Citation: Shuyu Li, Ning Gong, Zhi-Hao Lin, Jing Chen, Ge Chen, Jun Lv, Guangyang Liu, Yi Niu, Liao-Yuan Yao, Donghui Xu, Lin Qin. Addressing agricultural (micro)plastics pollution: The promises and perspectives of framework-based photocatalysis[J]. Chinese Journal of Structural Chemistry, ;2025, 44(12): 100752. doi: 10.1016/j.cjsc.2025.100752 shu

Addressing agricultural (micro)plastics pollution: The promises and perspectives of framework-based photocatalysis

Plastics, renowned for their flexibility, stability, and cost-effectiveness, have become indispensable materials in modern life. However, their extensive use has led to a global environmental and health crisis. Especially, plastic products infiltrate agroecosystems through atmospheric deposition, irrigation water, soil contamination, and the degradation of plastic mulch films, posing significant risks to vegetable quality and safety. Traditional disposal methods, such as incineration and landfilling, are energy-intensive and ecologically harmful, necessitating the development and application of innovative technologies for plastic removal. This paper reviews representative advanced (micro)plastic removal technologies, with a particular focus on frameworks-containing photocatalysis as a promising green method for processing (micro)plastics. First, we analyze and compare traditional, then discuss emerging removal technologies. Next, we elaborate on the principles of photocatalytic degradation of plastic products, discuss key influencing factors, and classify various photocatalysts. Additionally, we highlight the limitations of conventional photocatalysts, such as TiO2 and ZnO, and emphasize the advantages of framework materials (e.g., MOFs, COFs, ZIFs) in photocatalytic degradation, including their structural tunability and development potential. Finally, based on the current progress and applications of framework photocatalysts, we identify existing limitations and propose future research directions. This review provides a theoretical foundation and innovative technological insights to address the global challenge of plastic pollution.
- Plastic pollution,
- Agricultural security,
- Removal technology,
- Photocatalytic degradation,
- Frameworks catalysts
1. [1]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
2. [2]
  Shenghui Tu , Anru Liu , Hongxiang Zhang , Lu Sun , Minghui Luo , Shan Huang , Ting Huang , Honggen Peng . Oxygen vacancy regulating transition mode of MIL-125 to facilitate singlet oxygen generation for photocatalytic degradation of antibiotics. Chinese Chemical Letters, 2024, 35(12): 109761-. doi: 10.1016/j.cclet.2024.109761
3. [3]
  Guie Li , Chunyan Yang , Qiu Yang , Qingzhu Zheng , Menghan Li , Jianhua Qu , Guangshan Zhang . A magnetically recyclable CoFe₂O₄/BiOBr S-scheme heterojunction for efficient photocatalytic degradation of diuron: Performance, durability and mechanism exploration. Chinese Chemical Letters, 2026, 37(1): 111207-. doi: 10.1016/j.cclet.2025.111207
4. [4]
  Yuhao Ma , Yufei Zhou , Mingchuan Yu , Cheng Fang , Shaoxia Yang , Junfeng Niu . Covalently bonded ternary photocatalyst comprising MoSe₂/black phosphorus nanosheet/graphitic carbon nitride for efficient moxifloxacin degradation. Chinese Chemical Letters, 2024, 35(9): 109453-. doi: 10.1016/j.cclet.2023.109453
5. [5]
  Hongping Zhao , Hanzhaobing Wu , Baolong Shi , Jiayue Wang , Chunzheng Wu , Chaohai Wang , Xiaoyan Wang , Wei Liu , Chaoqing Dai , Dalei Wang . Fast and controllable anatase-to-rutile phase transition irradiated by NIR light. Chinese Chemical Letters, 2025, 36(11): 110815-. doi: 10.1016/j.cclet.2025.110815
