap Mass Analyzer with Triangular Electrodes by Simulation[J]. Chinese Journal of Analytical Chemistry,
;2016, 44(11): 1793-1797.
doi:
10.11895/j.issn.0253-3820.150978
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As a novel linear ion trap, the triangular-electrode linear ion trap (TeLIT) has simple structure and good performance. The relationship between its geometry and performance was investigated. Ion trajectories and mass peaks of TeLIT with different ratios of field radius (rx/ry) were analyzed by using simulation software SIMION and AXSIM. It was shown that the performance of the TeLIT could be enhanced by optimizing rx/ry which would improve internal electric fields distribution. The optimum mass resolution of 8387 was achieved for ions with m/z 1892 Th at rx/ry=5.75/5 when scan rate was 1500 Th/s. When the scan rate was decreased to about 300 Th/s, the resolving power of the mass spectrum was in excess of 23000.
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