Citation: Ming Zhong, Xue Guo, Yang Liu, Kun Zhao, Hui Peng, Suijun Liu, Xiaobo Zhang. Molybdenum-glycerate@zeolitic imidazolate framework spheres derived hierarchical nitrogen-doped carbon-encapsulated bimetallic selenides heterostructures for improved lithium-ion storage[J]. Chinese Chemical Letters, ;2025, 36(5): 109873. doi: 10.1016/j.cclet.2024.109873 shu

Molybdenum-glycerate@zeolitic imidazolate framework spheres derived hierarchical nitrogen-doped carbon-encapsulated bimetallic selenides heterostructures for improved lithium-ion storage

Ming Zhong ^{a, c, *,} ,
Xue Guo ^a ,
Yang Liu ^a ,
Kun Zhao ^a ,
Hui Peng ^c ,
Suijun Liu ^{b, *,} ,
Xiaobo Zhang ^{a, *,}

a.
State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
b.
School of Chemistry and Chemical Engineering, Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, China
c.
Key Laboratory of Eco-Functional Polymer Materials of the Ministry of Education, Key Laboratory of Eco-Environmental Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

zhongming@lut.edu.cn

sjliu@jxust.edu.cn

xbzhang@lut.edu.cn

Received Date: 7 February 2024
Revised Date: 24 March 2024
Accepted Date: 8 April 2024
Available Online: 10 April 2024

Figures(4)

In this work, the synthesis of uniform zeolitic imidazolate framework-coated Mo-glycerate spheres and their subsequent conversion into hierarchical architecture containing bimetallic selenides heterostructures and nitrogen-doped carbon shell are reported. Selenization temperature plays a significant role in determining the phases, morphology, and lithium-ion storage performance of the composite. Notably, the optimal electrode demonstrates an ultrahigh reversible capacity of 1298.2 mAh/g after 100 cycles at 0.2 A/g and an outstanding rate capability with the capacity still maintained 505.7 mAh/g after 300 cycles at 1.0 A/g, surpassing the calculated theoretical capacity according to individual component and most of the reported MoSe@C- or ZnSe@C-based anodes. Furthermore, ex-situ X-ray diffraction patterns reveal the combined conversion and alloying reaction mechanisms of the composite.
- Zeolitic imidazolate framework,
- Heterostructure,
- Core-shell structure,
- Electrode material,
- Lithium-ion battery
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