Citation: Linlu Bai, Wensen Li, Xiaoyu Chu, Haochun Yin, Yang Qu, Ekaterina Kozlova, Zhao-Di Yang, Liqiang Jing. Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction[J]. Chinese Chemical Letters, ;2025, 36(2): 109931. doi: 10.1016/j.cclet.2024.109931 shu

Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction

Linlu Bai ^{a, 1,} ,
Wensen Li ^{a, b, 1} ,
Xiaoyu Chu ^{a, b} ,
Haochun Yin ^a ,
Yang Qu ^a ,
Ekaterina Kozlova ^c ,
Zhao-Di Yang ^b ,
Liqiang Jing ^{a, *,}

a.
Department Key Laboratory of Functional Inorganic Materials Chemistry (Heilongjiang University), Ministry of Education, School of Chemistry and Materials Science, International Joint Research Center and Lab for Catalytic Technology, Harbin 150080, China
b.
School of Materials Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150080, China
c.
Federal Research Center Boreskov Institute of Catalysis, 630090 Novosibirsk, Russian Federation

llbai@hlju.edu.cn

jinglg@hlju.edu.cn

Received Date: 16 December 2022
Revised Date: 31 March 2024
Accepted Date: 27 April 2024
Available Online: 29 April 2024

Figures(5)

