Citation: Zhen-Qi Wang, Zhuo Zhang, Si-Yu Wan, Yuan Huang. The evolving landscape of synthesis enabled by gem-diboryl radicals[J]. Chinese Chemical Letters, ;2026, 37(12): 112748. doi: 10.1016/j.cclet.2026.112748 shu

The evolving landscape of synthesis enabled by gem-diboryl radicals

Department of Medicinal Chemistry, School of Pharmacy, Xi’an Jiaotong University, Xi’an 710061, China

huangyuan@xjtu.edu.cn

Received Date: 9 December 2025
Revised Date: 20 March 2026
Accepted Date: 7 April 2026
Available Online: 8 April 2026

Figures(18)

gem-Diboron compounds have attracted considerable attention in synthetic chemistry owing to their remarkable versatility and broad range of transformations. While the reactivity of gem-diboron compounds, such as anions and carbocation equivalents, has been extensively studied, the chemistry of gem-diboryl radicals remains comparatively underexplored. Nonetheless, this emerging field is developing rapidly and shows great promise for applications in both organic synthesis and medicinal chemistry. However, a comprehensive review of this field is still missing. This review summarizes recent advances in the chemistry of gem-diboryl radicals, highlighting their growing importance as highly versatile synthons in radical-mediated transformations. The manuscript systematically classifies the generation of gem-diboryl radicals into several pathways, including single-electron transfer (SET), energy transfer (EnT), and halogen-atom transfer (XAT). Furthermore, it discusses the underlying mechanisms, representative synthetic applications, and existing challenges associated with these reactions. Finally, the review provides an outlook on future directions for effectively harnessing gem-diboryl radicals in modern synthesis.
- gem-Diboryl radical,
- Single-electron transfer,
- Energy transfer,
- Halogen-atom transfer
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沈阳化工大学材料科学与工程学院沈阳 110142