Citation: Dong-yang Chen, Cheng Liu, Jin-yan Wang, Chun-yue Pan, Gui-peng Yu, Xi-gao Jian. Research Progress on the Electrochemical Application of Nanoporous Organic Polymers[J]. Acta Polymerica Sinica, ;2018, 0(5): 559-570. doi: 10.11777/j.issn1000-3304.2017.17298 shu

Research Progress on the Electrochemical Application of Nanoporous Organic Polymers

1.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083
2.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Corresponding author: Gui-peng Yu, gilbertyu@csu.edu.cn
Received Date: 27 October 2017
Revised Date: 28 November 2017
Available Online: 1 March 2018

As new emerged polymer materials, nanoporous organic polymers (NOPs), derived completely from light elements, are featured by high surface areas, low skeleton densities, and good chemical and thermal stabilities, which have led to numerous potential applications in heterogeneous catalysis, gas storage, and separation. Furthermore, their versatile synthetic methodology, controllable pore structure and easy modification significantly accelerate their development. Recently, the applications of NOPs targeted for organic electronic devices and solid state sensors have drawn increasing attention. The study of NOP-based electrochemical sensor technologies has become a very active and robust research area, and is expected to provide high-performance technologies for electrode materials, electrocatalytic carrier, and electrochemical detection, etc. One potential advantage of these materials is derived from their porous robust frameworks with high accessible surface areas, which enable structural preservation and efficient metal uptake and diffusion. However, the weak electron transport and wettability of NOPs somewhat limit their practical application in electrochemistry. In response, novel strategies have been developed to enhance their conductivity and wettability, including the incorporation of heteroatoms, extending of the skeleton conjugation, and the introduction of metal sites into the porous networks. Especially, the introduction of heteroatoms into the electrode materials is the mostly utilized technology, because it not only enables the increase in conductivity, wettablity and electroactive surface area of the electrodes, but also endows the electrodes with high pseudocapacitance. Furthermore, pore-size engineering, i.e., enhancing microporosity and constructing hierarchical structure, is crucial to improve the electrochemical performance. Hierarchically porous materials used as electrode matrices appear to be much more favorable for mass loading and ion diffusion or transport, endowing them with technological importance for applications in energy storage and sensor applications. This study summarizes recent research progress of NOPs in electrochemical applications, focuses on rational design, pore engineering and the structure-electrochemical property relationship, and also prospects their future development.
- Nanoporous organic polymers,
- Electrode materials,
- Electrocatalysis,
- Electrochemical properties
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