Citation: Kailong Zhang, Chao Zhang, Luanhui Wu, Qidong Yang, Jiadong Zhang, Guang Hu, Liang Song, Gaoran Li, Wenlong Cai. Chloride molten salt derived attapulgite with ground-breaking electrochemical performance[J]. Chinese Chemical Letters, ;2024, 35(10): 109618. doi: 10.1016/j.cclet.2024.109618 shu

Chloride molten salt derived attapulgite with ground-breaking electrochemical performance

Kailong Zhang ^{a, 1} ,
Chao Zhang ^{a, 1} ,
Luanhui Wu ^a ,
Qidong Yang ^a ,
Jiadong Zhang ^{a, *,} ,
Guang Hu ^a ,
Liang Song ^{a, *,} ,
Gaoran Li ^b ,
Wenlong Cai ^{c, *,}

a.
School of Chemical Engineering, Huaiyin Institute of Technology, Huaian 223003, China
b.
School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
c.
College of Materials Science and Engineering, Sichuan University, Chengdu 610064, China

jiadongzhang@hyit.edu.cn

songl@hyit.edu.cn

caiwl@scu.edu.cn

Received Date: 8 January 2024
Revised Date: 29 January 2024
Accepted Date: 7 February 2024
Available Online: 9 February 2024

Figures(4)

The existence of adsorbed water and structural water in the crystal structure of attapulgite (ATP) endows it with poor capability to store lithium ions. Herein, the chloride molten salt method was developed to function ATP materials based on theoretical calculations, which exhibit ground-breaking electrochemical performance. After the modification process, the metal ions in chloride molten salt occupy the vertices of the Mg-O octahedral structure from the liberation of structural water and hydroxyl groups in ATP, forming M_aMg_bAl_cSi_xO_y (M = Li, Na, or K). Using LiCl molten salt-modified ATP (Li-ATP) as a proof-of-concept, the detailed phase transition, physicochemical properties, and lithium storage capacity were investigated. Compared to the original ATP, Li-ATP achieves a nearly 7-fold increase in lithium storage capacity (498 mAh/g), featuring a promising low-cost polyanionic type anode material.
- Molten salt modification,
- Attapulgite,
- Phase transition,
- Electrochemical performance,
- Anode
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