Citation: Xu Guo, Dandan Yang, Zhongyu He, Jie Ding, Lan Ding, Daqian Song. Construction of porous molecularly imprinted polymer on amylose for selective adsorption of estradiol[J]. Chinese Chemical Letters, ;2026, 37(5): 111927. doi: 10.1016/j.cclet.2025.111927 shu

Construction of porous molecularly imprinted polymer on amylose for selective adsorption of estradiol

Xu Guo ^a ,
Dandan Yang ^a ,
Zhongyu He ^a ,
Jie Ding ^b ,
Lan Ding ^{a, *,} ,
Daqian Song ^a

a.
College of Chemistry, Jilin Province Research Center for Engineering and Technology of Spectral Analytical Instruments, Jilin University, Changchun 130012, China
b.
State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China

dinglan@jlu.edu.cn

Received Date: 25 March 2025
Revised Date: 6 July 2025
Accepted Date: 29 September 2025
Available Online: 29 September 2025

Figures(5)

The preparation of porous molecularly imprinted polymers (MIPs) from starch, a natural product, presents significant challenges. In this study, we developed a straightforward method for preparing porous MIPs (DFP-MIPs) by crosslinking short amylose as a functional monomer with decafluorobiphenyl (DFP) as a cross-linker. Experimental results indicated that DFP-MIPs exhibited a larger specific surface area (14.06 m²/g) and adsorption capacity (26.3 mg/g), and a high imprinting factor of 3.14 for estradiol (E2), compared to MIPs prepared using tetrafluorobenzenediamine with a single benzene ring as the cross-linker. A method for detecting E2 in milk and meat samples was also established using DFP-MIPs as the adsorbent in conjunction with high-performance liquid chromatography. Under optimal conditions, this method demonstrated a linear range of 0.0200–0.400 µg/g, a detection limit of 0.00300 µg/g, and a recovery rate of 85.2% to 101.4%. The proposed method for preparing DFP-MIPs is expected to provide a new pathway for the development of porous and highly selective MIPs using amylose.
- Molecularly imprinted polymers,
- Porous materials,
- Amylose,
- Decafluorobiphenyl,
- 17β-Estradiol
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沈阳化工大学材料科学与工程学院沈阳 110142