6. [6]
  Shuangyu Wu , Jian Peng , Yue Jiang , Sijie Lin . The overlooked promotional effects of alcohols to BiOBr catalysts in photocatalytic degradation of organic pollutants. Chinese Chemical Letters, 2025, 36(11): 110819-. doi: 10.1016/j.cclet.2025.110819
7. [7]
  Peiyang Du , Ling Yuan , Tong Bao , Yamin Xi , Jiaxin Li , Yin Bi , Luli Yin , Jing Wang , Chao Liu . Facet effect of metal-organic frameworks on supporting co-catalysts for photocatalytic hydrogen peroxide production. Chinese Chemical Letters, 2025, 36(11): 110472-. doi: 10.1016/j.cclet.2024.110472
8. [8]
  Shouchao Zhong , Yue Wang , Mingshu Xie , Yiqian Wu , Jiuqiang Li , Jing Peng , Liyong Yuan , Maolin Zhai , Weiqun Shi . Radiation reduction modification of sp² carbon-conjugated covalent organic frameworks for enhanced photocatalytic chromium(VI) removal. Chinese Chemical Letters, 2025, 36(5): 110312-. doi: 10.1016/j.cclet.2024.110312
9. [9]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
10. [10]
  Haibo Ye , Qianyu Li , Juan Li , Didi Li , Zhimin Ao . Review on the abiotic degradation of biodegradable plastic poly(butylene adipate-terephthalate): Mechanisms and main factors of the degradation. Chinese Chemical Letters, 2025, 36(1): 109861-. doi: 10.1016/j.cclet.2024.109861
11. [11]
  Xingyan Liu , Kaili Wu , Yacen Tang , Ning Qi , Yumeng Zhang , Youzhou He , Min Fu , Yanhui Ao . Ti₃C₂ MXene-derived TiO₂@C attached on Bi₂WO₆ with oxygen vacancies to fabricate S-scheme heterojunction for photocatalytic antibiotics degradation and NO removal. Chinese Chemical Letters, 2025, 36(11): 110882-. doi: 10.1016/j.cclet.2025.110882
12. [12]
  Qinwei Lu , Jinjie Lu , Juying Lei , Xubiao Luo , Yanbo Zhou . Cyclodextrin-boosted photocatalytic oxidation for efficient bisphenol A removal. Chinese Chemical Letters, 2025, 36(3): 110017-. doi: 10.1016/j.cclet.2024.110017
13. [13]
  Liangbo Zhang , Jun Cheng , Yahui Shi , Kunjie Hou , Qi An , Jingyi Li , Baohui Cui , Fei Chen . Efficient removal of tetracycline hydrochloride by ZnO/HNTs composites under visible light: Kinetics, degradation pathways and mechanism. Chinese Chemical Letters, 2025, 36(7): 110400-. doi: 10.1016/j.cclet.2024.110400
14. [14]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
15. [15]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
16. [16]
  Tianyao He , Gan Li , Xiaoqiang Xie , Dong Han , Yunyue Leng , Qiuli Zhang , Wenming Liu , Guobo Li , Hongxiang Zhang , Shan Huang , Ting Huang , Honggen Peng . Design of highly active meso-zeolite enveloping Pt–Ni bimetallic catalysts for degradation of toluene. Chinese Chemical Letters, 2025, 36(4): 110137-. doi: 10.1016/j.cclet.2024.110137
17. [17]
  Wan-Yin Gao , Xiao-Qiang Cao , Li-Fei Hou , Hao-Yun Lu , Zhao-Jing Zhu , Wen-Jia Kong , Yang Zhang , Yi-Zhen Zhang , Ya-Nan Shang , Xing Xu . Electron transfer chemistry triggered by silicon-doped carbon catalysts derived from natural minerals for the degradation of organic pollutants. Chinese Chemical Letters, 2026, 37(1): 111095-. doi: 10.1016/j.cclet.2025.111095
18. [18]
  Ke Zhang , Yajing Wei , Linhua Xie , Sha Kang , Fei Li , Chuanyi Wang . Amorphous titanium carbide on N-defective g-C₃N₅ for high-efficiency photocatalytic NO removal. Chinese Chemical Letters, 2025, 36(3): 110086-. doi: 10.1016/j.cclet.2024.110086
19. [19]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
20. [20]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(2)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142