The interface modulation significantly affects the photocatalytic performances of supported metal phthalocyanines (MPc)-based systems. Herein, ZnPc was loaded on nanosized Au-modified TiO₂ nanosheets (Au-T) to obtain wide-spectrum ZnPc/Au-T photocatalysts. Compared with large Au NP (8 nm)-mediated ZnPc/Au-T photocatalyst, ultrasmall Au NP (3 nm)-mediated one shows advantageous photoactivity, achieving 3- and 10-fold CO₂ conversion rates compared with reference ZnPc/T and pristine TiO₂ nanosheets, respectively. Employing monochromatic beam-assisted surface photovoltage and photocurrent action, etc., the introduction of ultrasmall Au NPs more effectively facilitates intrinsic interfacial charge transfer. Moreover, ZnPc molecules are found more dispersed with the existence of small Au NPs hence exposing abundant Zn²⁺sites as the catalytic center for CO₂ reduction. This work provides a feasible design strategy and renewed recognition for supported MPc-based photocatalyst systems.
- Supported MPc photocatalyst,
- Au nanoparticle,
- Interface modulation,
- Charge separation,
- CO₂ photoreduction
1. [1]
  C.A. Trickett, A. Helal, B.A. Al-Maythalony, et al., Nat. Rev. Mater. 2 (2017) 17045–17060. doi: 10.1038/natrevmats.2017.45
2. [2]
  D.U. Nielsen, X.M. Hu, K. Daasbjerg, T. Skrydstrup, Nat. Catal. 2 (2018) 95. doi: 10.1038/s41929-018-0152-z
3. [3]
  Y.F. Li, Y.C. Wei, Z.L. Tang, et al., Chin. Chem. Lett. 34 (2023) 108417. doi: 10.1016/j.cclet.2023.108417
4. [4]
  L. Jiang, S. Zhou, J. Yang, et al., Adv. Funct. Mater. 32 (2021) 2108977.
5. [5]
  Q.S. Zhang, X. Yang, Y. Liu, et al., Chin. Chem. Lett. 34 (2023) 107628. doi: 10.1016/j.cclet.2022.06.051
6. [6]
  R. Schappi, D. Rutz, F. Dahler, et al., Nature 601 (2022) 63–68. doi: 10.1038/s41586-021-04174-y
7. [7]
  Z. Xiong, H. Wang, N. Xu, et al., Int. J. Hydrog. Energy 40 (2015) 10049–10062. doi: 10.1016/j.ijhydene.2015.06.075
8. [8]
  Z. Xiong, Z. Lei, Y. Li, L. Dong, Y. Zhao, J. Zhan, J. Photochem. 36 (2018) 24–47. doi: 10.1016/j.jphotochemrev.2018.07.002
9. [9]
  J. Wang, R.T. Guo, Z.X. Bi, X. Chen, X. Hu, W.G. Pan, Nanoscale. 14 (2022) 11512–11528. doi: 10.1039/d2nr02527b
10. [10]
  F. Xu, K. Meng, B. Cheng, et al., Nat. Commun. 11 (2020) 4613–4621. doi: 10.1038/s41467-020-18350-7
11. [11]
  T. Zhang, X. Han, N.T. Nguyen, L. Yang, X. Zhou, Chin. J. Catal. 43 (2022) 2500–2529. doi: 10.1016/S1872-2067(21)64045-7
12. [12]
  J. Fernandez-Ariza, R.M. Krick Calderon, M.S. Rodriguez-Morgade, D.M. Guldi, T. Torres, J. Am. Chem. Soc. 138 (2016) 12963–12974. doi: 10.1021/jacs.6b07432
13. [13]
  A. de la Escosura, M.V. Martinez-Diaz, P. Thordarson, et al., J. Am. Chem. Soc. 125 (2003) 12300–12308. doi: 10.1021/ja030038m
14. [14]
  D. Chen, K. Wang, W. Hong, et al., Appl. Catal. B 166-167 (2015) 366–373. doi: 10.1016/j.apcatb.2014.11.050
15. [15]
  Y.Y. Wang, Y. Qu, B.H. Qu, et al., Adv. Mater. 33 (2021) 2105482. doi: 10.1002/adma.202105482
16. [16]
  J. Bian, J. Feng, Z. Zhang, et al., Angew. Chem. Int. Ed. 58 (2019) 10873–10878. doi: 10.1002/anie.201905274
17. [17]
  J. Bian, J. Feng, Z. Zhang, et al., Chem. Commun. 56 (2020) 4926–4929. doi: 10.1039/d0cc01518k
18. [18]
  L. Wang, W. Chen, D. Zhang, et al., Chem. Soc. Rev. 48 (2019) 5310–5349. doi: 10.1039/c9cs00163h
19. [19]
  S.D. Sun, L.P. He, M. Yang, J. Cui, S.H. Liang. Adv. Funct. Mater. 32 (2021) 2106982. doi: 10.1002/adfm.202106982
20. [20]
  M. Wang, Q.T. Han, L. Li, et al., Nanotechnology 28 (2017) 274002. doi: 10.1088/1361-6528/aa6bb5
21. [21]
  N. Zhang, S. Xie, B. Weng, Y.J. Xu, J. Mater. Chem. A 4 (2016) 18804–18814. doi: 10.1039/C6TA07845A
22. [22]
  P. Khurana, S. Thatai, N.B. Chaure, S. Mahamuni, S. Kulkarni, Thin Solid Films 565 (2014) 202–206. doi: 10.1016/j.tsf.2014.06.015
23. [23]
  Z. Wang, J. Feng, X. Li, et al., Colloid Interface Sci. 588 (2021) 787–794. doi: 10.1016/j.jcis.2020.11.112
24. [24]
  H. Lu, Y. Qu, L. Sun, et al., ACS Sustain. Chem. Eng. 6 (2018) 14652–14659. doi: 10.1021/acssuschemeng.8b03222
25. [25]
