Citation: Hao Wang, Meng-Qi Pan, Ya-Fei Wang, Chao Chen, Jian Xu, Yuan-Yuan Gao, Chuan-Song Qi, Wei Li, Xian-He Bu. Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes[J]. Chinese Chemical Letters, ;2024, 35(10): 109581. doi: 10.1016/j.cclet.2024.109581 shu

Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes

Hao Wang ^{a, *,} ,
Meng-Qi Pan ^a ,
Ya-Fei Wang ^a ,
Chao Chen ^a ,
Jian Xu ^{b, *,} ,
Yuan-Yuan Gao ^c ,
Chuan-Song Qi ^a ,
Wei Li ^a ,
Xian-He Bu ^b

a.
College of New Materials and Chemical Engineering, Beijing Key Lab of Special Elastomeric Composite Materials, Beijing Institute of Petrochemical Technology, Beijing 102617, China
b.
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China
c.
College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

wangh@bipt.edu.cn

jxu@nankai.edu.cn

Received Date: 8 November 2023
Revised Date: 2 January 2024
Accepted Date: 24 January 2024
Available Online: 1 February 2024

Figures(4)

Post-synthetic modifications (PSM) have drawn great attention as a vigoroso tool to tune or enhance the performance of metal-organic frameworks (MOFs). However, the current PSM method usually have to sacrifice the porosity of MOFs to enrich their functionality, such as pore space partition (PSP) and post-synthetic elimination and insertion (PSE&I), causing a trade-off in this aspect. To address this issue, we herein propose a new PSM strategy of using the size-matching ligands as the bolts to lock MOFs’ pores, which could be anchored onto open metal sites (OMSs) after guest loading through a stepwise manipulation. As a result, the loaded cargoes undergo a controlled releasing process with respect to different bolt ligands. Our proposed strategy provides a promising way to balance the functionality and porosity of MOFs.
- Post-synthetic modifications,
- Metal-organic frameworks,
- Bolting ligand,
- Control release,
- Cargo
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