Citation: Chun-Ying Xu, Xiao-Lin Luan, Yuan-Yuan Cui, Cheng-Xiong Yang. One-pot in situ doping synthesis of phenylboronic acid-functionalized magnetic-cyclodextrin microporous organic network for specific enrichment and detection of sulfonylurea herbicides[J]. Chinese Chemical Letters, ;2025, 36(9): 110937. doi: 10.1016/j.cclet.2025.110937 shu

One-pot in situ doping synthesis of phenylboronic acid-functionalized magnetic-cyclodextrin microporous organic network for specific enrichment and detection of sulfonylurea herbicides

School of Pharmaceutical Sciences, Medical Science and Technology Innovation Center, Shandong First Medical University & Shandong Academy of Medical Sciences, Ji’nan 250117, China

Received Date: 8 July 2024
Revised Date: 13 October 2024
Accepted Date: 8 February 2025
Available Online: 8 February 2025

Figures(5)

Microporous organic networks (MONs) are attractive adsorbents for use in sample pretreatment owning to their unique structure and properties. However, methods for constructing functional MONs are still limited because the lack of monomers via direct synthesis and their complex procedures via post-modification. To address this issue, a facile one-pot in situ doping strategy was proposed herein for synthesis a novel phenylboronic acid-functionalized magnetic cyclodextrin-based microporous organic network ([PBA]_3/4−MCD-MON-0.04). [PBA]_3/4−MCD-MON-0.04 was used for the selective and efficient extraction of sulfonylurea herbicides (SUHs) from complex food and environmental water samples via the synergistic hydrogen bonding, host-guest, hydrophobic and π-π interactions and the specific B-N coordination. [PBA]_3/4−MCD-MON-0.04 had a large surface area, high saturation magnetism, good reusability, and remarkable stability. A rapid, sensitive, and selective method was proposed for monitoring SUHs from diverse matrices. This study provides a new strategy for synthesizing novel and multifunctional magnetic CD-MONs-based adsorbents and reveals the considerable potential of CD-MONs in sample pretreatment.
- Cyclodextrin microporous organic network,
- Magnetic solid phase extraction,
- In situ doping,
- Sulfonylurea herbicide,
- B-N coordination
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