Citation: Weiqiang Zhang, Ya Chu, Baoye Hu, Longjun Xu, Guangjiu Zhao, Yan Sun, Longqing Xu, Jinsheng Zhao. Lead-free perovskites for photocatalysis: Synthesis, mechanisms and applications[J]. Chinese Chemical Letters, ;2026, 37(12): 112747. doi: 10.1016/j.cclet.2026.112747 shu

Lead-free perovskites for photocatalysis: Synthesis, mechanisms and applications

Weiqiang Zhang ^{a, 1*,} ,
Ya Chu ^{b, 1} ,
Baoye Hu ^b ,
Longjun Xu ^b ,
Guangjiu Zhao ^c ,
Yan Sun ^{d, *,} ,
Longqing Xu ^b ,
Jinsheng Zhao ^{a, *,}

a.
College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China
b.
School of Physics Science and Information Technology, Liaocheng University, Liaocheng 252059, China
c.
Micro-Nano Multiscales Water Science and Green Hydrogen Energy Technology Innovation Research Center, National Engineering Research Center of Water Resources Efficient Utilization and Engineering Safety, Institute of Water Science and Technology, School of Renewable Energy, Hohai University, Nanjing 210098, China
d.
Key Laboratory of Advanced Electrode Materials for Novel Solar Cells for Petroleum and Chemical Industry of China, School of Chemistry and Life Sciences, Suzhou University of Science and Technology, Suzhou 215009, China

zhangweiqiang@lcu.edu.cn

juzi147@163.com

zhaojinsheng@lcu.edu.cn

Received Date: 3 November 2025
Revised Date: 31 March 2026
Accepted Date: 7 April 2026
Available Online: 9 April 2026

Figures(18)

Metal halide perovskites have become very promising optoelectronic materials because of their excellent photophysical features such as wide absorption spectra, adjustable band structures and long diffusion lengths of charge carriers. However, the conventional lead-based perovskites cannot be deployed in practice because of their intrinsic toxicity and lack of stability at room temperature. These drawbacks have triggered a series of studies on lead-free perovskite substitutes, which can be more environmentally friendly and structurally resilient. Specifically, new developments in lead-free halide perovskites have created new possibilities in photocatalysis, allowing their use in solar-to-chemical energy conversion and photocatalytic organic reactions. The present review is a systematic overview of the current advancements in lead-free perovskite photocatalysts and outlines some of the challenges faced and the fundamental constraints in the current state, as well as provides some insight into the future research directions and possible applications.
- Lead-free perovskites,
- Stability,
- Synthesis method,
- Photocatalytic mechanism,
- Photocatalysis
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沈阳化工大学材料科学与工程学院沈阳 110142