Citation: Lu Zhang, Baohua Wang, Wei Yang, Lunan Ju, Zihan Fu, Lei Zhao, Yunqi Jiang, Hongyan Wang, Xiansheng Wang, Cong Lyu. CoOOH@COFs S−scheme heterojunction for efficient triclosan degradation in photocatalytic-peroxymonosulfate activation system: Enhanced interfacial electron transfer mechanism[J]. Chinese Chemical Letters, ;2026, 37(1): 111142. doi: 10.1016/j.cclet.2025.111142 shu

CoOOH@COFs S−scheme heterojunction for efficient triclosan degradation in photocatalytic-peroxymonosulfate activation system: Enhanced interfacial electron transfer mechanism

Lu Zhang ^{a, b} ,
Baohua Wang ^c ,
Wei Yang ^d ,
Lunan Ju ^{a, b} ,
Zihan Fu ^{a, b} ,
Lei Zhao ^e ,
Yunqi Jiang ^f ,
Hongyan Wang ^g ,
Xiansheng Wang ^{a, b, *,} ,
Cong Lyu ^{a, b, *,}

a.
Key Lab of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130026, China
b.
Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130026, China
c.
Shen Zhen LiYuan Water Design & Consultation Co. Ltd., Shenzhen 518000, China
d.
Water Conservancy Project Construction Management Station under Songliao River Water Resources Commission of Ministry of Water Resources, Changchun 130021, China
e.
Department of Agriculture and Rural Affairs of Jilin Province, Changchun 130051, China
f.
Department of Environmental Futures: Sustainable Systems MSc, University of Glasgow, Glasgow G12 8QQ, Scotland, United Kingdom
g.
Songyuan City Ecological Environment Monitoring Center, Songyuan 138001, China

wxs@jlu.edu.cn

lvcong@jlu.edu.cn

Received Date: 29 October 2024
Revised Date: 17 January 2025
Accepted Date: 25 March 2025
Available Online: 26 March 2025

Figures(6)

