Citation: Xiafeng Yang, Wushan Sun, Chen Li, Wei Bai, Qingyin Wang, Gongying Wang. Synthesis of novel isosorbide-based polycarbonates by melt chain extension method[J]. Chinese Chemical Letters, ;2026, 37(4): 111674. doi: 10.1016/j.cclet.2025.111674 shu

Synthesis of novel isosorbide-based polycarbonates by melt chain extension method

Xiafeng Yang ^{a, b} ,
Wushan Sun ^a ,
Chen Li ^a ,
Wei Bai ^{a, b, *,} ,
Qingyin Wang ^{a, b} ,
Gongying Wang ^{a, b, *,}

a.
Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041 China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

baiwei@cioc.ac.cn

wanggongying1102@126.com

Received Date: 25 April 2025
Revised Date: 29 July 2025
Accepted Date: 5 August 2025
Available Online: 8 August 2025

Figures(4)

The melt-transesterification polycondensation method necessitates elevated reaction temperatures and protracted reaction times in the copolymerization of modified isosorbide-based polycarbonates. This results in a decline in molecular weight and color degradation of the copolymerized IS-PC. In this paper, the process of polyethylene glycol (PEG) modification was introduced in the synthesis of isosorbide-based copolycarbonate (PE_XHDC_YC) by means of a melt chain extension method. As demonstrated by experimental findings, this method has the capacity to reduce the reaction temperature and shorten the reaction time. Additionally, it has been observed to enhance the molecular weight and overall properties of the material. Through the optimization of reaction conditions, a series of PE_XHDC_YC with weight average molecular weight (M_w) ranging from 19,004 g/mol to 73,294 g/mol were synthesized. The results demonstrated that the glass transition temperature (T_g) of PE_XHDC_YC decreased in conjunction with an increase in the PEG₁₀₀₀ content. It is noteworthy that the PE_XHDC_YC synthesized by this method exhibits an exceptional elongation at break, reaching up to 135.45% ± 24%. Furthermore, PE_XHDC_YC demonstrates superior optical properties in comparison to bisphenol A polycarbonate (BPA-PC).
- Isosorbide-based polycarbonate,
- Melt chain extension method,
- Mechanical properties,
- Optical properties
1. [1]
  K.L. Xie, Y.H. Su, C.X. Zhang, Chin. Chem. Lett. 22 (2011) 1447–1450. doi: 10.1016/j.cclet.2011.07.021
2. [2]
  B.T. Wang, F.D. Lu, F. Xu, et al., Chin. Chem. Lett. 27 (2016) 875–878. doi: 10.1016/j.cclet.2016.01.030
3. [3]
  B.A.J. Noordover, D. Havenman, R. Duchateau, R.A.T.M. Benthem, C.E. Koning, J. Appl. Polym. Sci. 121 (2011) 1450–1463. doi: 10.1002/app.33660
4. [4]
  Q. Li, W. Zhu, C. Li, et al., J. Polym. Sci. Pol. Chem. 51 (2013) 1387–1397. doi: 10.1002/pola.26507
5. [5]
