Citation: Zhong-bao Jian. Synthesis of Functionalized Polyolefins: Design from Catalysts to Polar Monomers[J]. Acta Polymerica Sinica, ;2018, 0(11): 1359-1371. doi: 10.11777/j.issn1000-3304.2018.18146 shu

Synthesis of Functionalized Polyolefins: Design from Catalysts to Polar Monomers

Zhong-bao Jian ^,

State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Corresponding author: Zhong-bao Jian, zbjian@ciac.ac.cn
Received Date: 26 June 2018
Available Online: 6 September 2018

Coordination-insertion copolymerization of olefins and polar monomers for the preparation of functionalized polyolefins is one of the most important project in the field of olefin polymerization in the past twenty years. Due to the incorporation of functional groups, functionalized polyolefins, as the high value-added polymer materials, are of better surface properties and compatibility than those without any functionality, thus leading to expanding the range of applications. However, the presence of functional groups can also accelerate the chain transfer and chelate to the active central metal in the copolymerization of olefin and polar monomers, therefore this type of copolymerization suffers from lower catalytic activity and lower polymer molecular weight than the corresponding homo-polymerization of the olefins. As a result, the key for the high performance synthesis of functionalized polyolefins is to overcome the problem related to the functional groups of the polar monomers. In this Feature Article, recent research progress on the copolymerization of olefins and polar monomers to achieve the functionalized polyolefins by using late transition metal catalysts will be mostly summarized. Firstly, the milestone catalysts for the synthesis of functionalized polyolefins are introduced, and the latest research progresses on how to overcome the problem of polar monomer by designing nickel and palladium catalysts are highlighted. Then a series of our findings in recent years on the design of the polar monomers for the synthesis of functionalized polyolefins are revealed in detail, including the concept of polar di-vinyl monomers to overcome the problems related to polar monomers (rapid chain transfer reaction and chelation of functional group to active central metal) and the strategy of vinyl furan monomer with secondary coordination effect to synthesize novel functionalized polyolefins (telechelic polyolefin with two reactive endgroups). Finally, future development and long-standing challenges in the community of functionalized polyolefins by the copolymerization of olefins and polar monomers are out looked.
- Functionalized polyolefin,
- Late transition metal catalyst,
- Polar monomer,
- Coordination insertion polymerization,
- Catalytic activity and molecular weight
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