Citation: Lu Cheng, Jinghua Quan, Hongyan Li. Recent advances in antimony-based anode materials for potassium-ion batteries: Material selection, structural design and storage mechanisms[J]. Chinese Chemical Letters, ;2025, 36(9): 110685. doi: 10.1016/j.cclet.2024.110685 shu

Recent advances in antimony-based anode materials for potassium-ion batteries: Material selection, structural design and storage mechanisms

Department of Materials Science and Engineering, College of Chemistry and Materials Science, Jinan University, Guangzhou 510632, China

lihongyan@jnu.edu.cn

Received Date: 12 September 2024
Revised Date: 24 November 2024
Accepted Date: 26 November 2024
Available Online: 27 November 2024

Figures(18)

Thanks to its abundant reserves, relatively high energy density, and low reduction potential, potassium ion batteries (PIBs) have a high potential for large-scale energy storage applications. Due to the large radius of potassium ions, most conventional anode materials undergo severe volume expansion, making it difficult to achieve stable and reversible energy storage. Therefore, developing high-performance anode materials is one of the critical factors in developing PIBs. In this sense, antimony (Sb)-based anode materials with high theoretical capacity and safe reaction potentials have a broad potential for application in PIBs. However, overcoming the rapid capacity decay induced by the large radius of potassium ions is still an issue that needs to be focused on. This paper reviews the latest research on different types of Sb-based anode materials and provides an in-depth analysis of their optimization strategies. We focus on material selection, structural design, and storage mechanisms to develop a detailed description of the material. In addition, the current challenges still faced by Sb-based anode materials are summarized, and some further optimization strategies have been added. We hope to provide some insights for researchers developing Sb-based anode materials for next-generation advanced PIBs.
- Antimony-based anode,
- Potassium ion batteries,
- Materials selection,
- Potassium storage mechanism,
- Structure design
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沈阳化工大学材料科学与工程学院沈阳 110142