Citation: Yuhao Guo, Na Li, Tingjiang Yan. Tandem catalysis for photoreduction of CO2 into multi-carbon fuels on atomically thin dual-metal phosphochalcogenides[J]. Chinese Journal of Structural Chemistry, ;2024, 43(7): 100320. doi: 10.1016/j.cjsc.2024.100320 shu

Tandem catalysis for photoreduction of CO2 into multi-carbon fuels on atomically thin dual-metal phosphochalcogenides

In summary, the ultrathin multimetallic phosphochalcogenides photocatalysts exhibit excellent photocatalytic activity. Among them, the ultrathin structure can provide more active sites, which is conducive to CO2 adsorption and activation, while the Cu–In dual sites act as tandem catalytic sites to accelerate C=O bond activation and C–C bond coupling. Despite this research has significant scientific value and theoretical significance for achieving carbon emission reduction and resource utilization of CO2 as well as guiding the design and preparation of highly efficient multimetallic 2D layered catalysts, the bottlenecks of large-scale preparation and the considerations on cost, stability and longevity of these 2D catalysts for industrial applications still remain a significant challenge. Furthermore, improving product selectivity and integrating such catalytic processes into existing industrial systems will contribute significantly to sustainable industrialization.
1. [1]
  Tinghui Yang , Min Kuang , Jianping Yang . Mesoporous CuCe dual-metal catalysts for efficient electrochemical reduction of CO2 to methane. Chinese Journal of Structural Chemistry, 2024, 43(8): 100350-100350. doi: 10.1016/j.cjsc.2024.100350
2. [2]
  Qiyan Wu , Qing Li . Topologically close-packed intermetallic alloy electrocatalysts for CO₂ reduction towards high value-added multi-carbon chemicals. Chinese Chemical Letters, 2025, 36(1): 110384-. doi: 10.1016/j.cclet.2024.110384
3. [3]
  Pei Xu , Tian-Zi Hao , Zhi-Tao Liu , Yi-Qin Liu , Hui-Xian Jiang , Dong Guo , Xu Zhu . Visible-light-induced dual catalysis for divergent reduction of nitro compounds with CO₂ radical anion. Chinese Chemical Letters, 2025, 36(10): 110899-. doi: 10.1016/j.cclet.2025.110899
4. [4]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
5. [5]
  Ming Yang , Lin-Bo Liu , Shuo Liu , Yan Li , Biao Ouyang , Xian-Zhu Fu , Jing-Li Luo , Yifei Sun , Subiao Liu . Electrosynthesizing high-value fuels from CO₂ in solid oxide electrolysis cells: Fundamentals, advances, and perspectives. Chinese Chemical Letters, 2025, 36(12): 110603-. doi: 10.1016/j.cclet.2024.110603
6. [6]
  Xiaofan ZHANG , Yu DUAN , Meijie SHI , Nan LU , Renhong LI , Xiaoqing YAN . Z-scheme Co₃O₄/BiOBr heterojunction for efficient photoreduction CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1878-1888. doi: 10.11862/CJIC.20250079
7. [7]
  Linlu Bai , Wensen Li , Xiaoyu Chu , Haochun Yin , Yang Qu , Ekaterina Kozlova , Zhao-Di Yang , Liqiang Jing . Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction. Chinese Chemical Letters, 2025, 36(2): 109931-. doi: 10.1016/j.cclet.2024.109931
8. [8]
  Weikang Wang , Lele Wang , Qinqin Liu . CO2 valorization to amides via S-scheme photocatalysis with tandem carbonylation. Chinese Journal of Structural Chemistry, 2025, 44(12): 100718-100718. doi: 10.1016/j.cjsc.2025.100718
9. [9]
  Huarui Han , Yangrui Xu , Yu Cheng , Liguang Tang , Jie Jin , Xinlin Liu , Changchang Ma , Ziyang Lu . Frustrated Lewis pairs in CO2 photoreduction: A review on synergistic activation and charge separation. Chinese Journal of Structural Chemistry, 2025, 44(10): 100728-100728. doi: 10.1016/j.cjsc.2025.100728
10. [10]
  Xiang-Da Zhang , Jian-Mei Huang , Xiaorong Zhu , Chang Liu , Yue Yin , Jia-Yi Huang , Yafei Li , Zhi-Yuan Gu . Auto-tandem CO₂ reduction by reconstructed Cu imidazole framework isomers: Unveiling pristine MOF-mediated CO₂ activation. Chinese Chemical Letters, 2025, 36(5): 109937-. doi: 10.1016/j.cclet.2024.109937
11. [11]
  Cheng-Cheng Jiao , Guang-Xing Dong , Ke Su , You-Xiang Feng , Min Zhang , Tong-Bu Lu . The construction of InVO₄/BiVO₄ heterojunction via cation-exchange for efficient and highly selective CO₂ photoreduction to methanol. Chinese Chemical Letters, 2026, 37(1): 110752-. doi: 10.1016/j.cclet.2024.110752
12. [12]
  Chenxi Shang , Boxuan Lu , Chongbei Wu , Shuqing Zhou , Luyan Shi , Tayirjan Taylor Isimjan , Xiulin Yang . Inducing electronic rearrangement through Co₃B-Mo₂B₅ catalysts: Efficient dual-function catalysis for NaBH₄ hydrolysis and 4-nitrophenol reduction. Chinese Chemical Letters, 2025, 36(9): 111152-. doi: 10.1016/j.cclet.2025.111152
13. [13]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
14. [14]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
15. [15]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
16. [16]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139
17. [17]
  Ruolin CHENG , Yue WANG , Fei YANG , Huagen LIANG , Shijian LU . Application of metal-organic frameworks (MOFs) in photocatalytic CO₂ cycloaddition reaction: A mini review. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2429-2440. doi: 10.11862/CJIC.20250242
18. [18]
  Zhi-Xin Li , Xiao-Feng Qiu , Pei-Qin Liao . Efficient electroreduction of CO₂ to acetate with relative purity of 100% by ultrasmall Cu₂O nanoparticle on a conductive metal-organic framework. Chinese Chemical Letters, 2025, 36(11): 110473-. doi: 10.1016/j.cclet.2024.110473
19. [19]
  Xingxing Jiang , Yuxin Zhao , Yan Kong , Jianju Sun , Shangzhao Feng , Xin Lu , Qi Hu , Hengpan Yang , Chuanxin He . Support effect and confinement effect of porous carbon loaded tin dioxide nanoparticles in high-performance CO₂ electroreduction towards formate. Chinese Chemical Letters, 2025, 36(1): 109555-. doi: 10.1016/j.cclet.2024.109555
20. [20]
  Ruowen Liang , Chao Zhang , Guiyang Yan . Enhancing CO2 cycloaddition through ligand functionalization: A case study of UiO-66 metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(2): 100211-100211. doi: 10.1016/j.cjsc.2023.100211

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(740)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return