Citation: Jian Ji, Jie Yan, Honggen Peng. Modulation of dinuclear site by orbital coupling to boost catalytic performance[J]. Chinese Journal of Structural Chemistry, ;2024, 43(8): 100360. doi: 10.1016/j.cjsc.2024.100360 shu

Modulation of dinuclear site by orbital coupling to boost catalytic performance

This work reports on a novel ship-in-a-bottle strategy to fabricate DSCs with well-defined microstructure. The resulting DSCs exhibited outstanding performance toward catalytic ozonation of CH3SH owing to the Fe 3d orbital coupling. This is of immediate interest to the DSCs synthesis but also to the reaction mechanism investigation of catalytic ozonation. Notably, the applicability of the electron paramagnetic resonance (EPR) spectroscopy approach for determining reactive oxygen species (ROS) on the catalyst surface during ozonation processes, as well as the theoretical underpinnings for the transformation of surface oxygen species to ROS, warrant further in-depth investigation. Additionally, the use of DSCs for catalytic ozonation of a broader spectrum of VOC pollutants, beyond the specific case of CH3SH oxidation, requires comprehensive evaluation.
1. [1]
  Kaili Wang , Pengcheng Liu , Mingzhe Wang , Tianran Wei , Jitao Lu , Xingling Zhao , Zaiyong Jiang , Zhimin Yuan , Xijun Liu , Jia He . Modulating d-d orbitals coupling in PtPdCu medium-entropy alloy aerogels to boost pH-general methanol electrooxidation performance. Chinese Chemical Letters, 2025, 36(4): 110532-. doi: 10.1016/j.cclet.2024.110532
2. [2]
  Yuhan Zheng , Yunzhen Jia , Xuelei Lang , Dazhong Zhong , Jinping Li , Qiang Zhao . Stabilizing Cu²⁺ in perovskite via A-site modulation for efficient CO₂ electrocatalysis to CH₄. Chinese Chemical Letters, 2025, 36(8): 111193-. doi: 10.1016/j.cclet.2025.111193
3. [3]
  Wei Peng , Yao Shen , Xiaolin Yu , Chenghang Zheng , Xiao Zhang , Jingkai Zhao , Jiexu Ye , Shihan Zhang , Xiang Gao . Asymmetric coupling of atop-type and hollow-type adsorbed *CO to boost electrocatalytic CO₂-to-C₂ conversion on high-index Cu₂O crystal planes. Chinese Chemical Letters, 2026, 37(1): 111187-. doi: 10.1016/j.cclet.2025.111187
4. [4]
  Junchen Peng , Zhongyuan Guo , Dandan Dong , Yusheng Lu , Bao Wang , Fangjie Lu , Chaofeng Huang , Bin Dai . Cu⁰/Cu^δ⁺ site construction and its catalytic role in acetylene hydrochlorination. Chinese Chemical Letters, 2025, 36(8): 111208-. doi: 10.1016/j.cclet.2025.111208
5. [5]
  Linfeng Li , Bao Wang , Tiantong Zhang , Xinyuan Wang , Dingqiang Feng , Wei Li , Jiangjiexing Wu , Jinli Zhang . Identifying the catalytic active site of durable Ru-based liquid-phase catalyst for acetylene hydrochlorination. Chinese Chemical Letters, 2025, 36(10): 111303-. doi: 10.1016/j.cclet.2025.111303
6. [6]
  Hao-Fei Ni , Jia-He Lin , Gele Teri , Qiang-Qiang Jia , Pei-Zhi Huang , Hai-Feng Lu , Chang-Feng Wang , Zhi-Xu Zhang , Da-Wei Fu , Yi Zhang . B-site ion regulation strategy enables performance optimization and multifunctional integration of hybrid perovskite ferroelectrics. Chinese Chemical Letters, 2025, 36(3): 109690-. doi: 10.1016/j.cclet.2024.109690
7. [7]
  Xia Liu , Wenzhuo Dong , Mengqian Jia , Dexiu Zhang , Jingyi Niu , Jiwei Shen , Chaozhan Wang , Yinmao Wei . Two-site synergistic binding strategy for improving adsorption and separation performance of antibodies. Chinese Chemical Letters, 2025, 36(12): 110991-. doi: 10.1016/j.cclet.2025.110991
