Citation: Yi-dong Zou, Xiao-wei Cheng, Yong-hui Deng. Amphiphilic Block Copolymer Directed Synthesis of Ordered Mesoporous Metal Oxide Semiconductors[J]. Acta Polymerica Sinica, ;2018, 0(11): 1400-1415. doi: 10.11777/j.issn1000-3304.2018.18175 shu

Amphiphilic Block Copolymer Directed Synthesis of Ordered Mesoporous Metal Oxide Semiconductors

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433

Corresponding author: Yong-hui Deng, yhdeng@fudan.edu.cn
Received Date: 9 August 2018
Revised Date: 21 August 2018
Available Online: 6 September 2018

Ordered mesoporous materials, a family of highly porous nanomaterials, have attracted extensive attentions of many researchers in various fields due to their stable structure, high specific surface area, adjustable pore size, and easily modifiable pore wall. Over 70% reports on mesoporous materials are about amorphous mesoporous materials (e.g., silica), because the traditional templates are widely commercially available and can be used readily for synthesis of amorphous mesoporous materials. However, conventional soft templates are not favorable for the synthesis of crystalline ordered mesoporous metal oxide semiconductors (OMMSs) with unique physical and chemical properties (i.e., light, electricity, magnetism, catalysis, gas sensitivity, etc). Fortunately, this issue is well tackled by the development of interdisciplinary research along with more involvement of polymer researchers into the field of inorganic porous materials. In recent years, various novel block copolymers, particularly those with high carbon residue, high glass transition temperature, and complex-ability, have been synthesized and applied for fabricating porous materials. Remarkable progress has been achieved in using these templates to direct the co-assembly of various precursors for OMMSs synthesis. Starting from the preparation and assembly of polymer templates, this review elucidates systematically the mechanism and assembly behavior between metal oxide precursor and polymer templates. In addition, in-depth discussion is developed on the common three assembly processes, i.e. the metal inorganic salt-polymer template assembly, the metal cluster compounds-polymer template assembly, and the metal nanocrystals-polymer template assembly. Future opportunities and challenges faced by the synthesis and applications of OMMSs based on these novel block copolymer templates are foreseen in the last section.
- Amphiphilic block copolymers,
- Metal oxides,
- Co-assembly,
- Mesostructure,
- Templating synthesis
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