Citation: Wen-Xuan Song, Yao-Yu Cai, Ying-Jie Liu, Shuang-Quan Zang. Cation-driven assembly of gold(Ⅰ) tweezers towards lighted circularly polarized phosphorescence[J]. Chinese Chemical Letters, ;2025, 36(9): 110326. doi: 10.1016/j.cclet.2024.110326 shu

Cation-driven assembly of gold(Ⅰ) tweezers towards lighted circularly polarized phosphorescence

Henan Key Laboratory of Crystalline Molecular Functional Materials and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

yingjieliu@zzu.edu.cn

Received Date: 28 June 2024
Revised Date: 18 July 2024
Accepted Date: 8 August 2024
Available Online: 10 August 2024

Figures(6)

Non-covalent interactions-driven host-guest assembly based on metallo-tweezers has been used to construct varied optical functional materials with attractive structures and properties. We reported here two pairs of chiral gold(Ⅰ)-based metallo-tweezers as hosts to clip Ag^Ⅰ or Cu^Ⅰ cations for circularly polarized phosphorescence (CPP), driven by the integration of two-fold coordination and heterometallophilic interactions. The Au^Ⅰ-based hosts and metal ions-guests formed sandwich structures in 1:1 ratio with high binding affinity. The achieved tweezer/cation adducts exhibited red-shifted absorption bands and circular dichroism signals, which were attributed to the newly formed ligand to metal-metal charge transfer process. Remarkably, the host-guest supramolecular adducts showed turn-on phosphorescence and CPP, which benefited from rigidifying effect of multiple intermolecular interactions and shorter excited-state lifetime. Overall, our findings bring new insights into the feasibility to achieve and modulate CPP performance by fabricating metallo-tweezer-based host-guest complexes.
- Gold(Ⅰ) tweezers,
- Host-guest assembly,
- Heterometallophilic interactions,
- Coordination interactions,
- Circularly polarized phosphorescence
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