8. [8]
  Jun Guo , Zhenbang Zhuang , Wanqiang Liu , Gang Huang . "Co-coordination force" assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries. Chinese Chemical Letters, 2024, 35(9): 109803-. doi: 10.1016/j.cclet.2024.109803
9. [9]
  Yuwei Kang , Can Yang , Jun Zhang , Qi Wu . Synergistic triple-site engineering in ABX₃-type hybrid halides for high-performance nonlinear optical crystals. Chinese Chemical Letters, 2026, 37(1): 111385-. doi: 10.1016/j.cclet.2025.111385
10. [10]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
11. [11]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
12. [12]
  Lu Qi , Zhaoyang Chen , Xiaoyu Luan , Zhiqiang Zheng , Yurui Xue , Yuliang Li . Atomically dispersed Mn enhanced catalytic performance for overall water splitting on graphdiyne-coated copper hydroxide nanowire. Chinese Journal of Structural Chemistry, 2024, 43(1): 100197-100197. doi: 10.1016/j.cjsc.2023.100197
13. [13]
  Yanyu Jin , Wenzhe Si , Xing Yuan , Hongjun Cheng , Bin Zhou , Li Cai , Yu Wang , Qibao Wang , Junhua Li . Tuning TM–O interaction by acid etching in perovskite catalysts boosting catalytic performance. Chinese Chemical Letters, 2025, 36(5): 110260-. doi: 10.1016/j.cclet.2024.110260
14. [14]
  Guang-Xu Duan , Queting Chen , Rui-Rui Shao , Hui-Huang Sun , Tong Yuan , Dong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO₂ nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751
15. [15]
  Ming Xu , Teng Deng , Chenzhaosha Li , Hongyang Zhao , Juan Wang , Yatao Liu , Jianan Wang , Guodong Feng , Na Li , Shujiang Ding , Kai Xi . Oxygen deficient Eu₂O₃₋_δ synchronizes the shielding and catalytic conversion of polysulfides toward high-performance lithium sulfur batteries. Chinese Chemical Letters, 2025, 36(10): 110372-. doi: 10.1016/j.cclet.2024.110372
16. [16]
  Xinnan XIE , Boyu ZHANG , Jianxun YANG , Yi ZHONG , Younis Osama , Jianxiao YANG , Xinchun YANG . Ultrafine platinum clusters achieved by metal-organic framework derived cobalt nanoparticle/porous carbon: Remarkable catalytic performance in dehydrogenation of ammonia borane. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2095-2102. doi: 10.11862/CJIC.20250025
17. [17]
  Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131
18. [18]
  Bin Chen , Chaoyang Zheng , Dehuan Shi , Yi Huang , Renxia Deng , Yang Wei , Zheyuan Liu , Yan Yu , Shenghong Zhong . p-d orbital hybridization induced by CuGa2 promotes selective N2 electroreduction. Chinese Journal of Structural Chemistry, 2025, 44(1): 100468-100468. doi: 10.1016/j.cjsc.2024.100468
19. [19]
  Guoliang Liu , Zhiqiang Liu , Anmin Zheng . Modulation of zeolite surface realizes dynamic copper species redispersion. Chinese Journal of Structural Chemistry, 2024, 43(6): 100308-100308. doi: 10.1016/j.cjsc.2024.100308
20. [20]
  Juhong Zhou , Hui Zhao , Ping Han , Ziyue Wang , Yan Zhang , Xiaoxia Mao , Konglin Wu , Shengjue Deng , Wenxiang He , Binbin Jiang . Strategic modulation of CoFe sites for advanced bifunctional oxygen electrocatalyst. Chinese Journal of Structural Chemistry, 2025, 44(1): 100470-100470. doi: 10.1016/j.cjsc.2024.100470

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1447)
HTML views(63)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return