  J.N. Feng, J. Bian, L.L. Bai, et al., Appl. Catal. B 295 (2021) 120260. doi: 10.1016/j.apcatb.2021.120260
26. [26]
  X. Han, Q. Kuang, M. Jin, Z. Xie, L. Zheng, J. Am. Chem. Soc. 131 (2009) 3152–3153. doi: 10.1021/ja8092373
27. [27]
  M. Du, D. Sun, H. Yang, et al., Phys. Chem. C 118 (2014) 19150–19157. doi: 10.1021/jp504681f
28. [28]
  D. Tsukamoto, Y. Shiraishi, Y. Sugano, et al., J. Am. Chem. Soc. 134 (2012) 6309–6315. doi: 10.1021/ja2120647
29. [29]
  Q. Wang, W. Wu, J. Chen, G. et al., Colloids Surf. 409 (2012) 118–125. doi: 10.1016/j.colsurfa.2012.06.010
30. [30]
  P. Gargiani, M. Angelucci, C. Mariani, M.G. Betti, Phys. Rev. B 81 (2010) 085412. doi: 10.1103/PhysRevB.81.085412
31. [31]
  Y.B. Shi, G.M. Zhan, H. Li, et al., Adv. Mater. 33 (2021) 2100143. doi: 10.1002/adma.202100143
32. [32]
  K. Wang, M.Y. Cao, J.B. Lu, et al., Appl. Catal. B 296 (2021) 120341. doi: 10.1016/j.apcatb.2021.120341
1. [1]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
2. [2]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Boosting bulk charge transport of CuWO4 photoanodes via Cs doping for solar water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100207-100207. doi: 10.1016/j.cjsc.2023.100207
3. [3]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
4. [4]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
5. [5]
  Yangrui Xu , Yewei Ren , Xinlin Liu , Hongping Li , Ziyang Lu . 具有高传质和亲和表面的NH₂-UIO-66基疏水多孔液体用于增强CO₂光还原. Acta Physico-Chimica Sinica, 2024, 40(11): 2403032-. doi: 10.3866/PKU.WHXB202403032
6. [6]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
7. [7]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
8. [8]
  Yongheng Ren , Yang Chen , Hongwei Chen , Lu Zhang , Jiangfeng Yang , Qi Shi , Lin-Bing Sun , Jinping Li , Libo Li . Electrostatically driven kinetic Inverse CO2/C2H2 separation in LTA-type zeolites. Chinese Journal of Structural Chemistry, 2024, 43(10): 100394-100394. doi: 10.1016/j.cjsc.2024.100394
9. [9]
  Huirong Chen , Yingzhi He , Yan Han , Jianbo Hu , Jiantang Li , Yunjia Jiang , Basem Keshta , Lingyao Wang , Yuanbin Zhang . A new SIFSIX anion pillared cage MOF with crs topological structure for efficient C2H2/CO2 separation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100508-100508. doi: 10.1016/j.cjsc.2024.100508
10. [10]
  Yuhao Guo , Na Li , Tingjiang Yan . Tandem catalysis for photoreduction of CO2 into multi-carbon fuels on atomically thin dual-metal phosphochalcogenides. Chinese Journal of Structural Chemistry, 2024, 43(7): 100320-100320. doi: 10.1016/j.cjsc.2024.100320
11. [11]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
12. [12]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
13. [13]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
14. [14]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
15. [15]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
16. [16]
  Fahui Xiang , Lu Li , Zhen Yuan , Wuji Wei , Xiaoqing Zheng , Shimin Chen , Yisi Yang , Liangji Chen , Zizhu Yao , Jianwei Fu , Zhangjing Zhang , Shengchang Xiang . Enhanced C₂H₂/CO₂ separation in tetranuclear Cu(Ⅱ) cluster-based metal-organic frameworks by adjusting divider length of pore space partition. Chinese Chemical Letters, 2025, 36(3): 109672-. doi: 10.1016/j.cclet.2024.109672
17. [17]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
18. [18]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
19. [19]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
20. [20]
  Chang LIU , Chao ZHANG , Tongbu LU . Small-size Au nanoparticles anchored on pyrenyl-graphdiyne for N₂ electroreduction. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 174-182. doi: 10.11862/CJIC.20240305

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(211)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effects of nanosized Au on the interface of zinc phthalocyanine/TiO2 for CO2 photoreduction

Metrics

通讯作者: 陈斌, bchen63@163.com

Effects of nanosized Au on the interface of zinc phthalocyanine/TiO₂ for CO₂ photoreduction