Citation: Xiaodong Wang, Miaomiao Zhou, Yirui Deng, Zijun Liu, Huiyou Dong, Peng Yan, Ruiping Liu. Dual functional Ti₃(PO₄)₄-coated NCM811 cathode enables highly stable sulfide-based all-solid-state lithium batteries[J]. Chinese Chemical Letters, ;2025, 36(9): 110307. doi: 10.1016/j.cclet.2024.110307 shu

Dual functional Ti₃(PO₄)₄-coated NCM811 cathode enables highly stable sulfide-based all-solid-state lithium batteries

School of Chemical & Environmental Engineering, China University of Mining & Technology (Beijing), Beijing 100083, China

lrp@cumtb.edu.cn

Received Date: 14 June 2024
Revised Date: 11 July 2024
Accepted Date: 30 July 2024
Available Online: 31 July 2024

Figures(5)

Nickel-rich layered oxide cathode materials such as LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) undergo deleterious side reactions when coupled with sulfide solid-state electrolytes (SSEs). To address this issue, we propose a dual-functional Ti₃(PO₄)₄ coating for NCM811 cathode to achieve a highly stable interface between NCM811 and sulfide SSEs. The electrochemically stabilized Ti₃(PO₄)₄ coating prevents direct contact between the SSEs and NCM811, thereby inhibiting interfacial side reactions. In addition, the internal structure of NCM811 can be stabilized by Ti doping, which inhibits the oxygen release behavior of NCM811 at high charge state, preventing further electrochemical oxidation of the SSEs. The modified NCM811@TiP cathode exhibits excellent long cycle stability, with 74.4% capacity retention after 100 cycles at a cut-off voltage of 4.2 V. This work provides a new insight for cathode modification based on nickel-rich layered oxides and sulfide-based all-solid-state lithium batteries.
- All-solid-state lithium batteries,
- Sulfide solid-state electrolytes,
- Nickel-rich layered oxide cathode,
- Ti₃(PO₄)₄ coating,
- Interfacial engineering,
- Oxygen release
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通讯作者: 陈斌, bchen63@163.com

Dual functional Ti₃(PO₄)₄-coated NCM811 cathode enables highly stable sulfide-based all-solid-state lithium batteries