Citation: Peng-jun Yuan, Miao Hong. Ring-opening Polymerizations of the “Non-strained” γ-Butyrolactone andIts Derivatives: An Overview and Outlook[J]. Acta Polymerica Sinica, ;2019, 50(4): 327-337. doi: 10.11777/j.issn1000-3304.2018.18232 shu

Ring-opening Polymerizations of the “Non-strained” γ-Butyrolactone andIts Derivatives: An Overview and Outlook

Peng-jun Yuan ¹ ,
Miao Hong ^2,,

1.
College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200235
2.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Miao Hong, miaohong@sioc.ac.cn
Received Date: 3 November 2018
Revised Date: 4 December 2018
Available Online: 17 January 2019

Aliphatic polyesters are a class of technologically important biodegradable and/or biocompatible polymers and have realized wide applications in biological medicine, temporary implants for tissue engineering, and packaging. Ring-opening polymerization (ROP) has proven to be a powerful methodology to prepare large-scale polyesters with different structures and properties. However, up to date, the monomers suitable for ROP are only restricted to the cyclic esters or lactones with a relatively high strain energy, which greatly limits the development and application of this methodology. Biomass-derived γ-butyrolactone (γ-BL), commercially available at a low price, would be a desirable monomer for ROP, but it is commonly referred as "non-polymerizable" in textbooks and the literature due to low strain energy of its five-membered ring. In 2016, Hong and Chen et al. established the first efficient ROP of γ-BL under mild conditions by controlling thermodynamics and kinetic conditions, which also provided a new approach for recyclable polymers. This breakthrough work attracted the attention of the scientific researchers in a short time, and a series of new catalysts have been developed for the ROP of γ-BL and its derivatives. In this context, this review article systematically summarizes the progress of the emerging area in the past three years by focusing on the discussion of the relationship between the catalyst structure and polymerization behavior, the structure-dependent polymer properties, as well as the recyclability of the resultant polymers. The currently unmet challenges in this field, and thus the suggested corresponding future research directions, are also presented.
- Ring-opening polymerization,
- Aliphatic polyesters,
- Degradable polymers,
- Recyclable polymers,
- Biomass-derived chemical,
- γ-Butyrolactone
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