Citation: Jingyu Shi, Xiaofeng Wu, Yutong Chen, Yi Zhang, Xiangyan Hou, Ruike Lv, Junwei Liu, Mengpei Jiang, Keke Huang, Shouhua Feng. Structure factors dictate the ionic conductivity and chemical stability for cubic garnet-based solid-state electrolyte[J]. Chinese Chemical Letters, ;2025, 36(5): 109938. doi: 10.1016/j.cclet.2024.109938 shu

Structure factors dictate the ionic conductivity and chemical stability for cubic garnet-based solid-state electrolyte

Jingyu Shi ^a ,
Xiaofeng Wu ^a ,
Yutong Chen ^a ,
Yi Zhang ^a ,
Xiangyan Hou ^a ,
Ruike Lv ^a ,
Junwei Liu ^a ,
Mengpei Jiang ^b ,
Keke Huang ^{a, *,} ,
Shouhua Feng ^a

a.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin Provincial International Cooperation Key Laboratory of Advanced Inorganic Solid Functional Materials, Jilin University, Changchun 130012, China
b.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

kkhuang@jlu.edu.cn

Received Date: 29 January 2024
Revised Date: 18 March 2024
Accepted Date: 28 April 2024
Available Online: 29 April 2024

Figures(9)

Solid-state electrolytes (SSEs), as the core component within the next generation of key energy storage technologies - solid-state lithium batteries (SSLBs) - are significantly leading the development of future energy storage systems. Among the numerous types of SSEs, inorganic oxide garnet-structured superionic conductors Li₇La₃Zr₂O₁₂ (LLZO) crystallized with the cubic Ia3d space group have received considerable attention owing to their highly advantageous intrinsic properties encompassing reasonable lithium-ion conductivity, wide electrochemical voltage window, high shear modulus, and excellent chemical stability with electrodes. However, no SSEs possess all the properties necessary for SSLBs, thus both the ionic conductivity at room temperature and stability in ambient air regarding cubic garnet-based electrolytes are still subject to further improvement. Hence, this review comprehensively covers the nine key structural factors affecting the ion conductivity of garnet-based electrolytes comprising Li concentration, Li vacancy concentration, Li carrier concentration and mobility, Li occupancy at available sites, lattice constant, triangle bottleneck size, oxygen vacancy defects, and Li-O bonding interactions. Furthermore, the general illustration of structures and fundamental features being crucial to chemical stability is examined, including Li concentration, Li-site occupation behavior, and Li-O bonding interactions. Insights into the composition-structure-property relations among cubic garnet-based oxide ionic conductors from the perspective of their crystal structures, revealing the potential compatibility conflicts between ionic transportation and chemical stability resulting from Li-O bonding interactions. We believe that this review will lay the foundation for future reasonable structural design of oxide-based or even other types of superionic conductors, thus assisting in promoting the rapid development of alternative green and sustainable technologies.
- Garnet-structured solid-state electrolyte,
- Structure factors,
- Ionic conductivity,
- Chemical stability,
- Li-ion battery
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沈阳化工大学材料科学与工程学院沈阳 110142