Citation: MA Yun-Qi, PENG Zhang-Kuang, CHEN Yan-Jiao, YANG Jian, XIAO Ying-Kai, ZHANG Yan-Ling. High Precise Determination of Bromine Isotopic Ratios by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs₂Br⁺ Ions[J]. Chinese Journal of Analytical Chemistry, ;2016, 44(2): 186-191. doi: 10.11895/j.issn.0253-3820.150728 shu

High Precise Determination of Bromine Isotopic Ratios by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs₂Br⁺ Ions

1.
¹ Laboratory of Salt Lake Geology and Environment, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China;
2.
² Salt Lake Chemical Analyzing and Testing Center, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China;
3.
³ University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: MA Yun-Qi,
Received Date: 14 September 2015
Available Online: 9 November 2015
Fund Project: 本文系国家自然科学基金项目(Nos.41173019, 41473117) (Nos.41173019, 41473117)中国科学院仪器设备功能开发技术创新项目(No.2016G106) (No.2016G106)中国科学院关键技术人才(2005)项目资助 (2005)

High precise determination of stable bromine isotopic ratios was carried out by thermal ionization mass spectrometer triton with 8 kV accelerating voltage using static multicollection of Cs₂Br⁺ ions. The effect of B and Cl content on the measurement of bromine isotope was studied. The static multicollection method has many advantages, such as, high precision (external accuracy lies between 0.09‰-0.18‰), small amount of sample loading (10-20 μg Br) and short acquisitiotest time (just 8 min for 100 data acquisition). The results showed that the effect of Cl on the measurement of Br isotope ratio increased with the increase of Cl content, and that the presence of B made the determined bromine isotope ratio lower than that without B. The effect of the sample loading sequence on the results of the determined Br isotopic ratio was insignificant. Meanwhile, the Br isotopic composition of four bromide was determined, its δ⁸¹Br was between 0.61‰ and 1.68‰, showing a significant bromine isotope fractionation.
- Bromine isotope,
- Positive thermal ionization mass spectrometry,
- Static multicollection,
- Cs₂Br⁺ ions
1. [1]
  1 IUPAC. Pure Appl. Chem., 1998, 70: 217-235
2. [2]
  2 Eggenkamp H G M, Coleman M L. Chem. Geo., 2000, 167: 393-402
3. [3]
  3 Silva S R, Kendall C, Wilkison D H. J. Hydrology, 2000, 228(1/2): 22-36
4. [4]
  4 Stotler R L, Frape S K, Shouakar-Stash O. Chem. Geo., 2010, 274(1/2): 38-55
5. [5]
  5 Canfield D E. Geochin.Cosmochim.Acta, 2001, 65(7): 1117-1124
6. [6]
  6 Shouakar-Stash O, Frape S K, Rostron B J, Rostron B J, Drimmie R J. Geochin. Cosmochim. Acta, 2006, 70(18): A589
7. [7]
  7 Shouakar-Stash O, Alexeev S V, Frape S K, Alexeeva L P, Drimmie R J. Appl. Geochem., 2007, 22(3): 589-605
8. [8]
  8 Stotler R L, Frape S K, Shouakar-Stash O. Geochin. Cosmochim. Acta, 2006, 70(18): A619
9. [9]
  9 Braitsch O. Entstehung und Stoffbest and der Salzlagerstätten. Berlin: Springer-Verlag, 1962
10. [10]
  10 Aston F W. Philos. Magaz., 1920, 40: 628-634
11. [11]
  11 Shouakar-Stash O, Frape S K, Drimmie R J. Anal. Chem., 2005. 77: 4027-4033
12. [12]
  12 Sylva S P, Ball L, Nelson R K, Reddy C M. Rapid Commun. Mass Spectrom., 2007, 21: 3301-3305
13. [13]
  13 Gelman F, Halicz L. Int. J. Mass Spectrom., 2010, 289: 167-169
14. [14]
  14 Gelman F, Halicz L. Int. J. Mass Spectrom., 2011, 307: 211-213
15. [15]
  15 Xiao Y K, Liu W G, Qi H P, Zhang C G. Int. J. Mass Spectrom. Ion Process, 1993, 123(92): 117-123
16. [16]
  16 LIU Wei-Guo, XIAO Ying-Kai, QI Hai-Ping, ZHANG Chong-Geng. J. Salt Lake Sci., 1993, 1(3): 57-61 刘卫国, 肖应凯, 祁海平, 张崇耿. 盐湖研究, 1993, 1(3): 57-61
17. [17]
  17 Wei H Z, Jiang S Y, Zhu Z Y, Yang T, Yang J H, Yan X, Wu H P, Yang T L. Talanta, 2015, 143: 302-306
18. [18]
  18 Du Y, Ma T, Chen L Z, Shan H M, Xiao C, Lu Y, Liu C F, Cai H S. Appl. Geochem, 2015, 59: 155-165
19. [19]
  19 Du Y, Ma T, Yang J, Liu L, Shan H M, Cai H S, Liu C F, Chen L Z. Int. J. Mass Spectrom, 2013, 338: 50-56
20. [20]
  20 LIU Ling, MA Teng, LIU Cun-Fu, CAI He-Sheng, YANG Jie, YAO Wei-Kun. Geo.Sci. Technol. Info., 2011, 29(3): 104-109 刘玲, 马腾, 刘存富, 蔡鹤生, 杨杰, 姚维坤. 地质科技情报, 2011, 29(3): 104-109
21. [21]
  21 YANG Jie, MA Teng, LIU Ling, LIU Cun-Fu, SHAN Hui-Mei, CHEN Liu-Zhu. J. Earth Sci. Environ., 2010, 33(4): 397-401 杨杰, 马腾, 刘玲, 刘存富, 单慧媚, 陈柳竹. 地球科学与环境学报, 2010, 33(4): 397-401
22. [22]
  22 Luo C G, Xiao Y K, Wen H J, Ma H Z, Ma Y Q, Zhang Y L, Zhang Y X, He M Y. Appl. Geochem., 2014, 47: 141-149
23. [23]
