Citation: Yu-Yao Li, Xiao-Hui Li, Zhi-Xuan An, Yang Chu, Xiu-Li Wang. Room-temperature olefin epoxidation reaction by two 2D cobalt metal-organic complexes under O₂ atmosphere: Coordination and structural regulation[J]. Chinese Chemical Letters, ;2025, 36(4): 109716. doi: 10.1016/j.cclet.2024.109716 shu

Room-temperature olefin epoxidation reaction by two 2D cobalt metal-organic complexes under O₂ atmosphere: Coordination and structural regulation

Yu-Yao Li ^{, 1} ,
Xiao-Hui Li ^{, 1} ,
Zhi-Xuan An ,
Yang Chu ,
Xiu-Li Wang ^{, *,}

College of Chemistry and Materials Engineering, Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, Bohai University, Jinzhou 121013, China

925091198@qq.com

wangxiuli@bhu.edu.cn

Received Date: 24 January 2024
Revised Date: 14 February 2024
Accepted Date: 1 March 2024
Available Online: 9 March 2024

Figures(5)

Selective oxidation of olefin to epoxides is an important reaction in industry, however, developing heterogeneous catalysts to achieve the effective catalysis for this reaction under O₂ atmosphere at room temperature is challenging but highly desired. In this work, two novel 2D cobalt metal-organic complexes, namely [Co(L)(5-HIP)]·2H₂O (Co-MOC-1) and [Co(L)(BTEC)_0.5]·H₂O (Co-MOC-2) (L = (E)-4,4′-(ethene-1,2-diyl)bis(N-(pyridin-3-yl)benzamide; 5-H₂HIP = 5-hydroxyisophthalic acid; H₄BTEC = pyromellitic acid) were designed and synthesized through hydrothermal method, which exhibited different metal coordination modes (4-coordinate and 5-coordinate, respectively) and 2D layer structures directed by different carboxylates co-ligands. Two Co-MOCs can serve as heterogeneous catalysts for the selective oxidation of olefins to epoxides at room temperature using O₂ as oxidant. Furthermore, a higher catalysis activity of Co-MOC-1 than Co-MOC-2 (96.7% vs. 90.2% yield of 1,2-epoxycyclooctane) was observed, which may be attributed to the coordination unsaturated Co centers, the less coordination number and larger interlayer spacing of Co-MOC-1.
- Epoxidation,
- Room-temperature reaction,
- Metal-organic complex,
- Heterogeneous catalysts,
- Coordination unsaturated Co
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Room-temperature olefin epoxidation reaction by two 2D cobalt metal-organic complexes under O2 atmosphere: Coordination and structural regulation

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通讯作者: 陈斌, bchen63@163.com

Room-temperature olefin epoxidation reaction by two 2D cobalt metal-organic complexes under O₂ atmosphere: Coordination and structural regulation