Citation: Fabrice Nelly Habarugira, Ducheng Yao, Wei Miao, Chengcheng Chu, Zhong Chen, Shun Mao. Synergy of sodium doping and nitrogen defects in carbon nitride for promoted photocatalytic synthesis of hydrogen peroxide[J]. Chinese Chemical Letters, ;2024, 35(8): 109886. doi: 10.1016/j.cclet.2024.109886 shu

Synergy of sodium doping and nitrogen defects in carbon nitride for promoted photocatalytic synthesis of hydrogen peroxide

Fabrice Nelly Habarugira ^{a, 1} ,
Ducheng Yao ^{a, 1} ,
Wei Miao ^b ,
Chengcheng Chu ^a ,
Zhong Chen ^a ,
Shun Mao ^{a, *,}

a.
College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China
b.
Baowu Water Technology Co., Ltd. Research Institute, Shanghai 201999, China

shunmao@tongji.edu.cn

Received Date: 30 December 2023
Revised Date: 21 February 2024
Accepted Date: 11 April 2024
Available Online: 12 April 2024

Figures(4)

Photocatalytic synthesis of hydrogen peroxide has gradually become a promising method for in-situ production of hydrogen peroxide, which relies on sustainable solar energy. However, the commonly used photocatalyst, i.e., carbon nitride (CN), still suffers from the drawbacks of narrow light absorption range and fast charge recombination. Here, we report a facile method to introduce nitrogen defects into carbon nitride together with sodium ion. By adjusting the ratio of sodium dicyandiamide, the band gap of carbon nitride can be controlled, while the carrier separation and transfer ability of carbon nitride is improved. The modified CN with sodium doping and nitrogen defect (SD-CN) demonstrates outstanding H₂O₂ production performance (H₂O₂ yield rate of 297.2 µmol L⁻¹ h⁻¹) under visible light irradiation, which is approximately 9.8 times higher than that of pristine CN. This work deepens the understanding of the coordinated effect of structural defect and element doping of carbon nitride on the photocatalytic H₂O₂ production performance, and provides new insight into the design of photocatalytic system for efficient production of H₂O₂.
- Photocatalysis,
- H₂O₂ evolution,
- Sodium doping,
- Nitrogen defect,
- Metal-free catalyst
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