Triclosan (TCS) poses harmful risks to ecosystems and human health owing to its endocrine-disrupting effects. Therefore, developing an efficient and sustainable technology to degrade TCS is urgently needed. Herein, cobalt oxyhydroxide @covalent organic frameworks (CoOOH@COFs) S−scheme heterojunction was synthesized, which combined the visible-light-driven photocatalysis and peroxymonosulfate (PMS) activation to synergistically generate abundant reactive oxygen species (ROSs) for TCS degradation. The degradation efficiency of TCS reached 100% within 8 min in the Vis-CoOOH@COFs/PMS system, and the reaction rate constant was 0.456 min⁻¹, which was nearly 1.90 and 2.85 times that of single CoOOH and COFs, and 2.36 times that under dark condition, respectively. The density functional theory (DFT) calculations confirmed the energy band bending of CoOOH@COFs and S-scheme charge transport from COFs to CoOOH. Both experimental and theoretical analyses indicated that CoOOH@COFs in photocatalytic-PMS activation systems synergistically facilitated photo-generated carrier separation, enhanced interfacial electron transfer, accelerated PMS activation, and generated multiple ROSs. In particular, photogenerated electrons (e⁻) accelerated the Co(Ⅲ)/Co(Ⅱ) redox cycle, while the PMS captured the e⁻, which significantly decreased the charge combination of CoOOH@COFs. Radicals (O₂^•−, ^•OH, and SO₄^•−) and non-radicals (such as ¹O₂, h⁺, and e⁻) were both presented in the Vis-CoOOH@COFs/PMS system, with O₂⁻ playing a dominant role in TCS degradation. Furthermore, the pathway of TCS degradation and toxicity of intermediates were explored by DFT calculation and transformation product identification. Importantly, the environmentally friendly CoOOH@COFs S−scheme heterojunction exhibited excellent stability and reusability. In conclusion, this study innovatively designed an S−scheme heterojunction in the photocatalytic-PMS activation system, providing guidance and theoretical support for efficient and eco-friendly wastewater treatment.
- Covalent organic frameworks,
- Cobalt oxyhydroxide,
- S−scheme heterojunction,
- Interfacial electron transfer,
- Peroxymonosulfate activation
1. [1]
  Y. Jiang, L. Liu, B. Jin, et al., Sci. Total Environ. 932 (2024) 173013–173028. doi: 10.1016/j.scitotenv.2024.173013
2. [2]
  Z. Wang, X. Li, H. Liu, et al., Crit. Rev. Env. Sci. Tec. 54 (2024) 1340–1363. doi: 10.1080/10643389.2024.2309846
3. [3]
  Y. Guo, W. Shi, Z. Liu, et al., J. Hazard. Mater. 459 (2023) 132289–132299. doi: 10.1016/j.jhazmat.2023.132289
4. [4]
  Q.E. Yang, X. Ma, M. Li, et al., Nat. Commun. 15 (2024) 3654–3666. doi: 10.1038/s41467-024-48006-9
5. [5]
  J.S. Lee, J.S. Lee, H.S. Kim, Sci. Total. Environ. 920 (2024) 170902–170915. doi: 10.1016/j.scitotenv.2024.170902
6. [6]
  L. Huang, W. Zhang, D. Tong, et al., Water Res. 233 (2023) 119736–119752. doi: 10.1016/j.watres.2023.119736
7. [7]
  X. Qian, L. Xu, Y. Zhu, et al., Chem. Eng. J. 420 (2021) 127615–127624. doi: 10.1016/j.cej.2020.127615
8. [8]
  Z. Huang, Q. Lin, N. Cai, et al., Sep. Purif. 276 (2021) 119318–119327. doi: 10.1016/j.seppur.2021.119318
9. [9]
  L.W. Olaniyan, N. Mkwetshana, A.I. Okoh, Springerplus 5 (2016) 1639–1655. doi: 10.1186/s40064-016-3287-x
10. [10]
  M. Bilal, D. Barceló, H.M.N. Iqbal, Sci. Total Environ. 735 (2020) 139194–139206. doi: 10.1016/j.scitotenv.2020.139194
11. [11]
  Z. Huang, Q. Lin, N. Cai, et al., Sep. Purif. 276 (2021) 119318–119326. doi: 10.1016/j.seppur.2021.119318
12. [12]
  X. Li, D. Zhang, Z. Liu, et al., Chem. Eng. J. 400 (2020) 125897–125907. doi: 10.1016/j.cej.2020.125897
13. [13]
  Z.H. Diao, W. Qian, Z.W. Zhang, et al., Chem. Eng. J. 397 (2020) 125382–125390. doi: 10.1016/j.cej.2020.125382
14. [14]
  Q. Zhang, D. He, X. Li, et al., J. Hazard. Mater. 384 (2020) 121350. doi: 10.1016/j.jhazmat.2019.121350
15. [15]
  C. Lyu, D. He, Y. Chang, et al., Sci. Total Environ. 680 (2019) 61–69. doi: 10.1016/j.scitotenv.2019.04.324
16. [16]
  L. Zhang, L. Ju, X. Li, et al., J. Hazard. Mater. 460 (2023) 132403. doi: 10.1016/j.jhazmat.2023.132403
17. [17]
  J. Huang, Q. Shang, Y. Huang, et al., Angew. Chem. Int. Ed. 55 (2016) 2137–2141. doi: 10.1002/anie.201510642
18. [18]
  L. Shi, K. Zhao, S. Liu, Mater. Lett. 228 (2018) 121–124. doi: 10.1016/j.matlet.2018.05.134
19. [19]
  Q. Yi, J. Tan, W. Liu, et al., Chem. Eng. J. 400 (2020) 125965–125973. doi: 10.1016/j.cej.2020.125965
20. [20]
  M. Wang, G. Tan, H. Ren, et al., Appl. Surf. Sci. 492 (2019) 690–702. doi: 10.1016/j.apsusc.2019.06.260
21. [21]
  R. Chong, Z. Wang, J. Lv, et al., J. Catal. 399 (2021) 170–181. doi: 10.1016/j.jcat.2021.05.006
22. [22]
  Z. Wang, L. Huang, Y. Wang, et al., Environ. Res. 193 (2021) 110537–110547. doi: 10.1016/j.envres.2020.110537
23. [23]
  H.B. Qiu, P.C. Guo, L. Yuan, et al., Chin. Chem. Lett. 31 (2020) 2614–2618. doi: 10.1016/j.cclet.2020.08.014
24. [24]
  P. Sun, H. Liu, M. Feng, et al., Appl. Catal. B: Environ. 272 (2020) 119005–119015. doi: 10.1016/j.apcatb.2020.119005
25. [25]
  Y. Gao, C. Zhi, P. Cui, et al., Chem. Eng. J. 400 (2020) 125967–125977. doi: 10.1016/j.cej.2020.125967
26. [26]
  M. Liu, K. Jiang, X. Ding, et al., Adv. Mater. 31 (2019) 1807865–1807871. doi: 10.1002/adma.201807865
27. [27]
  Z. Tan, P. Zhang, Q. Chen, et al., Catal. Sci. Technol. 11 (2021) 1874–1880. doi: 10.1039/d0cy02094j
28. [28]
  G. Li, J. Ye, Y. Shen, et al., Chem. Eng. J. 421 (2021) 127784–127794. doi: 10.1016/j.cej.2020.127784
29. [29]
  Y. He, X. Chen, C. Huang, et al., Chin. J. Catal. 42 (2021) 123–130. doi: 10.1117/12.2589522
30. [30]
  Z. Cheng, K. Zheng, G. Lin, et al., Nanoscale adv. 1 (2019) 2674–2680. doi: 10.1039/c9na00089e
31. [31]
  W. Chen, L. Wang, D. Mo, et al., Angew. Chem. Int. Ed. 59 (2020) 16902–16909. doi: 10.1002/anie.202006925
32. [32]
  D. Cao, J. Guan, J. Du, et al., J. Hazard. Mater. 476 (2024) 134956–134965. doi: 10.1016/j.jhazmat.2024.134956
33. [33]
  H. Ye, Z. Wang, F. Yu, et al., Appl. Catal. B: Environ. 267 (2020) 118577–118588. doi: 10.1016/j.apcatb.2019.118577
34. [34]
  P.B. Pati, G. Damas, L. Tian, et al., Energy Environ. Sci. 10 (2017) 1372–1376. doi: 10.1039/C7EE00751E
35. [35]
  C. Matei Ghimbeu, K. Guerin, M. Dubois, et al., Carbon 84 (2015) 567–583. doi: 10.1016/j.carbon.2014.12.034
36. [36]
  Z. Zheng, J. Min, X. Wang, et al., Environ. Sci. Technol. 57 (2023) 8414–8425. doi: 10.1021/acs.est.2c09122
37. [37]
  Y. Zhong, S. Ma, D. Chen, et al., Water. Res. 258 (2024) 121774–121785. doi: 10.1016/j.watres.2024.121774
38. [38]
  G. Xu, L. Hou, C. Liu, et al., ACS Appl. Mater. Interfaces 13 (2021) 51535–51545. doi: 10.1021/acsami.1c15869
39. [39]
  Q. Liao, C. Ke, X. Huang, et al., J. Mater. Chem. A 7 (2019) 18959–18970. doi: 10.1039/c9ta06214a
40. [40]
  J. Liu, H. Liu, Q. Pan, et al., Colloids. Surf. 655 (2022) 130314–130324. doi: 10.1016/j.colsurfa.2022.130314
41. [41]
  D.E. Zhang, L.Z. Ren, X.Y. Hao, et al., Appl. Surf. Sci. 355 (2015) 547–552. doi: 10.1016/j.apsusc.2015.04.018
