Citation: Xiaoqin Li, Xiaohan Chen, Yongqiang Guo, Jian Xiang, Yinkun Zhao, Taotao Gao, Qu Yue, Wenlong Liu, Lu Qiu, Dan Xiao, Panpan Li. Regulating zincophilic sites and electric field distribution to achieve reversible zinc plating/stripping for high-performance flexible Zn-ion batteries[J]. Chinese Chemical Letters, ;2025, 36(9): 110327. doi: 10.1016/j.cclet.2024.110327 shu

Regulating zincophilic sites and electric field distribution to achieve reversible zinc plating/stripping for high-performance flexible Zn-ion batteries

Xiaoqin Li ^a ,
Xiaohan Chen ^b ,
Yongqiang Guo ^b ,
Jian Xiang ^b ,
Yinkun Zhao ^b ,
Taotao Gao ^a ,
Qu Yue ^a ,
Wenlong Liu ^{c, *,} ,
Lu Qiu ^{c, *,} ,
Dan Xiao ^{a, *,} ,
Panpan Li ^{d, *,}

a.
Institute for Advanced Study, Chengdu University, Chengdu 610106, China
b.
School of Mechanical Engineering, Chengdu University, Chengdu 610106, China
c.
College of Food and Biological Engineering, Chengdu University, Chengdu 610106, China
d.
College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China

iuwenlong_666@126.com

qiulu@cdu.edu.cn

xiaodan@scu.edu.cn

panpanli@scu.edu.cn

Received Date: 28 June 2024
Revised Date: 12 July 2024
Accepted Date: 8 August 2024
Available Online: 10 August 2024

Figures(4)

Here, we present a regulation strategy involving heteroatom doping and structural construction to adjust zincophilic sites and electric field distribution, achieving a robust and dendrite-free Zn host anode. Theoretical calculations and experimental results confirm that sulfur atoms can provide moderate zincophilicity, while graphene-like nanosheets can even the electric field distribution, imparting the sulfur-doped graphene-like network (S-GP) with a longer lifespan (exceeding 500 h) and acceptable coulombic efficiency. Importantly, the S-GP host is used as the substrate for flexible Zn-ion batteries, exhibiting impressive electrochemical performance and great mechanical flexibility, indicating a broad application prospect in portable and wearable electronic devices.
- Flexible Zn-ion batteries,
- Graphene-like network,
- Sulfur-doped substrate,
- Zincophilic site,
- Electric field distribution
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