Citation: Hongshan Wang, Zhenglong Li, Ran An, Zhenyou Wang, Juanjuan Lu, Guansong Zheng, Zhihua Yang, Yu Chu, Junjie Li. NaAg3Ga8S14: A new diamond-like framework infrared nonlinear optical material derived from AgGaS2[J]. Chinese Journal of Structural Chemistry, ;2025, 44(12): 100757. doi: 10.1016/j.cjsc.2025.100757 shu

NaAg3Ga8S14: A new diamond-like framework infrared nonlinear optical material derived from AgGaS2

Diamond-like AgGaS2 (DL AGS), as the typical infrared nonlinear optical (IR NLO) material, has suffered from its intrinsic drawbacks like narrow band gap (Eg) and low laser-induced damage threshold (LIDT). In this work, by first introducing [NaS8] polyhedral unit into the A2IQVI-Ag2QVI-C2IIIQ3VI system, a new Ag-based sulfide NaAg3Ga8S14 with diamond-like framework (DLF) has been successfully synthesized via a high-temperature solid-state method in experiment. The compound shows a wide Eg (∼3.0 eV), high LIDT (3.0 × AGS) and moderate phase-matching NLO response (∼0.7 × AGS), effectively balancing the Eg (≥ 3.0 eV) and NLO response (≥ 0.5 × AGS), demonstrating its promise for IR NLO applications. Theoretical calculations elucidate the orbital hybridization between Na 3s, Ag 4d5s and S 3p enhances Eg, and the aligned NLO-active units ([AgS4] and [GaS4]) induce moderate NLO response in the compound. These findings not only expand the chemical and structural diversities of Ag-based chalcogenides, but also provide effective strategies for designing DLF functional materials derived from diamond-like structures.
- Diamond-like framework,
- Nonlinear optical materials,
- Chalcogenides,
- High laser-induced damage threshold,
- AI2QVI-Ag2QVI-CIII2QVI3 system
1. [1]
  Xiaodong Zhang , Bohui Xu , Deshuai Xiao , Xinyuan Zhang , Pifu Gong , Zheshuai Lin . From centrosymmetric CN3H6C6H5SO3 to non-centrosymmetric CN3H6C6H4SO3(OH): Hydroxyl introduced hydrogen bond reconstruction to realize strong second harmonic generation. Chinese Journal of Structural Chemistry, 2025, 44(10): 100707-100707. doi: 10.1016/j.cjsc.2025.100707
2. [2]
  Weiping Guo , Ying Zhu , Hong-Hua Cui , Lingyun Li , Yan Yu , Zhong-Zhen Luo , Zhigang Zou . β-Pb₃P₂S₈: A new optical crystal with exceptional birefringence effect. Chinese Chemical Letters, 2025, 36(2): 110256-. doi: 10.1016/j.cclet.2024.110256
3. [3]
  Yuwei Kang , Can Yang , Jun Zhang , Qi Wu . Synergistic triple-site engineering in ABX₃-type hybrid halides for high-performance nonlinear optical crystals. Chinese Chemical Letters, 2026, 37(1): 111385-. doi: 10.1016/j.cclet.2025.111385
4. [4]
  Tianyang Dong , Xingyuan Wen , Xingzhi Wu , Ying Jiang , Chong Wang , Ruizhi Liu , Junyi Li , Wenfa Zhou , Yinglin Song , Xiaofeng Shi , Rui Wen , Chunru Wang , Li Jiang , Chunli Bai . Ionic covalent organic frameworks enable laser-pulse-duration-dependent high third-order nonlinear optical responses. Chinese Journal of Structural Chemistry, 2025, 44(10): 100733-100733. doi: 10.1016/j.cjsc.2025.100733
5. [5]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
6. [6]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
7. [7]
  Tian Cao , Xuyin Ding , Qiwen Peng , Min Zhang , Guoyue Shi . Intelligent laser-induced graphene sensor for multiplex probing catechol isomers. Chinese Chemical Letters, 2024, 35(7): 109238-. doi: 10.1016/j.cclet.2023.109238
8. [8]