42. [42]
  X. Li, L. Zhang, S. Niu, et al., J. Hazard. Mater. 444 (2023) 130366–130377. doi: 10.1016/j.jhazmat.2022.130366
43. [43]
  M. Yao, M. Xie, S. Zhang, et al., Sep. Purif. 302 (2022) 122145–122155. doi: 10.1016/j.seppur.2022.122145
44. [44]
  H. Zeng, H. Zhu, J. Deng, et al., Chem. Eng. J. 442 (2022) 136251–136261. doi: 10.1016/j.cej.2022.136251
45. [45]
  Z. Zhang, X. Zhan, B. Hong, et al., J. Colloid. Interf. Sci. 663 (2024) 909–918. doi: 10.1016/j.jcis.2024.03.010
46. [46]
  M. Xiong, B. Chai, G. Fan, et al., J. Colloid. Interf. Sci. 638 (2023) 412–426. doi: 10.1016/j.jcis.2023.02.002
47. [47]
  X. Li, Z. Liu, Y. Zhu, et al., Sci. Total. Environ. 749 (2020) 141466–141478. doi: 10.1016/j.scitotenv.2020.141466
48. [48]
  Y. d. Chen, X. Duan, C. Zhang, et al., Chem. Eng. J. 384 (2020) 123244–123254. doi: 10.1016/j.cej.2019.123244
49. [49]
  J. Qin, L. Dai, P. Shi, et al., J. Hazard. Mater. 398 (2020) 122808–122815. doi: 10.1016/j.jhazmat.2020.122808
50. [50]
  Y. Yang, P. Zhang, K. Hu, et al., Appl. Catal. B: Environ. 286 (2021) 119903–119913. doi: 10.1016/j.apcatb.2021.119903
51. [51]
  W. Ren, L. Xiong, G. Nie, et al., Environ. Sci. Technol. 54 (2020) 1267–1275. doi: 10.1021/acs.est.9b06208
52. [52]
  P. Shao, S. Yu, X. Duan, et al., Environ. Sci. Technol. 54 (2020) 8464–8472. doi: 10.1021/acs.est.0c02645
53. [53]
  S. Li, J. Huang, X. Li, et al., Chem. Eng. J. 398 (2020) 125529–125538. doi: 10.1016/j.cej.2020.125529
54. [54]
  J. Li, J. Chen, Y. Ao, et al., Sep. Purif. 281 (2022) 119863–119875. doi: 10.1016/j.seppur.2021.119863
55. [55]
  S. Wang, J. Wang, Chem. Eng. J. 356 (2019) 350–358. doi: 10.1016/j.cej.2018.09.062
1. [1]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
2. [2]
  Xian-Rui Meng , Qian Chen , Mei-Feng Wu , Qiang Wu , Su-Qin Wang , Li-Ping Jin , Fan Zhou , Ren-Li Ma , Jian-Ping Zou . Nano-flowers FeS/MoS2 composites as a peroxymonosulfate activator for efficient p-chlorophenol degradation. Chinese Journal of Structural Chemistry, 2025, 44(3): 100543-100543. doi: 10.1016/j.cjsc.2025.100543
3. [3]
  Jiaqi Ma , Lan Li , Yiming Zhang , Jinjie Qian , Xusheng Wang . Covalent organic frameworks: Synthesis, structures, characterizations and progress of photocatalytic reduction of CO2. Chinese Journal of Structural Chemistry, 2024, 43(12): 100466-100466. doi: 10.1016/j.cjsc.2024.100466
4. [4]
  Chunrui Zhao , Tianren Li , Jiage Li , Yansong Liu , Zian Fang , Xinyu Wang , Mingxin Huo , Shuangshi Dong , Mingyu Li . Doped cobalt for simultaneously promoting active (001) facet exposure of MIL-68(In) and acting as reactive sites in peroxymonosulfate-mediated photocatalytic decontamination. Chinese Chemical Letters, 2025, 36(5): 110201-. doi: 10.1016/j.cclet.2024.110201
5. [5]
  Yuting Wu , Haifeng Lv , Xiaojun Wu . Design of two-dimensional porous covalent organic framework semiconductors for visible-light-driven overall water splitting: A theoretical perspective. Chinese Journal of Structural Chemistry, 2024, 43(11): 100375-100375. doi: 10.1016/j.cjsc.2024.100375
6. [6]
  Cunjun Li , Wencong Liu , Xianlei Chen , Liang Li , Shenyu Lan , Mingshan Zhu . Adsorption and activation of peroxymonosulfate on BiOCl for carbamazepine degradation: The role of piezoelectric effect. Chinese Chemical Letters, 2024, 35(10): 109652-. doi: 10.1016/j.cclet.2024.109652
7. [7]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
8. [8]