  23 Catanzaro E J, Murphy T J, Garner E L, Shields W R. J. Res. Nat.Bureau of Standards, 1964, Sect A 68: 593-599
1. [1]
  Zongyuan Chen , ChunSheng Shi , Yiwen Li , Ganlin Zu , Qiang Jin , Haishan Wang , Fujun Wang , Dekun Yan , Zhijun Guo , Wangsuo Wu . Measurement of Uranium Isotopes in Environmental Water Samples by Alpha-Spectroscopy: Design of an Undergraduate Radiochemistry Experiment. University Chemistry, 2025, 40(4): 353-358. doi: 10.12461/PKU.DXHX202406103
2. [2]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
3. [3]
  Wenwen Zhang , Peichao Zhang , Conghao Gai , Xiaoyun Chai , Yan Zou , Qingjie Zhao . Unveiling Kinetics at Natural Abundance: ¹³C NMR Isotope Effect Experiments. University Chemistry, 2025, 40(10): 203-207. doi: 10.12461/PKU.DXHX202411076
4. [4]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
5. [5]
  Yongmei Xia , Zuming He , Gang He , Lianxiang Chen , Juan Zhang , Jiangbin Su , Muhammad Saboor Siddique , Xiaofei Fu , Guihua Chen , Wei Zhou . Lead-free perovskite Cs₃Bi₂Br₉/FeS₂ hollow core-shell Z-scheme heterojunctions toward optimized photothermal-photocatalytic H₂ production. Chinese Chemical Letters, 2025, 36(10): 111521-. doi: 10.1016/j.cclet.2025.111521
6. [6]
  Chao Liu , Huan Yu , Jiaming Li , Xi Yu , Zhuangzhi Yu , Yuxi Song , Feng Zhang , Qinfang Zhang , Zhigang Zou . 具有光热效应的多级Ti₃C₂/Bi₁₂O₁₇Br₂肖特基异质结简单合成及其太阳能驱动抗生素光降解的研究. Acta Physico-Chimica Sinica, 2025, 41(7): 100075-0. doi: 10.1016/j.actphy.2025.100075
7. [7]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
8. [8]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
9. [9]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
10. [10]
  Junjie Duan , Dan Chen , Long Chen , Shuying Li , Ting Chen , Dong Wang . 2D hexagonal tessellations sustained by Br···Br/H contacts: From regular to semiregular to k-uniform tilings. Chinese Chemical Letters, 2025, 36(3): 110445-. doi: 10.1016/j.cclet.2024.110445
11. [11]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
12. [12]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
13. [13]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
14. [14]
  Xueli Mu , Lingli Han , Tao Liu . Quantum Chemical Calculation Study on the E2 Elimination Reaction of Halohydrocarbon: Designing a Computational Chemistry Experiment. University Chemistry, 2025, 40(3): 68-75. doi: 10.12461/PKU.DXHX202404057
15. [15]
  Jianding LI , Junyang FENG , Huimin REN , Gang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464
16. [16]
  Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . In Situ Electrochemical Impedance Spectroscopy Monitoring of the High-Temperature Double-Discharge Mechanism of Nb₁₂WO₃₃ Cathode Material for Long-Life Thermal Batteries. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-0. doi: 10.1016/j.actphy.2024.100040
17. [17]
  Le Han , Zhou Yuan , Bohan Li , Yuchi Zhang , Lin Yang , Yan Xu . Highly-stable cesium lead halide perovskite CsPbBr₃/CsPb₂Br₅ heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation. Chinese Chemical Letters, 2025, 36(6): 110349-. doi: 10.1016/j.cclet.2024.110349
18. [18]
  Qilin YU , Yifei XU , Pengjun ZHANG , Shuwei HAO , Chongqiang ZHU , Chunhui YANG . Effect of regulating K⁺/Na⁺ ratio on the structure and optical properties of double perovskite Cs₂NaBiCl₆: Mn²⁺. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1058-1067. doi: 10.11862/CJIC.20240418
19. [19]
  Hongyu Tang , Dongming Liu , Jinfu Huang , Liang Zhang , Yang Tang , Bin Huang , Yanwei Li , Shunhua Xiao , Yiling Sun , Renheng Wang . Excellent structural stability and electrochemical properties of LiNi_0.9Co_0.05Mn_0.05O₂ material by surface Ni²⁺ anchoring and Cs⁺ doping. Chinese Chemical Letters, 2025, 36(6): 109987-. doi: 10.1016/j.cclet.2024.109987
20. [20]
  Ximeng CHI , Jianwei WEI , Yunyun WANG , Wenxin DENG , Jiayi DAI , Xu ZHOU . First-principles study of the electronic structure and optical properties of Au and I doped-inorganic lead-free double perovskite Cs₂NaBiCl₆. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1371-1379. doi: 10.11862/CJIC.20240401

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(726)
HTML views(185)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

High Precise Determination of Bromine Isotopic Ratios by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2Br+ Ions

Metrics

通讯作者: 陈斌, bchen63@163.com

High Precise Determination of Bromine Isotopic Ratios by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs₂Br⁺ Ions