Citation: Hanhan Chen, Yahao Sun, Mingyang Zhang, Pengtao Ma, Jingping Wang, Jingyang Niu. Self-assembly of cis-trans Ta/W mixed-addendum POMs based on hexalacunary [H₂P₂W₁₂O₄₈]¹²⁻ building blocks[J]. Chinese Chemical Letters, ;2025, 36(9): 110329. doi: 10.1016/j.cclet.2024.110329 shu

Self-assembly of cis-trans Ta/W mixed-addendum POMs based on hexalacunary [H₂P₂W₁₂O₄₈]¹²⁻ building blocks

Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Molecular Sciences, Henan University, Kaifeng 475004, China

jpwang@henu.edu.cn

jyniu@henu.edu.cn

Received Date: 2 July 2024
Revised Date: 22 July 2024
Accepted Date: 8 August 2024
Available Online: 10 August 2024

Figures(4)

The synthesis of Ta-substituted polyoxometalates has always been an attractive but challenging goal. Three novel tantalum-containing 12-tungsto-2-phosphates were successfully prepared using the water bath method. The monomer, K₁₁Li[P₂W₁₂(TaO₂)₆O₅₆]·19H₂O (1), is composed of {P₂W₁₂} and 6 {Ta(O₂)} building blocks, similar to [P₂W₁₂(NbO₂)₆O₅₆]¹²⁻. Monomer 1 polymerized to form two cis-trans dimers, K₁₃Li₆H-cis-[P₂W₁₂Ta₄(TaO₂)₂O₅₉]₂·61H₂O (2) and KNa₃Li₄H₁₂-trans-[P₂W₁₂Ta₄(TaO₂)₂O₅₉]₂·37H₂O (3). Compounds 1–3 can serve as a structural motif to manufacture additional fascinating molecular clusters, promoting the advancement of POM chemistry. In contrast to [P₂W₁₂(NbO₂)₆O₅₆]¹²⁻, compound 1 exhibits exceptional stability, evidenced by ESI-MS, IR, and NMR spectroscopy. In addition, 2 and 3 exhibit high proton conductivity and superior water adsorption properties.
- Polyoxometalates,
- Cis-trans isomerism,
- Hexalacunary {P₂W₁₂},
- Ta/W mixed-addendum POMs,
- Proton-conductive materials
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沈阳化工大学材料科学与工程学院沈阳 110142

Self-assembly of cis-trans Ta/W mixed-addendum POMs based on hexalacunary [H2P2W12O48]12− building blocks

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通讯作者: 陈斌, bchen63@163.com

Self-assembly of cis-trans Ta/W mixed-addendum POMs based on hexalacunary [H₂P₂W₁₂O₄₈]¹²⁻ building blocks