  Yujie Wang , Haoran Wang , Yanni Liu , Manhua Peng , Hongwei Fan , Hong Meng . A comprehensive review on the scalable and sustainable synthesis of covalent organic frameworks. Chinese Chemical Letters, 2025, 36(8): 110189-. doi: 10.1016/j.cclet.2024.110189
9. [9]
  Liying Ou , Zhenluan Xue , Bo Li , Zhiwei Jin , Jiaochan Zhong , Lixia Yang , Penghui Shao , Shenglian Luo . Nitrogen-containing linkage-bonds in covalent organic frameworks: Synthesis and applications. Chinese Chemical Letters, 2025, 36(6): 110294-. doi: 10.1016/j.cclet.2024.110294
10. [10]
  Bo Li , Yuanzhe Cheng , Xuyang Ma , Dongxu Zhao , Yang Zhang , Yongxing Sun , Jia Chen , Li Wu , Liang Zhao , Hongdeng Qiu , Yujian He . Facile and scale-up synthesis of cyano-functionalized covalent organic frameworks for selective gold recovery. Chinese Chemical Letters, 2026, 37(1): 111134-. doi: 10.1016/j.cclet.2025.111134
11. [11]
  Shiyan Ai , Yaning Xu , Hui Zhou , Ziwei Cui , Tiantian Wu , Dan Tian . Superelastic and ultralight covalent organic framework composite aerogels modified with different functional groups for ultrafast adsorbing organic pollutants in water. Chinese Chemical Letters, 2025, 36(10): 110761-. doi: 10.1016/j.cclet.2024.110761
12. [12]
  Guorong Li , Yijing Wu , Chao Zhong , Yixin Yang , Zian Lin . Predesigned covalent organic framework with sulfur coordination: Anchoring Au nanoparticles for sensitive colorimetric detection of Hg(Ⅱ). Chinese Chemical Letters, 2024, 35(5): 108904-. doi: 10.1016/j.cclet.2023.108904
13. [13]
  Yue Qian , Zhoujia Liu , Haixin Song , Ruize Yin , Hanni Yang , Siyang Li , Weiwei Xiong , Saisai Yuan , Junhao Zhang , Huan Pang . Imide-based covalent organic framework with excellent cyclability as an anode material for lithium-ion battery. Chinese Chemical Letters, 2024, 35(6): 108785-. doi: 10.1016/j.cclet.2023.108785
14. [14]
  Ning Liu , Man Tian , Ye Zhang , Jinming Yang , Zhihao Wang , Wangxi Dai , Guixiang Quan , Jianqiu Lei , Xiaodong Zhang , Liang Tang . Three-dimensional MIL-88A(Fe)-derived α-Fe₂O₃ and graphene composite for efficient photo-Fenton-like degradation of ciprofloxacin. Chinese Chemical Letters, 2025, 36(12): 111063-. doi: 10.1016/j.cclet.2025.111063
15. [15]
  Lina Zou , Dengke Wang , Shiqin Lai , Xunheng Jiang , Siqi Chen , Lanqing Deng , Dong Fan , Hengshuai Li , Zhigang Zhou , Denglong Chen , Xiangyang Yao , Jianping Zou . Local spin-state manipulation of iron single-atom sites induced by sulfur modification to boost Fenton-like reaction. Chinese Chemical Letters, 2025, 36(12): 111094-. doi: 10.1016/j.cclet.2025.111094
16. [16]
  Ming Yue , Yi-Rong Wang , Jia-Yong Weng , Jia-Li Zhang , Da-Yu Chi , Mingjin Shi , Xiao-Gang Hu , Yifa Chen , Shun-Li Li , Ya-Qian Lan . Multi-metal porous crystalline materials for electrocatalysis applications. Chinese Chemical Letters, 2025, 36(6): 110049-. doi: 10.1016/j.cclet.2024.110049
17. [17]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
18. [18]
  Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458
19. [19]
  Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327
20. [20]
  Huiyuan Deng , Na Zhao , Junjie You , Zhicheng Pan , Bo Xing , Yuling Ye , Bo Lai , Yuxi Wang , Tongrui Lu , Xiaonan Liu . Removal of bisphenol a through peroxymonosulfate activation with N-doped graphite carbon spheres coated cobalt nanoparticles catalyst: Synergy of nonradicals. Chinese Chemical Letters, 2025, 36(8): 110650-. doi: 10.1016/j.cclet.2024.110650

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(8)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142