  Y.S. Eo, H.W. Rhee, S. Shin, J. Ins. Eng. Chem. 37 (2016) 42–46. doi: 10.1016/j.jiec.2016.03.007
6. [6]
  W. Sun, F. Xu, W. Cheng, et al., Chin. J. Catal. 38 (2017) 908–917. doi: 10.1016/S1872-2067(17)62822-5
7. [7]
  M. Zhang, W. Lai, L. Su, G. Wu, Ind. Eng. Chem. Res. 57 (2018) 4824–4831. doi: 10.1021/acs.iecr.8b00241
8. [8]
  D.J. Saxon, A.M. Luke, H. Sajjad, W.B. Tolman, T.M. Reinekea, Prog. Polym. Sci. 101 (2019) 101196.
9. [9]
  M. Zhang, W. Lai, L. Su, Y. Lin, G. Wu, Polym. Chem. 10 (2019) 3380–3389. doi: 10.1039/C9PY00331B
10. [10]
  M. Miyashita, M. Yamaguchi, Polymer 202 (2020) 122713. doi: 10.1016/j.polymer.2020.122713
11. [11]
  W. Qian, L. Liu, Z. Zhang, et al., Green Chem. 22 (2020) 2488–2497. doi: 10.1039/D0GC00493F
12. [12]
  T. Abe, R. Takashima, T. Kamiya, et al., Green Chem. 23 (2021) 9030–9037. doi: 10.1039/D1GC02327F
13. [13]
  O. Gómez-de-miranda-jiménez-de-aberasturi, A. Centeno-Pedrazo, S.P. Fernández, et al., Green Chem. Lett. Rev. 14 (2021) 534–544. doi: 10.1080/17518253.2021.1965223
14. [14]
  W. Wang, Z. Yang, Y. Zhang, et al., Green Chem. 23 (2021) 4134–4143. doi: 10.1039/D1GC01150B
15. [15]
  H. Wang, F. Xu, Z. Zhang, et al., RSC Sustain. 1 (2023) 2162–2179. doi: 10.1039/D3SU00248A
16. [16]
  W. Lai, G. Wu, React. Funct. Polym. 143 (2019) 104328. doi: 10.1016/j.reactfunctpolym.2019.104328
17. [17]
  W. Lai, G. Wu, Polym. Degrad. Stabil. 162 (2019) 201–212. doi: 10.1016/j.polymdegradstab.2019.02.020
18. [18]
  S.A. Park, J. Choi, S. Ju, et al., Polymer 116 (2017) 153–159. doi: 10.1016/j.polymer.2017.03.077
19. [19]
  C.H. Lee, H. Takagi, H. Okamoto, M. Kato, J. Appl. Polym. Sci. 127 (2013) 530–534. doi: 10.1002/app.37838
20. [20]
  C. Ma, F. Xu, W. Cheng, et al., ACS Sustain. Chem. Eng. 6 (2018) 2684–2693. doi: 10.1021/acssuschemeng.7b04284
21. [21]
  X. Shen, S. Liu, Q. Wang, H. Zhang, G. Wang, Chem. Res. Chinses U. 35 (2019) 721–728. doi: 10.1007/s40242-019-8356-6
22. [22]
  S. Yum, H. Kim, Y. Seo, Polymer 179 (2019) 121685. doi: 10.1016/j.polymer.2019.121685
23. [23]
  Z. Zhang, F. Xu, H. He, et al., Green Chem. 21 (2019) 3891–3901. doi: 10.1039/C9GC01500K
24. [24]
  J. Chu, H. Wang, Y. Zhang, et al., React. Funct. Polym. 170 (2022) 105145. doi: 10.1016/j.reactfunctpolym.2021.105145
25. [25]
  Y. Zhang, C. Li, H. Wang, et al., Polymer 313 (2024) 127729. doi: 10.1016/j.polymer.2024.127729
26. [26]
  M. Durand, Y. Zhu, V. Molinier, T. Fŕron, J.M. Aubry, J. Surfact. Deterg. 12 (2009) 371–378. doi: 10.1007/s11743-009-1128-4
27. [27]
  L. Feng, W. Zhu, C. Li, et al., Polym. Chem. 6 (2015) 633–642. doi: 10.1039/C4PY00976B
28. [28]
  F. Aricò, A.S. Aldoshin, P. Tundo, ChemSusChem 10 (2016) 53–57.
29. [29]
  F. Aricò, P. Tundo, Beilstein J. Org. Chem. 12 (2016) 2256–2266. doi: 10.3762/bjoc.12.218