  A-Yang Wang , Sheng-Hua Zhou , Mao-Yin Ran , Xin-Tao Wu , Hua Lin , Qi-Long Zhu . Regulating the key performance parameters for Hg-based IR NLO chalcogenides via bandgap engineering strategy. Chinese Chemical Letters, 2024, 35(10): 109377-. doi: 10.1016/j.cclet.2023.109377
9. [9]
  Jiajing Wu , Ru-Ling Tang , Sheng-Ping Guo . Three types of promising functional building units for designing metal halide nonlinear optical crystals. Chinese Journal of Structural Chemistry, 2024, 43(6): 100291-100291. doi: 10.1016/j.cjsc.2024.100291
10. [10]
  Lihua Gao , Yinglei Han , Chensheng Lin , Huikang Jiang , Guang Peng , Guangsai Yang , Jindong Chen , Ning Ye . Halogen-assisted octet binding electrons construction of pnictogens towards wide-bandgap nonlinear optical pnictides. Chinese Chemical Letters, 2024, 35(12): 109529-. doi: 10.1016/j.cclet.2024.109529
11. [11]
  Hongyuan Sha , Dongling Yang , Yanran Shang , Zujian Wang , Rongbing Su , Chao He , Xiaoming Yang , Xifa Long . Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra. Chinese Chemical Letters, 2025, 36(4): 109730-. doi: 10.1016/j.cclet.2024.109730
12. [12]
  Yangfeifei Ou , Xiao-Liang Zhou , You-Zhao Lan , Jian-Wen Cheng . Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions. Chinese Journal of Structural Chemistry, 2025, 44(9): 100708-100708. doi: 10.1016/j.cjsc.2025.100708
13. [13]
  Yijia Chen , Wendan Luo , Ke Liu , Taihong Liu , Liping Ding , Yu Fang . Diverse roles of indacenodithiophene in push-pull chromophores for enhanced two-photon absorption and efficient nonlinear optical limiting. Chinese Journal of Structural Chemistry, 2025, 44(10): 100704-100704. doi: 10.1016/j.cjsc.2025.100704
14. [14]
  Ying Xu , Yan Pu , Qiong Zhang , Xi Kang , Manzhou Zhu . Order-by-order control over the nonlinear optical properties of atomically precise nanoclusters. Chinese Journal of Structural Chemistry, 2025, 44(10): 100735-100735. doi: 10.1016/j.cjsc.2025.100735
15. [15]
  Jun-Jie Fang , Zheng Liu , Yun-Peng Xie , Xing Lu . Superatomic Ag₅₈ nanoclusters incorporating a [MS₄@Ag₁₂]²⁺ (M = Mo or W) kernel show aggregation-induced emission. Chinese Chemical Letters, 2024, 35(10): 109345-. doi: 10.1016/j.cclet.2023.109345
16. [16]
  Lanfang Wang , Jiangnan Lv , Yujia Li , Yanqing Hao , Wenjiao Liu , Hui Zhang , Xiaohong Xu . One-step synthesis of nanowoven ball-like NiS-WS₂ for high-efficiency hydrogen evolution. Chinese Chemical Letters, 2025, 36(1): 109597-. doi: 10.1016/j.cclet.2024.109597
17. [17]
  Yinghao Zhang , Ke Shao , Yihang Zhu , Haokun Zhang , Yinuo Zhuo , Huihui Bao , Yeye Ai , Yongguang Li . Unanticipated optical properties of π-conjugated cyclometalated Pt(Ⅱ) complexes for advanced information storage and anti-counterfeiting materials. Chinese Chemical Letters, 2025, 36(9): 110735-. doi: 10.1016/j.cclet.2024.110735
18. [18]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
19. [19]
  Gaojie Zhu , Zhen Yang , Shijun Li , Weihua Zhu , Rui Cao , Junlong Zhang , Jianzhang Zhao , Jonathan L. Sessler , Xunjin Zhu , Jianxin Song , Yongshu Xie , Jianzhuang Jiang . The 2^nd Asian Conference on Porphyrins, Phthalocyanines and Related Materials. Chinese Chemical Letters, 2024, 35(7): 109535-. doi: 10.1016/j.cclet.2024.109535
20. [20]
  Pu Zhang , Xiang Mao , Xuehua Dong , Ling Huang , Liling Cao , Daojiang Gao , Guohong Zou . Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions. Chinese Chemical Letters, 2024, 35(9): 109235-. doi: 10.1016/j.cclet.2023.109235

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