Citation: Zhuo Li, Peng Yu, Di Shen, Xinxin Zhang, Zhijian Liang, Baoluo Wang, Lei Wang. Low-loading Pt anchored on molybdenum carbide-based polyhedral carbon skeleton for enhancing pH-universal hydrogen production[J]. Chinese Chemical Letters, ;2025, 36(4): 109713. doi: 10.1016/j.cclet.2024.109713 shu

Low-loading Pt anchored on molybdenum carbide-based polyhedral carbon skeleton for enhancing pH-universal hydrogen production

Zhuo Li ^{a, 1} ,
Peng Yu ^{b, 1} ,
Di Shen ^a ,
Xinxin Zhang ^a ,
Zhijian Liang ^a ,
Baoluo Wang ^a ,
Lei Wang ^{a, *,}

a.
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, Heilongjiang University, Harbin 150080, China
b.
Key Laboratory for Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, Harbin Normal University, Harbin 150025, China

wanglei0525@hlju.edu.cn

Received Date: 4 February 2024
Revised Date: 19 February 2024
Accepted Date: 1 March 2024
Available Online: 11 March 2024

Figures(7)

Developing high-efficient and low-loading Pt based catalyst is significant for the electrocatalytic pH-universal hydrogen evolution reaction (HER). Herein, the molybdenum carbide nanoparticles supported on the polyhedral N-doped carbon nanotube skeleton (MoC/NCT) composite has been synthesized by a pyrolysis of polyacid organo-metallic phosphate framework precursor. Then, only 2.15 wt% Pt are loaded on the MoC/NCT to form Pt-MoC/NCT catalyst, which performs superior HER activity and stability in entire pH range. Specially, the overpotentials of 22 and 74 mV are respectively attained at 10 mA/cm² in 1.0 mol/L KOH and 0.5 mol/L H₂SO₄ electrolytes, approaching or even exceeding commercial Pt/C. More importantly, it can be used as excellent catalyst for efficient hydrogen production at 0–14 pH range. Density functional theory (DFT) calculations demonstrate that the interaction between MoC and Pt leads to the electron redistribution at the corresponding interfaces and the downward shift of the d-band centers, thus optimizing H* adsorption and desorption for promoting the HER activity. Besides, the unique three-dimensional network structure is conductive to the transmission of mass and electrons. In the application of both alkaline and acidic electrolysers, only 1.52 V voltage of solar panel can drive a hydrogen production current density of 10 mA/cm².
- Organo-metallic phosphate framework,
- Low-Pt electrocatalyst,
- Wide-pH,
- Hydrogen evolution reaction,
- Water electrolysis
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