30. [30]
  J.R. Ochoa-Gómez, S. Gil-Río, B. Maestro-Madurga, O. Gómez-Jiménez-Aberasturi, F. Río-Pérez, Arab. J. Chem. 12 (2019) 4764–4774. doi: 10.1016/j.arabjc.2016.09.017
31. [31]
  W. Qian, X. Tan, Q. Su, et al., ChemSusChem 12 (2019) 1169–1178. doi: 10.1002/cssc.201802572
32. [32]
  W. Fang, Z. Zhang, Z. Yang, et al., Green Chem. 22 (2020) 4550–4560. doi: 10.1039/D0GC01440K
33. [33]
  W. Qian, X. Ma, L. Liu, et al., Green Chem. 22 (2020) 5357–5368. doi: 10.1039/D0GC01804J
34. [34]
  Z. Yang, L. Liu, H. An, et al., ACS Sustain. Chem. Eng. 8 (2020) 9968–9979. doi: 10.1021/acssuschemeng.0c00430
35. [35]
  W. Fang, Y. Zhang, Z. Yang, et al., Appl. Catal. A: Gen. 617 (2021) 118111. doi: 10.1016/j.apcata.2021.118111
36. [36]
  W. Wang, Y. Zhang, Z. Yang, et al., Green Chem. 23 (2021) 973–982. doi: 10.1039/D0GC03798B
37. [37]
  Z. Yang, X. Li, F. Xu, et al., Green Chem. 23 (2021) 447–456. doi: 10.1039/D0GC03247F
38. [38]
  M. Jiang, X. Zhang, M. Feng, et al., Carbon Capture Sci. Technol. 13 (2024) 100281.
39. [39]
  L. Zheng, C. Li, D. Zhang, et al., Polym. Int. 60 (2010) 666–675.
40. [40]
  L. Zheng, C. Li, W. Huang, et al., Polym. Adv. Technol. 22 (2011) 279–285. doi: 10.1002/pat.1530
41. [41]
  J. Gong, X.J. Lou, W.D. Li, et al., J. Polym. Sci. Pol. Chem. 48 (2010) 2828–2837. doi: 10.1002/pola.24056
42. [42]
  S. Oh, M.S. Kang, J.C. Knowles, M.S. Gong, J. Biomater. Appl. 30 (2015) 327–337. doi: 10.1177/0885328215590054
43. [43]
  W.J. Yoon, S.Y. Hwang, J.M. Koo, et al., Macromolecules 46 (2013) 7219–7231. doi: 10.1021/ma4015092
44. [44]
  C. Li, Z. Zhang, Z. Yang, et al., React. Funct. Polym. 155 (2020) 104689. doi: 10.1016/j.reactfunctpolym.2020.104689
45. [45]
  X. Yang, X. Long, J. Li, et al., Res. Chem. Intermediat. 50 (2024) 4871–4887. doi: 10.1007/s11164-024-05279-5
46. [46]
  T. Chen, G. Jiang, G. Li, et al., RSC Adv. 5 (2015) 60570–60580. doi: 10.1039/C5RA09252C
47. [47]
  J. Wang, X. Liu, J. Zhu, Macromol. Chem. Phys. 219 (2018) 1800172. doi: 10.1002/macp.201800172
48. [48]
  S. Legrand, N. Jacquel, H. Amedro, et al., Eur. Polym. J. 115 (2019) 22–29. doi: 10.1016/j.eurpolymj.2019.03.018
49. [49]
  L. Gu, J. Lan, Q. Yang, et al., J. Macromol. Sci. A 56 (2019) 871–876. doi: 10.1080/10601325.2019.1617633
50. [50]
  S. Yang, R. Wu, W. Bai, et al., J. Polym. Environ. 33 (2025) 2267–2279. doi: 10.1007/s10924-025-03517-4
51. [51]
  X. Liu, S. Feng, X. Wang, et al., Turk. J. Chem. 44 (2020) 1430–1444. doi: 10.3906/kim-2006-55
52. [52]
  W. Miyano, E. Inoue, M. Tsuchiya, K. Ishimaru, T. Kojima, J. Therm. Anal. Calorim. 64 (2001) 459–465. doi: 10.1023/A:1011553826342
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