Citation: WEI Xiao-Ping, LIANG Shun-Chao, HUANG Wen-Gang, LI Jian-Ping. Study on Molecularly Imprinted Sensor Based on Photocurrent Response for Ni-complex[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(3): 348-354. doi: 10.11895/j.issn.0253-3820.150918 shu

Study on Molecularly Imprinted Sensor Based on Photocurrent Response for Ni-complex

1.
Electromagnetic Functional Material Key Laboratory in Guangxi, Guilin University of Technology, College of Chemistry and Bioengineering, Guilin 541004, China

Corresponding author: LI Jian-Ping,
Received Date: 16 October 2015
Available Online: 24 November 2015
Fund Project: 本文系国家自然科学基金(No.21375031) (No.21375031)广西自然科学基金(Nos.2015GXNSFFA139005,2015GXNSFAA139029)项目资助 (Nos.2015GXNSFFA139005,2015GXNSFAA139029)

A novel molecularly imprinted sensor for Ni²⁺ detection was fabricated based on photocurrent method. CdTe quantum dot (QDs) was selected as photoelectric material and modified in ITO electrode, then the nickel-1-(2-pyridylazo)-2-naphthol molecularly imprinted film was formed on the QDs layer by photopolymerization. By using 365 nm ultraviolet light as excitation light, the QDs generated electron-hole, and the electron donor-ascorbic acid combined with electron to form the photocurrent signals. Based on this evidence, Ni²⁺ was detected according to "gate-effect". The complex was characterized by Fourier transform infrared spectrum and the CdTe QDs was characterized by ultraviolet absorption spectrum and fluorescence emission spectrum, the time for elution and rebinding and the concentration of ascorbic acid in base solution were optimized. The experiment showed that there was a liner relationship between the photocurrent and the concentration of Ni²⁺ at 5×10^-11-5×10^-8 mol/L, with the detection limit of 8.3×10^-12 mol/L. The sensor also had good selectivity, and it was applied in real water samples analysis.
- Molecularly imprinted sensor,
- Photocurrent,
- Nickel-1-(2-pyridylazo)-2-naphthol,
- Quantum dot,
- Nickel ion
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沈阳化工大学材料科学与工程学院沈阳 110142