Citation: Xiao-Ming Chen, Lianhui Song, Jun Pan, Fei Zeng, Yi Xie, Wei Wei, Dong Yi. Visible-light-induced four-component difunctionalization of alkenes to construct phosphorodithioate-containing quinoxalin-2(1H)-ones[J]. Chinese Chemical Letters, ;2024, 35(11): 110112. doi: 10.1016/j.cclet.2024.110112 shu

Visible-light-induced four-component difunctionalization of alkenes to construct phosphorodithioate-containing quinoxalin-2(1H)-ones

Xiao-Ming Chen ^{a, 1,*,} ,
Lianhui Song ^{b, 1} ,
Jun Pan ^a ,
Fei Zeng ^a ,
Yi Xie ^a ,
Wei Wei ^{b, *,} ,
Dong Yi ^{c, *,}

a.
Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou 425199, China
b.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
c.
Green Pharmaceutical Technology Key Laboratory of Luzhou City, School of Pharmacy, Southwest Medical University, Luzhou 646000, China

chenxiaoming3012@163.com

weiweiqfnu@163.com

yidong@swmu.edu.cn

Received Date: 15 April 2024
Revised Date: 29 May 2024
Accepted Date: 11 June 2024
Available Online: 25 June 2024

Figures(7)

A facile visible-light-induced 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) catalyzed four-component reaction of alkenes, quinoxalin-2(1H)-ones, P₄S₁₀ and alcohols has been developed at room temperature. This tandem reaction provides an efficient strategy for the construction of various phosphorodithioate-containing quinoxalin-2(1H)-ones with moderate to good yields by using air (dioxygen) as the green oxidant. Experimental studies revealed a radical process was involved in this photochemical reaction.
- Visible-light catalysis,
- Four-component reaction,
- Phosphorodithioate,
- Quinoxalin-2(1H)-ones
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