Citation: Fengrui Yang, Debing Wang, Xinying Zhang, Jie Zhang, Zhichao Wu, Qiaoying Wang. Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways[J]. Chinese Chemical Letters, ;2024, 35(10): 109599. doi: 10.1016/j.cclet.2024.109599 shu

Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways

Fengrui Yang ^a ,
Debing Wang ^{a, *,} ,
Xinying Zhang ^b ,
Jie Zhang ^a ,
Zhichao Wu ^a ,
Qiaoying Wang ^{a, *,}

a.
State Key Laboratory of Pollution Control and Resource Reuse, Shanghai Institute of Pollution Control and Ecological Security, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
b.
Fujian Provincial Engineering Research Center of Rural Waste Recycling Technology, College of Environment & Safety Engineering, Fuzhou University, Fuzhou 350108, China

Wangdb@tongji.edu.cn

qywang@tongji.edu.cn

Received Date: 23 October 2023
Revised Date: 4 January 2024
Accepted Date: 31 January 2024
Available Online: 4 February 2024

Figures(5)

Tetracycline (TC) as a typical emerging pollutant is becoming a serious threat to the environment and human health. A combined advanced oxidation technology of UV/Ozone (O₃)/peroxydisulfate (PDS) process was developed to explore an efficient and economic treatment process of TC in wastewater. Furthermore, the reactive sites and transformation pathways of TC were explored and the toxicity of the intermediates was quantified with a quantitative structure-activity relationship (QSAR) assessment. The degradation performance of TC was substantially enhanced in UV/O₃/PDS process with a k_obs of 0.0949 min⁻¹, which was 2.3 times higher than UV/O₃ and 3.2 times than sole UV. The results demonstrated that there was a superior synergistic effect of PDS on UV/O₃ processes for the degradation of TC. Electron paramagnetic resonance (EPR) analysis and quenching experiments show that ^•OH, SO₄^•−, O₂^•− and ¹O₂ all contributed to TC degradation in the UV/O₃/PDS process and exhibited a synergistic effect, which inhibited the generation of harmful products. In addition, the UV/O₃/PDS system can effectively degrade TC in a wide range of substrate concentrations and pH, and also showed excellent adaptability to various concentrations of anions (Cl⁻ and HCO₃⁻). This study proves the feasibility of UV/O₃/PDS process for treating TC contaminated wastewater with complicated water matrix.
- UV/ozonation/peroxydisulfate,
- Synergistic effect,
- Tetracycline,
- Degradation,
- Wastewater
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Synergistic effects of peroxydisulfate on UV/O3 process for tetracycline degradation: Mechanism and pathways

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通讯作者: 陈斌, bchen63@163.com

Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways